Photogeneration of active formate decomposition catalysts to produce hydrogen from formate and water
Abstract
A process for producing hydrogen from formate and water by photogenerating an active formate decomposition catalyst from transition metal carbonyl precursor catalysts at relatively low temperatures and otherwise mild conditions is disclosed. Additionally, this process may be expanded to include the generation of formate from carbon monoxide and hydroxide such that the result is the water gas shift reaction.
- Inventors:
-
- (Athens, GA)
- Athens, GA
- Issue Date:
- OSTI Identifier:
- 864489
- Patent Number(s):
- 4372833
- Application Number:
- 06/254,588
- Assignee:
- University of Georgia Research Foundation, Inc. (Athens, GA)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
- DOE Contract Number:
- AS09-76ER00933
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- photogeneration; active; formate; decomposition; catalysts; produce; hydrogen; water; process; producing; photogenerating; catalyst; transition; metal; carbonyl; precursor; relatively; temperatures; otherwise; mild; conditions; disclosed; additionally; expanded; generation; carbon; monoxide; hydroxide; result; gas; shift; reaction; produce hydrogen; carbon monoxide; transition metal; metal carbonyl; producing hydrogen; mild conditions; shift reaction; metal carbon; water gas; gas shift; formate decomposition; active form; active formate; decomposition catalyst; /204/
Citation Formats
King, Jr., Allen D., King, Robert B, and Sailers, III, Earl L. Photogeneration of active formate decomposition catalysts to produce hydrogen from formate and water. United States: N. p., 1983.
Web.
King, Jr., Allen D., King, Robert B, & Sailers, III, Earl L. Photogeneration of active formate decomposition catalysts to produce hydrogen from formate and water. United States.
King, Jr., Allen D., King, Robert B, and Sailers, III, Earl L. Tue .
"Photogeneration of active formate decomposition catalysts to produce hydrogen from formate and water". United States. https://www.osti.gov/servlets/purl/864489.
@article{osti_864489,
title = {Photogeneration of active formate decomposition catalysts to produce hydrogen from formate and water},
author = {King, Jr., Allen D. and King, Robert B and Sailers, III, Earl L.},
abstractNote = {A process for producing hydrogen from formate and water by photogenerating an active formate decomposition catalyst from transition metal carbonyl precursor catalysts at relatively low temperatures and otherwise mild conditions is disclosed. Additionally, this process may be expanded to include the generation of formate from carbon monoxide and hydroxide such that the result is the water gas shift reaction.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Feb 08 00:00:00 EST 1983},
month = {Tue Feb 08 00:00:00 EST 1983}
}
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