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Title: Liquefaction process

Abstract

Scale formation during the liquefaction of lower ranking coals and similar carbonaceous materials is significantly reduced and/or prevented by pretreatment with a combination of pretreating agents comprising SO.sub.2 and an oxidizing agent. The pretreatment is believed to convert at least a portion of the scale-forming components and particularly calcium, to the corresponding sulfate prior to liquefaction. The pretreatment may be accomplished with the combination of pretreating agents either simultaneously by using a mixture comprising SO.sub.2 and an oxidizing agent or sequentially by first treating with SO.sub.2 and then with an oxidizing agent.

Inventors:
 [1];  [2];  [2]
  1. Westfield, NJ
  2. Houston, TX
Issue Date:
Research Org.:
Exxon Research and Engineering Co.
OSTI Identifier:
864352
Patent Number(s):
4351716
Assignee:
Exxon Research & Engineering Co. (Florham Park, NJ)
Patent Classifications (CPCs):
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10S - TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10G - CRACKING HYDROCARBON OILS
DOE Contract Number:  
EF-77-A-01-2893
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
liquefaction; process; scale; formation; ranking; coals; similar; carbonaceous; materials; significantly; reduced; prevented; pretreatment; combination; pretreating; agents; comprising; oxidizing; agent; believed; convert; portion; scale-forming; components; particularly; calcium; corresponding; sulfate; prior; accomplished; simultaneously; mixture; sequentially; treating; scale formation; significantly reduce; scale-forming components; ranking coals; carbonaceous materials; liquefaction process; carbonaceous material; mixture comprising; significantly reduced; oxidizing agent; similar carbonaceous; sulfate prior; particularly calcium; pretreating agents; oxidizing agen; agents comprising; /208/

Citation Formats

Gorbaty, Martin L, Stone, John B, and Poddar, Syamal K. Liquefaction process. United States: N. p., 1982. Web.
Gorbaty, Martin L, Stone, John B, & Poddar, Syamal K. Liquefaction process. United States.
Gorbaty, Martin L, Stone, John B, and Poddar, Syamal K. Fri . "Liquefaction process". United States. https://www.osti.gov/servlets/purl/864352.
@article{osti_864352,
title = {Liquefaction process},
author = {Gorbaty, Martin L and Stone, John B and Poddar, Syamal K},
abstractNote = {Scale formation during the liquefaction of lower ranking coals and similar carbonaceous materials is significantly reduced and/or prevented by pretreatment with a combination of pretreating agents comprising SO.sub.2 and an oxidizing agent. The pretreatment is believed to convert at least a portion of the scale-forming components and particularly calcium, to the corresponding sulfate prior to liquefaction. The pretreatment may be accomplished with the combination of pretreating agents either simultaneously by using a mixture comprising SO.sub.2 and an oxidizing agent or sequentially by first treating with SO.sub.2 and then with an oxidizing agent.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1982},
month = {1}
}