High temperature concrete composites containing organosiloxane crosslinked copolymers

Zeldin, Arkady; Carciello, Neal; Kukacka, Lawrence; Fontana, Jack

Title: High temperature concrete composites containing organosiloxane crosslinked copolymers

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Abstract

This invention relates to high temperature polymer concrete composites comprising about 10-30% by weight of a liquid monomer mixture consisting essentially of an organosiloxane polymer crosslinked with an olefinically unsaturated monomer selected from the group consisting of styrene, methyl methacrylate, trimethylolpropane trimethacrylate, triallyl cyanurate, n-phenylmalimide, divinyl benzene and mixtures theroef; and about 70-90% by weight of an inert inorganic filler system containing silica sand and preferably a member selected from the group consisting of portland cement, Fe.sub.2 O.sub.3, carbon black and mixtures thereof; and optionally a free radical initiator such as di-tert-butyl peroxide, azobisisobutyronitrile, benzoyl peroxide, lauryl peroxide and other organic peroxides to initiate crosspolymerization of the monomer mixture in the presence of the inorganic filler.

Inventors:

Zeldin, Arkady ^[1]; Carciello, Neal ^[2]; Kukacka, Lawrence ^[3]; Fontana, Jack ^[4]

Rego Park, NY
Patchogue, NY
Port Jefferson, NY
Shoreham, NY

Issue Date:: 1980-01-01

Research Org.:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

OSTI Identifier:: 863708

Patent Number(s):: 4231917

Assignee:: United States of America as represented by United States (Washington, DC)

Patent Classifications (CPCs):: C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA

C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08K - Use of inorganic or non-macromolecular organic substances as compounding ingredients

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C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B14/022 - {Carbon}
C04B14/06 - Quartz
C04B14/30 - Oxides other than silica {
C04B24/42 - Organo-silicon compounds
C04B26/32 - containing silicon
C04B28/04 - Portland cements
C04B7/02 - Portland cement

C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08K - Use of inorganic or non-macromolecular organic substances as compounding ingredients
C08K3/34 - Silicon-containing compounds
C08K3/36 - Silica
C08K5/01 - Hydrocarbons {
C08K5/11 - of acyclic polycarboxylic acids
C08K5/14 - Peroxides
C08K5/34 - Heterocyclic compounds having nitrogen in the ring

C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08L - COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
C08L83/04 - Polysiloxanes

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DOE Contract Number:: EY-76-C-02-0016

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: temperature; concrete; composites; containing; organosiloxane; crosslinked; copolymers; relates; polymer; comprising; 10-30; weight; liquid; monomer; mixture; consisting; essentially; olefinically; unsaturated; selected; styrene; methyl; methacrylate; trimethylolpropane; trimethacrylate; triallyl; cyanurate; n-phenylmalimide; divinyl; benzene; mixtures; theroef; 70-90; inert; inorganic; filler; silica; sand; preferably; portland; cement; carbon; black; optionally; free; radical; initiator; di-tert-butyl; peroxide; azobisisobutyronitrile; benzoyl; lauryl; organic; peroxides; initiate; crosspolymerization; presence; free radical; portland cement; consisting essentially; carbon black; composites containing; polymer concrete; radical initiator; silica sand; monomer selected; methyl methacrylate; olefinically unsaturated; mixture consisting; composites comprising; liquid monomer; containing silica; temperature polymer; unsaturated monomer; divinyl benzene; concrete composites; /524/106/

Citation Formats


                    Zeldin, Arkady, Carciello, Neal, Kukacka, Lawrence, and Fontana, Jack. High temperature concrete composites containing organosiloxane crosslinked copolymers.  United States: N. p., 1980. 
        Web.

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                    Zeldin, Arkady, Carciello, Neal, Kukacka, Lawrence, & Fontana, Jack. High temperature concrete composites containing organosiloxane crosslinked copolymers.  United States.

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                    Zeldin, Arkady, Carciello, Neal, Kukacka, Lawrence, and Fontana, Jack. Tue .  
        "High temperature concrete composites containing organosiloxane crosslinked copolymers".  United States.  https://www.osti.gov/servlets/purl/863708.

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@article{osti_863708,

  title        = {High temperature concrete composites containing organosiloxane crosslinked copolymers},

  author       = {Zeldin, Arkady and Carciello, Neal and Kukacka, Lawrence and Fontana, Jack},

  abstractNote = {This invention relates to high temperature polymer concrete composites comprising about 10-30% by weight of a liquid monomer mixture consisting essentially of an organosiloxane polymer crosslinked with an olefinically unsaturated monomer selected from the group consisting of styrene, methyl methacrylate, trimethylolpropane trimethacrylate, triallyl cyanurate, n-phenylmalimide, divinyl benzene and mixtures theroef; and about 70-90% by weight of an inert inorganic filler system containing silica sand and preferably a member selected from the group consisting of portland cement, Fe.sub.2 O.sub.3, carbon black and mixtures thereof; and optionally a free radical initiator such as di-tert-butyl peroxide, azobisisobutyronitrile, benzoyl peroxide, lauryl peroxide and other organic peroxides to initiate crosspolymerization of the monomer mixture in the presence of the inorganic filler.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {1980},

  month        = {1}

}

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