Process for introducing electrical conductivity into high-temperature polymeric materials
Abstract
High-temperature electrically conducting polymers. The in situ reactions: AgNO/sub 3/ + RCHO ..-->.. Ag/sup 0/ + RCOOH and R/sub 3/M ..-->.. M/sup 0/ + 3R, where M = Au or Pt have been found to introduce either substantial bulk or surface conductivity in high- temperature polymers. The reactions involving the R/sub 3/M were caused to proceed thermally suggesting the possibility of using laser means for initiating such reactions in selected areas or volumes of the polymeric materials. The polymers successfully investigated to date are polyphenylquinoxaline, polytolylquinoxaline, polyquinoline, polythiazole, and pyrrone. 3 tabs.
- Inventors:
- Issue Date:
- Research Org.:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- OSTI Identifier:
- 6871044
- Patent Number(s):
- 6091251
- Assignee:
- TIC; EDB-88-178458
- Patent Classifications (CPCs):
-
G - PHYSICS G01 - MEASURING G01R - MEASURING ELECTRIC VARIABLES
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01L - SEMICONDUCTOR DEVICES
- DOE Contract Number:
- W-7405-ENG-36
- Resource Type:
- Patent
- Resource Relation:
- Other Information: Portions of this document are illegible in microfiche products
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; POLYMERS; ELECTRIC CONDUCTIVITY; POLYPHENYLS; QUINOLINES; THIAZOLES; CHEMICAL PREPARATION; CHEMICAL REACTIONS; GOLD; INVENTIONS; LASERS; PLATINUM; SILVER NITRATES; THIN FILMS; AROMATICS; AZAARENES; AZINES; AZOLES; ELECTRICAL PROPERTIES; ELEMENTS; FILMS; HETEROCYCLIC COMPOUNDS; HYDROCARBONS; METALS; NITRATES; NITROGEN COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; ORGANIC SULFUR COMPOUNDS; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; PLATINUM METALS; PYRIDINES; SILVER COMPOUNDS; SYNTHESIS; TRANSITION ELEMENT COMPOUNDS; TRANSITION ELEMENTS; 360603* - Materials- Properties; 360601 - Other Materials- Preparation & Manufacture; 400201 - Chemical & Physicochemical Properties
Citation Formats
Liepins, R, Jorgensen, B S, and Liepins, L Z. Process for introducing electrical conductivity into high-temperature polymeric materials. United States: N. p., 1987.
Web.
Liepins, R, Jorgensen, B S, & Liepins, L Z. Process for introducing electrical conductivity into high-temperature polymeric materials. United States.
Liepins, R, Jorgensen, B S, and Liepins, L Z. Thu .
"Process for introducing electrical conductivity into high-temperature polymeric materials". United States.
@article{osti_6871044,
title = {Process for introducing electrical conductivity into high-temperature polymeric materials},
author = {Liepins, R and Jorgensen, B S and Liepins, L Z},
abstractNote = {High-temperature electrically conducting polymers. The in situ reactions: AgNO/sub 3/ + RCHO ..-->.. Ag/sup 0/ + RCOOH and R/sub 3/M ..-->.. M/sup 0/ + 3R, where M = Au or Pt have been found to introduce either substantial bulk or surface conductivity in high- temperature polymers. The reactions involving the R/sub 3/M were caused to proceed thermally suggesting the possibility of using laser means for initiating such reactions in selected areas or volumes of the polymeric materials. The polymers successfully investigated to date are polyphenylquinoxaline, polytolylquinoxaline, polyquinoline, polythiazole, and pyrrone. 3 tabs.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1987},
month = {8}
}