Fabrication of fuel cell electrodes and other catalytic structures
Abstract
A porous layer of catalyst material suitable for use as an electrode in a molten carbonate fuel cell includes elongated pores substantially extending across the layer thickness. The catalyst layer is prepared by depositing particulate catalyst material into polymeric flocking on a substrate surface by a procedure such as tape casting. The loaded substrate is heated in a series of steps with rising temperatures to set the tape, thermally decompose the substrate with flocking and sinter bond the catalyst particles into a porous catalytic layer with elongated pores across its thickness. Employed as an electrode, the elongated pores provide distribution of reactant gas into contact with catalyst particles wetted by molten electrolyte. 1 fig.
- Inventors:
- Issue Date:
- Research Org.:
- Argonne National Lab., IL (USA)
- OSTI Identifier:
- 6813153
- Patent Number(s):
- -US-A6013472
- Assignee:
- ANL; ERA-14-000761; EDB-88-183974
- DOE Contract Number:
- W-31109-ENG-38
- Resource Type:
- Patent
- Resource Relation:
- Other Information: Paper copy only, copy does not permit microfiche production
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 30 DIRECT ENERGY CONVERSION; ELECTRODES; FABRICATION; MOLTEN CARBONATE FUEL CELLS; ANODES; CATALYSTS; CATHODES; DESIGN; ELECTROLYTES; INVENTIONS; IRON COMPOUNDS; LITHIUM COMPOUNDS; NICKEL OXIDES; ALKALI METAL COMPOUNDS; CHALCOGENIDES; DIRECT ENERGY CONVERTERS; ELECTROCHEMICAL CELLS; FUEL CELLS; HIGH-TEMPERATURE FUEL CELLS; NICKEL COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; TRANSITION ELEMENT COMPOUNDS 300501* -- Fuel Cells-- Design & Development; 300503 -- Fuel Cells-- Materials, Components, & Auxiliaries
Citation Formats
Smith, J.L. Fabrication of fuel cell electrodes and other catalytic structures. United States: N. p., 1987.
Web.
Smith, J.L. Fabrication of fuel cell electrodes and other catalytic structures. United States.
Smith, J.L. Wed .
"Fabrication of fuel cell electrodes and other catalytic structures". United States.
@article{osti_6813153,
title = {Fabrication of fuel cell electrodes and other catalytic structures},
author = {Smith, J.L.},
abstractNote = {A porous layer of catalyst material suitable for use as an electrode in a molten carbonate fuel cell includes elongated pores substantially extending across the layer thickness. The catalyst layer is prepared by depositing particulate catalyst material into polymeric flocking on a substrate surface by a procedure such as tape casting. The loaded substrate is heated in a series of steps with rising temperatures to set the tape, thermally decompose the substrate with flocking and sinter bond the catalyst particles into a porous catalytic layer with elongated pores across its thickness. Employed as an electrode, the elongated pores provide distribution of reactant gas into contact with catalyst particles wetted by molten electrolyte. 1 fig.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1987},
month = {2}
}