Electrochemical method of controlling thiolate coverage on a conductive substrate such as gold
Abstract
An electrochemical method is described for forming a partial monomolecular layer of a predetermined extent of coverage of a thiolate of the formula, XRS-, therein R can be a linear or branched chain hydrocarbon or an aromatic or the like and X can be any compatible end group, e.g., OH, COOH, CH{sub 3} or the like, upon a substrate such as gold, which involves applying in an electrochemical system a constant voltage preselected to yield the desired predetermined extent of coverage. 13 figs.
- Inventors:
- Issue Date:
- Research Org.:
- Iowa State Univ., Ames, IA (United States)
- Sponsoring Org.:
- USDOE, Washington, DC (United States); National Aeronautics and Space Administration, Washington, DC (United States)
- OSTI Identifier:
- 675801
- Patent Number(s):
- 5827417
- Application Number:
- PAN: 8-797,409; CNN: Contract ITA[81]87-02;Grant NAS7-918;Grant JPL959452
- Assignee:
- Iowa State Univ. Research Foundation, Inc., Ames, IA (United States)
- DOE Contract Number:
- W-7405-ENG-82
- Resource Type:
- Patent
- Resource Relation:
- Other Information: PBD: 27 Oct 1998
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; ORGANIC SULFUR COMPOUNDS; ELECTRODEPOSITION; CHEMICAL COMPOSITION; GOLD; ELECTRODEPOSITED COATINGS
Citation Formats
Porter, M D, and Weisshaar, D E. Electrochemical method of controlling thiolate coverage on a conductive substrate such as gold. United States: N. p., 1998.
Web.
Porter, M D, & Weisshaar, D E. Electrochemical method of controlling thiolate coverage on a conductive substrate such as gold. United States.
Porter, M D, and Weisshaar, D E. Tue .
"Electrochemical method of controlling thiolate coverage on a conductive substrate such as gold". United States.
@article{osti_675801,
title = {Electrochemical method of controlling thiolate coverage on a conductive substrate such as gold},
author = {Porter, M D and Weisshaar, D E},
abstractNote = {An electrochemical method is described for forming a partial monomolecular layer of a predetermined extent of coverage of a thiolate of the formula, XRS-, therein R can be a linear or branched chain hydrocarbon or an aromatic or the like and X can be any compatible end group, e.g., OH, COOH, CH{sub 3} or the like, upon a substrate such as gold, which involves applying in an electrochemical system a constant voltage preselected to yield the desired predetermined extent of coverage. 13 figs.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1998},
month = {10}
}
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