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Title: Method for removal of plutonium impurity from americium oxides and fluorides

Abstract

Method for removal of plutonium impurity from americium oxides and fluorides. AmF/sub 4/ is not further oxidized to AmF/sub 6/ by the application of O/sub 2/F at room temperature thereto, while plutonium compounds present in the americium sample are fluorinated to volatile PuF/sub 6/, which can readily be separated therefrom, leaving the purified americium oxides and/or fluorides as the solid tetrafluoride thereof.

Inventors:
; ;
Issue Date:
Research Org.:
Los Alamos National Lab., NM (USA)
OSTI Identifier:
6755777
Patent Number(s):
-US-A6014324
Assignee:
TIC; ERA-14-000126; EDB-88-182613
DOE Contract Number:  
W-7405-ENG-36
Resource Type:
Patent
Resource Relation:
Other Information: Portions of this document are illegible in microfiche products
Country of Publication:
United States
Language:
English
Subject:
11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS; AMERICIUM; PURIFICATION; AMERICIUM OXIDES; FLUORINATION; PLUTONIUM; AMERICIUM FLUORIDES; INVENTIONS; REMOVAL; ACTINIDE COMPOUNDS; ACTINIDES; AMERICIUM COMPOUNDS; CHALCOGENIDES; CHEMICAL REACTIONS; ELEMENTS; FLUORIDES; FLUORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; HALOGENATION; METALS; OXIDES; OXYGEN COMPOUNDS; TRANSPLUTONIUM COMPOUNDS; TRANSPLUTONIUM ELEMENTS; TRANSURANIUM COMPOUNDS; TRANSURANIUM ELEMENTS 050700* -- Nuclear Fuels-- Fuels Production & Properties

Citation Formats

FitzPatrick, J.R., Dunn, J.G., and Avens, L.R. Method for removal of plutonium impurity from americium oxides and fluorides. United States: N. p., 1987. Web.
FitzPatrick, J.R., Dunn, J.G., & Avens, L.R. Method for removal of plutonium impurity from americium oxides and fluorides. United States.
FitzPatrick, J.R., Dunn, J.G., and Avens, L.R. Fri . "Method for removal of plutonium impurity from americium oxides and fluorides". United States.
@article{osti_6755777,
title = {Method for removal of plutonium impurity from americium oxides and fluorides},
author = {FitzPatrick, J.R. and Dunn, J.G. and Avens, L.R.},
abstractNote = {Method for removal of plutonium impurity from americium oxides and fluorides. AmF/sub 4/ is not further oxidized to AmF/sub 6/ by the application of O/sub 2/F at room temperature thereto, while plutonium compounds present in the americium sample are fluorinated to volatile PuF/sub 6/, which can readily be separated therefrom, leaving the purified americium oxides and/or fluorides as the solid tetrafluoride thereof.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1987},
month = {2}
}