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Title: Catalyst system comprising a first catalyst system tethered to a supported catalyst

Abstract

The present invention provides new catalyst formats which comprise a supported catalyst tethered to a second and different catalyst by a suitable tethering ligand. A preferred system comprises a heterogeneous supported metal catalyst tethered to a homogeneous catalyst. This combination of homogeneous and heterogeneous catalysts has a sufficient lifetime and unusually high catalytic activity in arene hydrogenations, and potentially many other reactions as well, including, but not limited to hydroformylation, hydrosilication, olefin oxidation, isomerization, hydrocyanidation, olefin metathesis, olefin polymerization, carbonylation, enantioselective catalysis and photoduplication. These catalysts are easily separated from the products, and can be reused repeatedly, making these systems very economical. 2 figs.

Inventors:
;
Issue Date:
Research Org.:
Iowa State Univ., Ames, IA (United States)
Sponsoring Org.:
USDOE, Washington, DC (United States)
OSTI Identifier:
672674
Patent Number(s):
5789333
Application Number:
PAN: 8-811,426
Assignee:
Iowa State Univ. Research Foundation, Inc., Ames, IA (United States)
DOE Contract Number:  
W-7405-ENG-82
Resource Type:
Patent
Resource Relation:
Other Information: PBD: 4 Aug 1998
Country of Publication:
United States
Language:
English
Subject:
40 CHEMISTRY; CATALYST SUPPORTS; CATALYSTS; SERVICE LIFE; HYDROGENATION; ALKENES; RECYCLING

Citation Formats

Angelici, R J, and Gao, H. Catalyst system comprising a first catalyst system tethered to a supported catalyst. United States: N. p., 1998. Web.
Angelici, R J, & Gao, H. Catalyst system comprising a first catalyst system tethered to a supported catalyst. United States.
Angelici, R J, and Gao, H. Tue . "Catalyst system comprising a first catalyst system tethered to a supported catalyst". United States.
@article{osti_672674,
title = {Catalyst system comprising a first catalyst system tethered to a supported catalyst},
author = {Angelici, R J and Gao, H},
abstractNote = {The present invention provides new catalyst formats which comprise a supported catalyst tethered to a second and different catalyst by a suitable tethering ligand. A preferred system comprises a heterogeneous supported metal catalyst tethered to a homogeneous catalyst. This combination of homogeneous and heterogeneous catalysts has a sufficient lifetime and unusually high catalytic activity in arene hydrogenations, and potentially many other reactions as well, including, but not limited to hydroformylation, hydrosilication, olefin oxidation, isomerization, hydrocyanidation, olefin metathesis, olefin polymerization, carbonylation, enantioselective catalysis and photoduplication. These catalysts are easily separated from the products, and can be reused repeatedly, making these systems very economical. 2 figs.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1998},
month = {8}
}