Glass capable of ionic conduction and method of preparation

Susman, S; Boehm, L; Volin, K J; Delbecq, C J

Title: Glass capable of ionic conduction and method of preparation

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Abstract

Sulfide glasses capable of conducting alkali metal ions are prepared from a nonmetal glass former such as GeS/sub 2/, B/sub 2/S/sub 2/ and SiS/sub 2/ in mixture with a glass modifier such as Na/sub 2/S or another alkali metal sulfide. A molten mixture of the constituents is rapidly quenched to below the glass transition temperature by contact with a metal mold. The rapid quench is sufficient to prevent crystallization and permit solidification as an amorphous solid mixture. An oxygen-free atmosphere is maintained over the mixture to prevent oxidation. A new glass system of (1 - X) Na/sub 2/O:XB/sub 2/S/sub 3/ is disclosed.

Inventors:: Susman, S; Boehm, L; Volin, K J; Delbecq, C J

Issue Date:: 1982-05-06

OSTI Identifier:: 6312306

Application Number:: ON: DE83010476

Assignee:: ERA-08-029966; EDB-83-086006

DOE Contract Number:: W-31-109-ENG-38

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; SOLID ELECTROLYTES; PRODUCTION; GLASS; IONIC CONDUCTIVITY; SODIUM SULFIDES; SULFIDES; ALKALI METAL COMPOUNDS; CHALCOGENIDES; ELECTRIC CONDUCTIVITY; ELECTRICAL PROPERTIES; ELECTROLYTES; PHYSICAL PROPERTIES; SODIUM COMPOUNDS; SULFUR COMPOUNDS; 360601* - Other Materials- Preparation & Manufacture; 400400 - Electrochemistry

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                    Susman, S, Boehm, L, Volin, K J, and Delbecq, C J. Glass capable of ionic conduction and method of preparation.  United States: N. p., 1982. 
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                    Susman, S, Boehm, L, Volin, K J, & Delbecq, C J. Glass capable of ionic conduction and method of preparation.  United States.

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                    Susman, S, Boehm, L, Volin, K J, and Delbecq, C J. Thu .  
        "Glass capable of ionic conduction and method of preparation".  United States.

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@article{osti_6312306,

  title        = {Glass capable of ionic conduction and method of preparation},

  author       = {Susman, S and Boehm, L and Volin, K J and Delbecq, C J},

  abstractNote = {Sulfide glasses capable of conducting alkali metal ions are prepared from a nonmetal glass former such as GeS/sub 2/, B/sub 2/S/sub 2/ and SiS/sub 2/ in mixture with a glass modifier such as Na/sub 2/S or another alkali metal sulfide. A molten mixture of the constituents is rapidly quenched to below the glass transition temperature by contact with a metal mold. The rapid quench is sufficient to prevent crystallization and permit solidification as an amorphous solid mixture. An oxygen-free atmosphere is maintained over the mixture to prevent oxidation. A new glass system of (1 - X) Na/sub 2/O:XB/sub 2/S/sub 3/ is disclosed.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {1982},

  month        = {5}

}

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