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Title: Cyano- and polycyanometallo-porphyrins as catalysts for alkane oxidation

Abstract

New compositions of matter comprising cyano-substituted metal complexes of porphyrins are catalysts for the oxidation of alkanes. The metal is iron, chromium, manganese, ruthenium, copper or cobalt. The porphyrin ring has cyano groups attached thereto in meso- and/or [beta]-pyrrolic positions.

Inventors:
;
Issue Date:
OSTI Identifier:
6298393
Patent Number(s):
5212300
Application Number:
PPN: US 7-892107
Assignee:
Sun Co., Inc. (R and M), Philadelphia, PA (United States)
DOE Contract Number:  
FC21-90MC26029
Resource Type:
Patent
Resource Relation:
Patent File Date: 2 Jun 1992
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 02 PETROLEUM; ALKANES; OXIDATION; CATALYSTS; CHEMICAL COMPOSITION; PORPHYRINS; CATALYTIC EFFECTS; CHROMIUM COMPLEXES; COBALT COMPLEXES; COPPER COMPLEXES; CYANIDES; IRON COMPLEXES; MANGANESE COMPLEXES; ORGANOMETALLIC COMPOUNDS; RUTHENIUM COMPLEXES; CARBOXYLIC ACIDS; CHEMICAL REACTIONS; COMPLEXES; HETEROCYCLIC ACIDS; HETEROCYCLIC COMPOUNDS; HYDROCARBONS; ORGANIC ACIDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; TRANSITION ELEMENT COMPLEXES; 400201* - Chemical & Physicochemical Properties; 020400 - Petroleum- Processing

Citation Formats

Ellis, Jr, P E, and Lyons, J E. Cyano- and polycyanometallo-porphyrins as catalysts for alkane oxidation. United States: N. p., 1993. Web.
Ellis, Jr, P E, & Lyons, J E. Cyano- and polycyanometallo-porphyrins as catalysts for alkane oxidation. United States.
Ellis, Jr, P E, and Lyons, J E. Tue . "Cyano- and polycyanometallo-porphyrins as catalysts for alkane oxidation". United States.
@article{osti_6298393,
title = {Cyano- and polycyanometallo-porphyrins as catalysts for alkane oxidation},
author = {Ellis, Jr, P E and Lyons, J E},
abstractNote = {New compositions of matter comprising cyano-substituted metal complexes of porphyrins are catalysts for the oxidation of alkanes. The metal is iron, chromium, manganese, ruthenium, copper or cobalt. The porphyrin ring has cyano groups attached thereto in meso- and/or [beta]-pyrrolic positions.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1993},
month = {5}
}