Electrically conductive doped block copolymer of polyacetylene and polyisoprene. [Soluble in organic solvents]

Title: Electrically conductive doped block copolymer of polyacetylene and polyisoprene. [Soluble in organic solvents]

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Abstract

An electrically conductive block copolymer of polyisoprene and polyacetylene and a method of making the same are disclosed. The polymer is prepared by first polymerizing isoprene with n-butyllithium in a toluene solution to form an active isoprenyllithium polymer. The active polymer is reacted with an equimolar amount of titanium butoxide and subsequently exposed to gaseous acetylene. A block copolymer of polyisoprene and polyacetylene is formed. The copolymer is soluble in common solvents and may be doped with I/sub 2/ to give it an electrical conductivity in the metallic regime.

Inventors:: Aldissi, M

Issue Date:: 1984-06-27

OSTI Identifier:: 6255608

Application Number:: ON: TI85006500

Assignee:: Dept. of Energy

DOE Contract Number:: W-7405-ENG-36

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; COPOLYMERS; SYNTHESIS; POLYACETYLENES; POLYISOPRENE; ACETYLENE; ADDITIVES; ELECTRIC CONDUCTIVITY; IODINE; LITHIUM COMPOUNDS; ORGANIC SOLVENTS; ORGANOMETALLIC COMPOUNDS; POLYMERIZATION; SOLUBILITY; ALKALI METAL COMPOUNDS; ALKYNES; CHEMICAL REACTIONS; ELASTOMERS; ELECTRICAL PROPERTIES; ELEMENTS; HALOGENS; HYDROCARBONS; NONMETALS; ORGANIC COMPOUNDS; ORGANIC POLYMERS; PHYSICAL PROPERTIES; POLYENES; POLYMERS; SOLVENTS; 360401* - Polymers & Plastics- Preparation & Fabrication- (-1987)

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                    Aldissi, M. Electrically conductive doped block copolymer of polyacetylene and polyisoprene. [Soluble in organic solvents].  United States: N. p., 1984. 
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                    Aldissi, M. Electrically conductive doped block copolymer of polyacetylene and polyisoprene. [Soluble in organic solvents].  United States.

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                    Aldissi, M. Wed .  
        "Electrically conductive doped block copolymer of polyacetylene and polyisoprene. [Soluble in organic solvents]".  United States.

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@article{osti_6255608,

  title        = {Electrically conductive doped block copolymer of polyacetylene and polyisoprene. [Soluble in organic solvents]},

  author       = {Aldissi, M},

  abstractNote = {An electrically conductive block copolymer of polyisoprene and polyacetylene and a method of making the same are disclosed. The polymer is prepared by first polymerizing isoprene with n-butyllithium in a toluene solution to form an active isoprenyllithium polymer. The active polymer is reacted with an equimolar amount of titanium butoxide and subsequently exposed to gaseous acetylene. A block copolymer of polyisoprene and polyacetylene is formed. The copolymer is soluble in common solvents and may be doped with I/sub 2/ to give it an electrical conductivity in the metallic regime.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {1984},

  month        = {6}

}

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