Method and apparatus for synthesizing HMX and N/sub 2/O/sub 5/. [Patent application; cyclotetramethylenetetraamine]

McGuire, R R; Coon, C L; Harrar, J E; Pearson, R K

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Title: Method and apparatus for synthesizing HMX and N/sub 2/O/sub 5/. [Patent application; cyclotetramethylenetetraamine]

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Abstract

A method and apparatus for electrochemically synthesizing N/sub 2/O/sub 5/ includes oxidizing a solution of N/sub 2/O/sub 4//HNO/sub 3/ at an anode, while maintaining a controlled potential between the N/sub 2/O/sub 4//HNO/sub 3/ solution and the anode. A potential of about 1.35 to 2.0V vs. SCE is preferred, while a potential of about 1.80V vs. SCE is most preferred. Thereafter, the N/sub 2/O/sub 5/ is reacted with either 1.5-diacetyl-3,7-dinitro-1,3,5,7-tetraazacyclooctane (DADN) or 1,3,5,7-tetraacetyl-1,3,5,7-tetraazacyclooctane (TAT) to form cyclotetramethylenetetraamine (HMX).

Inventors:: McGuire, R R; Coon, C L; Harrar, J E; Pearson, R K

Issue Date:: 1982-07-20

OSTI Identifier:: 6204945

Application Number:: ON: DE83013188

Assignee:: ERA-08-036647; EDB-83-112631

DOE Contract Number:: W-7405-ENG-48

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; AMINES; SYNTHESIS; NITROGEN OXIDES; ELECTRIC POTENTIAL; ELECTROCHEMISTRY; NITRIC ACID; NITRO COMPOUNDS; OXIDATION; CHALCOGENIDES; CHEMICAL REACTIONS; CHEMISTRY; HYDROGEN COMPOUNDS; INORGANIC ACIDS; NITROGEN COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; 400201* - Chemical & Physicochemical Properties

Citation Formats


                    McGuire, R R, Coon, C L, Harrar, J E, and Pearson, R K. Method and apparatus for synthesizing HMX and N/sub 2/O/sub 5/. [Patent application; cyclotetramethylenetetraamine].  United States: N. p., 1982. 
        Web.

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                    McGuire, R R, Coon, C L, Harrar, J E, & Pearson, R K. Method and apparatus for synthesizing HMX and N/sub 2/O/sub 5/. [Patent application; cyclotetramethylenetetraamine].  United States.

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                    McGuire, R R, Coon, C L, Harrar, J E, and Pearson, R K. Tue .  
        "Method and apparatus for synthesizing HMX and N/sub 2/O/sub 5/. [Patent application; cyclotetramethylenetetraamine]".  United States.

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@article{osti_6204945,

  title        = {Method and apparatus for synthesizing HMX and N/sub 2/O/sub 5/. [Patent application; cyclotetramethylenetetraamine]},

  author       = {McGuire, R R and Coon, C L and Harrar, J E and Pearson, R K},

  abstractNote = {A method and apparatus for electrochemically synthesizing N/sub 2/O/sub 5/ includes oxidizing a solution of N/sub 2/O/sub 4//HNO/sub 3/ at an anode, while maintaining a controlled potential between the N/sub 2/O/sub 4//HNO/sub 3/ solution and the anode. A potential of about 1.35 to 2.0V vs. SCE is preferred, while a potential of about 1.80V vs. SCE is most preferred. Thereafter, the N/sub 2/O/sub 5/ is reacted with either 1.5-diacetyl-3,7-dinitro-1,3,5,7-tetraazacyclooctane (DADN) or 1,3,5,7-tetraacetyl-1,3,5,7-tetraazacyclooctane (TAT) to form cyclotetramethylenetetraamine (HMX).},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {1982},

  month        = {7}

}

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