Alkene epoxidation employing metal nitro complexes
Abstract
Process for converting alkenes to form epoxides utilizes transition metal nitro complexes of the formula: M(RCN)/sub 2/XNO/sub 2/ wherein M is palladium or platinum, R is an alkyl or aryl group containing up to 12 carbon atoms, and X is a monoanionic, monodentate ligand such as chlorine, optionally in the presence of molecular oxygen.
- Inventors:
- Issue Date:
- OSTI Identifier:
- 6011643
- Application Number:
- ON: DE83013191
- Assignee:
- ERA-08-036678; EDB-83-112748
- DOE Contract Number:
- AC02-76CH00016
- Resource Type:
- Patent
- Resource Relation:
- Other Information: Portions are illegible in microfiche products
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ALKENES; CHEMICAL REACTIONS; EPOXIDES; CHEMICAL PREPARATION; NITRO COMPOUNDS; HYDROCARBONS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; SYNTHESIS; 400301* - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)
Citation Formats
Andrews, M A, Cheng, C W, and Kelley, K P. Alkene epoxidation employing metal nitro complexes. United States: N. p., 1982.
Web.
Andrews, M A, Cheng, C W, & Kelley, K P. Alkene epoxidation employing metal nitro complexes. United States.
Andrews, M A, Cheng, C W, and Kelley, K P. Thu .
"Alkene epoxidation employing metal nitro complexes". United States.
@article{osti_6011643,
title = {Alkene epoxidation employing metal nitro complexes},
author = {Andrews, M A and Cheng, C W and Kelley, K P},
abstractNote = {Process for converting alkenes to form epoxides utilizes transition metal nitro complexes of the formula: M(RCN)/sub 2/XNO/sub 2/ wherein M is palladium or platinum, R is an alkyl or aryl group containing up to 12 carbon atoms, and X is a monoanionic, monodentate ligand such as chlorine, optionally in the presence of molecular oxygen.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1982},
month = {7}
}