Method for quantitative determination and separation of trace amounts of chemical elements in the presence of large quantities of other elements having the same atomic mass
Abstract
Photoionization via autoionizing atomic levels combined with conventional mass spectroscopy provides a technique for quantitative analysis of trace quantities of chemical elements in the presence of much larger amounts of other elements with substantially the same atomic mass. Ytterbium samples smaller than 10 ng have been detected using an ArF* excimer laser which provides the atomic ions for a time-of-flight mass spectrometer. Elemental selectivity of greater than 5:1 with respect to lutetium impurity has been obtained. Autoionization via a single photon process permits greater photon utilization efficiency because of its greater absorption cross section than bound-free transitions, while maintaining sufficient spectroscopic structure to allow significant photoionization selectivity between different atomic species. Separation of atomic species from others of substantially the same atomic mass is also described.
- Inventors:
- Issue Date:
- OSTI Identifier:
- 5826653
- Application Number:
- ON: DE83018088
- Assignee:
- ERA-08-054304; EDB-83-177861
- DOE Contract Number:
- W-7405-ENG-36
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; LASER SPECTROSCOPY; MASS SPECTROSCOPY; PHOTOIONIZATION; YTTERBIUM; ELEMENTS; ISOTOPE RATIO; TRACE AMOUNTS; IONIZATION; METALS; RARE EARTHS; SPECTROSCOPY; 400104* - Spectral Procedures- (-1987)
Citation Formats
Miller, C M, and Nogar, N S. Method for quantitative determination and separation of trace amounts of chemical elements in the presence of large quantities of other elements having the same atomic mass. United States: N. p., 1982.
Web.
Miller, C M, & Nogar, N S. Method for quantitative determination and separation of trace amounts of chemical elements in the presence of large quantities of other elements having the same atomic mass. United States.
Miller, C M, and Nogar, N S. Thu .
"Method for quantitative determination and separation of trace amounts of chemical elements in the presence of large quantities of other elements having the same atomic mass". United States.
@article{osti_5826653,
title = {Method for quantitative determination and separation of trace amounts of chemical elements in the presence of large quantities of other elements having the same atomic mass},
author = {Miller, C M and Nogar, N S},
abstractNote = {Photoionization via autoionizing atomic levels combined with conventional mass spectroscopy provides a technique for quantitative analysis of trace quantities of chemical elements in the presence of much larger amounts of other elements with substantially the same atomic mass. Ytterbium samples smaller than 10 ng have been detected using an ArF* excimer laser which provides the atomic ions for a time-of-flight mass spectrometer. Elemental selectivity of greater than 5:1 with respect to lutetium impurity has been obtained. Autoionization via a single photon process permits greater photon utilization efficiency because of its greater absorption cross section than bound-free transitions, while maintaining sufficient spectroscopic structure to allow significant photoionization selectivity between different atomic species. Separation of atomic species from others of substantially the same atomic mass is also described.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1982},
month = {9}
}