Method for making block siloxane copolymers
Abstract
A method for synthesizing block polysiloxane copolymers is disclosed. Diorganoscyclosiloxanes and an end-blocking compound are interacted in the presence of a ring opening polymerization catalyst, producing a blocked prepolymer. The prepolymer is then interacted with a silanediol, resulting in condensation polymerization of the prepolymers. A second end-blocking compound is subsequently introduced to end-cap the polymers and copolymers formed from the condensation polymerization.
- Inventors:
- Issue Date:
- OSTI Identifier:
- 5742673
- Application Number:
- ON: DE82004528
- Assignee:
- Dept. of Energy
- DOE Contract Number:
- W-7405-ENG-48
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; SILOXANES; SYNTHESIS; COPOLYMERS; POLYMERIZATION; CHEMICAL REACTIONS; ORGANIC COMPOUNDS; ORGANIC POLYMERS; POLYMERS; 360400* - Polymers & Plastics- (-1987)
Citation Formats
Butler, N L, Jessop, E S, and Kolb, J R. Method for making block siloxane copolymers. United States: N. p., 1981.
Web.
Butler, N L, Jessop, E S, & Kolb, J R. Method for making block siloxane copolymers. United States.
Butler, N L, Jessop, E S, and Kolb, J R. Wed .
"Method for making block siloxane copolymers". United States.
@article{osti_5742673,
title = {Method for making block siloxane copolymers},
author = {Butler, N L and Jessop, E S and Kolb, J R},
abstractNote = {A method for synthesizing block polysiloxane copolymers is disclosed. Diorganoscyclosiloxanes and an end-blocking compound are interacted in the presence of a ring opening polymerization catalyst, producing a blocked prepolymer. The prepolymer is then interacted with a silanediol, resulting in condensation polymerization of the prepolymers. A second end-blocking compound is subsequently introduced to end-cap the polymers and copolymers formed from the condensation polymerization.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Wed Feb 25 00:00:00 EST 1981},
month = {Wed Feb 25 00:00:00 EST 1981}
}
