Preparation of 1,1'-dinitro-3,3'-azo-1,2,4-triazole. [1,1'-dinitro-3,3'-azo-1,2,4-triazole]

Title: Preparation of 1,1'-dinitro-3,3'-azo-1,2,4-triazole. [1,1'-dinitro-3,3'-azo-1,2,4-triazole]

Full Record
Other Related Research

Abstract

A new high density composition of matter, 1,1'-dinitro-3,3'-azo-1,2,4-triazole, has been synthesized using inexpensive, commonly available compounds. This compound has been found to be an explosive, and its use as a propellant is anticipated. 1 fig., 1 tab.

Inventors:: Lee, K Y

Issue Date:: 1985-03-05

Research Org.:: Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

OSTI Identifier:: 5432844

Application Number:: ON: DE86013784

Assignee:: Dept. of Energy

DOE Contract Number:: W-7405-ENG-36

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: 45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEFENSE; CHEMICAL EXPLOSIVES; CHEMICAL PREPARATION; DENSITY; MOLECULAR WEIGHT; AZOLES; EXPERIMENTAL DATA; NITRO COMPOUNDS; OXIDATION; POTASSIUM PERMANGANATES; ALKALI METAL COMPOUNDS; CHEMICAL REACTIONS; DATA; EXPLOSIVES; HETEROCYCLIC COMPOUNDS; INFORMATION; MANGANESE COMPOUNDS; NUMERICAL DATA; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; OXYGEN COMPOUNDS; PERMANGANATES; PHYSICAL PROPERTIES; POTASSIUM COMPOUNDS; SYNTHESIS; TRANSITION ELEMENT COMPOUNDS; 450100* - Military Technology, Weaponry, & National Defense- Chemical Explosions & Explosives

Citation Formats


                    Lee, K Y. Preparation of 1,1'-dinitro-3,3'-azo-1,2,4-triazole. [1,1'-dinitro-3,3'-azo-1,2,4-triazole].  United States: N. p., 1985. 
        Web.

Copy to clipboard


                    Lee, K Y. Preparation of 1,1'-dinitro-3,3'-azo-1,2,4-triazole. [1,1'-dinitro-3,3'-azo-1,2,4-triazole].  United States.

Copy to clipboard


                    Lee, K Y. Tue .  
        "Preparation of 1,1'-dinitro-3,3'-azo-1,2,4-triazole. [1,1'-dinitro-3,3'-azo-1,2,4-triazole]".  United States.

Copy to clipboard


                    
@article{osti_5432844,

  title        = {Preparation of 1,1'-dinitro-3,3'-azo-1,2,4-triazole. [1,1'-dinitro-3,3'-azo-1,2,4-triazole]},

  author       = {Lee, K Y},

  abstractNote = {A new high density composition of matter, 1,1'-dinitro-3,3'-azo-1,2,4-triazole, has been synthesized using inexpensive, commonly available compounds. This compound has been found to be an explosive, and its use as a propellant is anticipated. 1 fig., 1 tab.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {1985},

  month        = {3}

}

Copy to clipboard

Patent:

Search for the full text at the U.S. Patent and Trademark Office

Save / Share:

Export Metadata

Save to My Library

Similar Records in DOE Patents and OSTI.GOV collections:

Preparation of 1,1'-dinitro-3,3'-azo-1,2,4-triazole

Patent Lee, Kien-Yin [Los Alamos, NM]

A new high density composition of matter, 1,1'-dinitro-3,3'-azo-1,2,4-triazole, has been synthesized using inexpensive, commonly available compounds. This compound has been found to be an explosive, and its use as a propellant is anticipated.
Full Text Available
Synthesis of 1,1'-dinitro-3,3'-azo-1,2,4-triazole

Technical Report Lee, K Y

A novel compound has been prepared and is a candidate for high-energy propellant applications. The 1,1'-dinitro-3,3'-azo-1,2,4-triazole (N-DNAT) has a density of 1.77 g/cm/sup 3/ and can be prepared from inexpensive starting materials.
Production of the ammonium salt of 3,5-dinitro-1,2,4-triazole by solvent extraction

Patent Lee, K Y; Ott, D G

The ammonium salt of 3,5-dinitro-1,2,4-triazole has utility as a chemical explosive. In accordance with the present invention, it may readily be produced by solvent extraction using high-molecular weight, water-insoluble amines, followed by amination with anhydrous ammonia gas. The aqueous reaction mixture produced in the synthesis of the parent compound, 3,5-dinitro-1,2,4-triazole, is quite suitable - and indeed is preferred - for use as the feed material in the process of the invention.
Production of the ammonium salt of 3,5-dinitro-1,2,4-triazole by solvent extraction

Patent Lee, Kien Y [Los Alamos, NM]; Ott, Donald G [Los Alamos, NM]

The ammonium salt of 3,5-dinitro-1,2,4-triazole has utility as a chemical explosive. In accordance with the present invention, it may readily be produced by solvent extraction using high-molecular weight, water-insoluble amines followed by amination with anhydrous ammonia gas. The aqueous reaction mixture produced in the synthesis of the parent compound, 3,5-dinitro-1,2,4-triazole, is quite suitable--and indeed is preferred--for use as the feed material in the process of the invention.
Full Text Available
Vicarious nucleophilic substitution using 4-amino-1,2,4-triazole, hydroxylamine or O-alkylhydroxylamine to prepare 1,3-diamino-2,4,6-trinitrobenzene or 1,3,5-triamino-2,4,6-trinitrobenzene

Patent Mitchell, A R; Pagoria, P F; Schmidt, R D

The present invention relates to a process to produce 1,3-diamino-2,4,6-trinitrobenzene (DATB) or 1,3,5-triamino-2,4,6,trinitrobenzene (TATB) by: (a) reacting at ambient pressure and a temperature of between about 0 and 50 C for between about 0.1 and 24 hr, a trinitroaromatic compound of the structure shown where X, Y, and Z are each independently selected from the group consisting of -H and -NH{sub 2}, with the proviso that at least 1 or 2 of X, Y, and Z are hydrogen; with an effective amount of 1-amino-1,2,4-triazole, hydroxylamine or O-alkylhydroxamine to produce DATB or TATB; in the presence of a strong base selectedmore »« less

Similar Records