Super ionic conductive glass
Abstract
Described is an ionically conducting glass for use as a solid electrolyte in a power or secondary cell containing an alkali metal-containing anode and a cathode separated by an alkali metal ion conducting glass having an ionic transference number of unity and the general formula: A/sub 1 + x/D/sub 2-x/3/Si/sub x/P/sub 3 - x/O/sub 12 - 2x/3/, wherein A is a network modifier for the glass and is an alkali metal of the anode, D is an intermediate for the glass and is selected from the class consisting of Zr, Ti, Ge, Al, Sb, Be, and Zn and X is in the range of from 2.25 to 3.0. Of the alkali metals, Na and Li are preferred and of the intermediate, Zr, Ti and Ge are preferred.
- Inventors:
- OSTI Identifier:
- 5317310
- Application Number:
- ON: DE84005928
- Assignee:
- ERA-09-012422; EDB-84-037039
- DOE Contract Number:
- W-31-109-ENG-38
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; GLASS; IONIC CONDUCTIVITY; SOLID ELECTROLYTES; PHOSPHATES; SILICATES; SODIUM COMPOUNDS; ZIRCONIUM COMPOUNDS; ALKALI METAL COMPOUNDS; ELECTRIC CONDUCTIVITY; ELECTRICAL PROPERTIES; ELECTROLYTES; OXYGEN COMPOUNDS; PHOSPHORUS COMPOUNDS; PHYSICAL PROPERTIES; SILICON COMPOUNDS; TRANSITION ELEMENT COMPOUNDS; 400400* - Electrochemistry
Citation Formats
Susman, S., and Volin, K.J. Super ionic conductive glass. United States: N. p.,
Web.
Susman, S., & Volin, K.J. Super ionic conductive glass. United States.
Susman, S., and Volin, K.J. .
"Super ionic conductive glass". United States.
@article{osti_5317310,
title = {Super ionic conductive glass},
author = {Susman, S. and Volin, K.J.},
abstractNote = {Described is an ionically conducting glass for use as a solid electrolyte in a power or secondary cell containing an alkali metal-containing anode and a cathode separated by an alkali metal ion conducting glass having an ionic transference number of unity and the general formula: A/sub 1 + x/D/sub 2-x/3/Si/sub x/P/sub 3 - x/O/sub 12 - 2x/3/, wherein A is a network modifier for the glass and is an alkali metal of the anode, D is an intermediate for the glass and is selected from the class consisting of Zr, Ti, Ge, Al, Sb, Be, and Zn and X is in the range of from 2.25 to 3.0. Of the alkali metals, Na and Li are preferred and of the intermediate, Zr, Ti and Ge are preferred.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {},
month = {}
}
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