Apparatus and method for the preparation of dioxygen difluoride

Title: Apparatus and method for the preparation of dioxygen difluoride

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Abstract

Dioxygen difluoride, O/sub 2/F/sub 2/, is prepared in high yield by microwave discharge of a flowing gas mixture of F/sub 2/ with or without a carrier gas such as argon or helium with the subsequent reaction of the discharge products with molecular gaseous oxygen downstream from and outside of the region of discharge. The O/sub 2/F/sub 2/ product is collected by cryogenic trapping, and is free of oxygen difluoride impurity and ozone since the oxygen molecules are not dissociated before they react with the microwave discharge products.

Inventors:: Beattie, W H

Issue Date:: 1985-01-30

Research Org.:: Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

OSTI Identifier:: 5272849

Application Number:: ON: DE85017787

Assignee:: Dept. of Energy

DOE Contract Number:: W-7405-ENG-36

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; FLUORINE OXIDES; CHEMICAL PREPARATION; HIGH-FREQUENCY DISCHARGES; MICROWAVE RADIATION; CHALCOGENIDES; ELECTRIC DISCHARGES; ELECTROMAGNETIC RADIATION; FLUORINE COMPOUNDS; HALOGEN COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; RADIATIONS; SYNTHESIS; 400200* - Inorganic, Organic, & Physical Chemistry

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                    Beattie, W H. Apparatus and method for the preparation of dioxygen difluoride.  United States: N. p., 1985. 
        Web.

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                    Beattie, W H. Apparatus and method for the preparation of dioxygen difluoride.  United States.

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                    Beattie, W H. Wed .  
        "Apparatus and method for the preparation of dioxygen difluoride".  United States.

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@article{osti_5272849,

  title        = {Apparatus and method for the preparation of dioxygen difluoride},

  author       = {Beattie, W H},

  abstractNote = {Dioxygen difluoride, O/sub 2/F/sub 2/, is prepared in high yield by microwave discharge of a flowing gas mixture of F/sub 2/ with or without a carrier gas such as argon or helium with the subsequent reaction of the discharge products with molecular gaseous oxygen downstream from and outside of the region of discharge. The O/sub 2/F/sub 2/ product is collected by cryogenic trapping, and is free of oxygen difluoride impurity and ozone since the oxygen molecules are not dissociated before they react with the microwave discharge products.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {1985},

  month        = {1}

}

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