Halogenation of cobalt dicarbollide
Abstract
A method for selectively adding chlorine, bromine, or iodine to cobalt dicarbollide anions by means of electrophilic substitution reactions. Halogens are added only to the B10 and B10{prime} positions of the anion. The process involves use of hypohalous acid or N-halosuccinimide or gaseous chlorine in the presence of iron. 1 fig.
- Inventors:
- Issue Date:
- Research Org.:
- Univ. of California (United States)
- Sponsoring Org.:
- USDOE, Washington, DC (United States)
- OSTI Identifier:
- 489090
- Patent Number(s):
- 5631390
- Application Number:
- PAN: 8-455,372
- Assignee:
- Univ. of California, Alameda, CA (United States)
- DOE Contract Number:
- W-7405-ENG-36
- Resource Type:
- Patent
- Resource Relation:
- Other Information: PBD: 20 May 1997
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 40 CHEMISTRY; COBALT COMPOUNDS; HALOGENATION; CHLORINATION; BROMINATION; IODINATION; INORGANIC ACIDS; POWDER METALLURGY
Citation Formats
Hurlburt, P K, Abney, K D, and Kinkead, S A. Halogenation of cobalt dicarbollide. United States: N. p., 1997.
Web.
Hurlburt, P K, Abney, K D, & Kinkead, S A. Halogenation of cobalt dicarbollide. United States.
Hurlburt, P K, Abney, K D, and Kinkead, S A. Tue .
"Halogenation of cobalt dicarbollide". United States.
@article{osti_489090,
title = {Halogenation of cobalt dicarbollide},
author = {Hurlburt, P K and Abney, K D and Kinkead, S A},
abstractNote = {A method for selectively adding chlorine, bromine, or iodine to cobalt dicarbollide anions by means of electrophilic substitution reactions. Halogens are added only to the B10 and B10{prime} positions of the anion. The process involves use of hypohalous acid or N-halosuccinimide or gaseous chlorine in the presence of iron. 1 fig.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1997},
month = {5}
}
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