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Title: Halogenation of cobalt dicarbollide

Abstract

A method for selectively adding chlorine, bromine, or iodine to cobalt dicarbollide anions by means of electrophilic substitution reactions. Halogens are added only to the B10 and B10{prime} positions of the anion. The process involves use of hypohalous acid or N-halosuccinimide or gaseous chlorine in the presence of iron. 1 fig.

Inventors:
; ;
Issue Date:
Research Org.:
University of California
Sponsoring Org.:
USDOE, Washington, DC (United States)
OSTI Identifier:
489090
Patent Number(s):
5,631,390
Application Number:
PAN: 8-455,372
Assignee:
Univ. of California, Alameda, CA (United States) PTO; SCA: 400201; PA: EDB-97:086421; SN: 97001799053
DOE Contract Number:  
W-7405-ENG-36
Resource Type:
Patent
Resource Relation:
Other Information: PBD: 20 May 1997
Country of Publication:
United States
Language:
English
Subject:
40 CHEMISTRY; COBALT COMPOUNDS; HALOGENATION; CHLORINATION; BROMINATION; IODINATION; INORGANIC ACIDS; POWDER METALLURGY

Citation Formats

Hurlburt, P.K., Abney, K.D., and Kinkead, S.A. Halogenation of cobalt dicarbollide. United States: N. p., 1997. Web.
Hurlburt, P.K., Abney, K.D., & Kinkead, S.A. Halogenation of cobalt dicarbollide. United States.
Hurlburt, P.K., Abney, K.D., and Kinkead, S.A. Tue . "Halogenation of cobalt dicarbollide". United States.
@article{osti_489090,
title = {Halogenation of cobalt dicarbollide},
author = {Hurlburt, P.K. and Abney, K.D. and Kinkead, S.A.},
abstractNote = {A method for selectively adding chlorine, bromine, or iodine to cobalt dicarbollide anions by means of electrophilic substitution reactions. Halogens are added only to the B10 and B10{prime} positions of the anion. The process involves use of hypohalous acid or N-halosuccinimide or gaseous chlorine in the presence of iron. 1 fig.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1997},
month = {5}
}