Hydridosiloxanes as precursors to ceramic products
Abstract
A method is provided for preparing ceramic precursors from hydridosiloxane starting materials and then pyrolyzing these precursors to give rise to silicious ceramic materials. Si-H bonds present in the hydridosiloxane starting materials are catalytically activated, and the activated hydrogen atoms may then be replaced with nonhydrogen substituents. These preceramic materials are pyrolyzed in a selected atmosphere to give the desired ceramic product. Ceramic products which may be prepared by this technique include silica, silicon oxynitride, silicon carbide, metal silicates, and mullite.
- Inventors:
- Issue Date:
- Sponsoring Org.:
- USDOE, Washington, DC (United States)
- OSTI Identifier:
- 489083
- Patent Number(s):
- 5635250
- Application Number:
- PAN: 8-437,722
- Assignee:
- SRI International, Menlo Park, CA (United States)
- Resource Type:
- Patent
- Resource Relation:
- Other Information: PBD: 3 Jun 1997
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 40 CHEMISTRY; 36 MATERIALS SCIENCE; PRECURSOR; CERAMICS; CHEMICAL PREPARATION; SILOXANES; PYROLYSIS; SILICON OXIDES; SILICON NITRIDES; SILICON CARBIDES; SILICATES; MULLITE; CHEMICAL ACTIVATION
Citation Formats
Blum, Y D, Johnson, S M, and Gusman, M I. Hydridosiloxanes as precursors to ceramic products. United States: N. p., 1997.
Web.
Blum, Y D, Johnson, S M, & Gusman, M I. Hydridosiloxanes as precursors to ceramic products. United States.
Blum, Y D, Johnson, S M, and Gusman, M I. Tue .
"Hydridosiloxanes as precursors to ceramic products". United States.
@article{osti_489083,
title = {Hydridosiloxanes as precursors to ceramic products},
author = {Blum, Y D and Johnson, S M and Gusman, M I},
abstractNote = {A method is provided for preparing ceramic precursors from hydridosiloxane starting materials and then pyrolyzing these precursors to give rise to silicious ceramic materials. Si-H bonds present in the hydridosiloxane starting materials are catalytically activated, and the activated hydrogen atoms may then be replaced with nonhydrogen substituents. These preceramic materials are pyrolyzed in a selected atmosphere to give the desired ceramic product. Ceramic products which may be prepared by this technique include silica, silicon oxynitride, silicon carbide, metal silicates, and mullite.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1997},
month = {6}
}
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