Separation of Californium from other Actinides
Abstract
A method is provided for separating californium from a fused fluoride composition containing californium and at least one element selected from the group consisting of plutonium, americium, curium, uranium, thorium, and protactinium which comprises contacting said fluoride composition with a liquid bismuth phase containing sufficient lithium or thorium to effect transfer of said actinides to the bismuth phase and then contacting the liquid bismuth phase with molten LiCl to effect selective transfer of californium to the chloride phase.
- Inventors:
- Issue Date:
- Research Org.:
- Originating Research Org. not identified
- OSTI Identifier:
- 4441686
- Patent Number(s):
- 3761564
- Assignee:
- United States Atomic Energy Commission
- Patent Classifications (CPCs):
-
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01G - COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
C - CHEMISTRY C22 - METALLURGY C22B - PRODUCTION AND REFINING OF METALS
- NSA Number:
- NSA-28-029770
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 1972 Jan 24; Other Information: C01g56/00. Orig. Receipt Date: 31-DEC-73
- Country of Publication:
- United States
- Language:
- English
- Subject:
- N40440* -Chemistry-Radiochemistry & Nuclear Chemistry- Radioisotope Production; N40450 -Chemistry-Radiochemistry & Nuclear Chemistry-Reactor Fuel Processing; *AMERICIUM- SEPARATION PROCESSES; *CALIFORNIUM- ISOTOPE PRODUCTION; *CURIUM- SEPARATION PROCESSES; *PLUTONIUM- SEPARATION PROCESSES; *PROTACTINIUM- SEPARATION PROCESSES; *THORIUM- SEPARATION PROCESSES; *URANIUM- SEPARATION PROCESSES; FLUORIDES; LIQUID METALS; LITHIUM CHLORIDES; MOLTEN SALTS; NUCLEAR FUELS; PATENTS; REPROCESSING ISOTOPE PRODUCTION
Citation Formats
Mailen, J C, and Ferris, L M. Separation of Californium from other Actinides. United States: N. p., 1973.
Web.
Mailen, J C, & Ferris, L M. Separation of Californium from other Actinides. United States.
Mailen, J C, and Ferris, L M. Tue .
"Separation of Californium from other Actinides". United States. https://www.osti.gov/servlets/purl/4441686.
@article{osti_4441686,
title = {Separation of Californium from other Actinides},
author = {Mailen, J C and Ferris, L M},
abstractNote = {A method is provided for separating californium from a fused fluoride composition containing californium and at least one element selected from the group consisting of plutonium, americium, curium, uranium, thorium, and protactinium which comprises contacting said fluoride composition with a liquid bismuth phase containing sufficient lithium or thorium to effect transfer of said actinides to the bismuth phase and then contacting the liquid bismuth phase with molten LiCl to effect selective transfer of californium to the chloride phase.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Sep 25 00:00:00 EDT 1973},
month = {Tue Sep 25 00:00:00 EDT 1973}
}