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Title: SEPARATION PROCESS FOR TRANSURANIC ELEMENT AND COMPOUNDS THEREOF

Abstract

S> A process is presented for the separation of pluto nium from uranium and fission products in an aqueous acidic solution by use of a chelating agent. The plutonium is maintained in the tetravalent state and the uranium in the hexavalent state, and the acidic concentration is adjusted to about 1 N bar. The aqueous solution is then contacted with a water-immiscible organic solvent solution and the chelating agent. The chelating agents covered by this invention comprise a group of compounds characterized as fluorinated beta-diketones.

Inventors:
Issue Date:
Research Org.:
Originating Research Org. not identified
OSTI Identifier:
4247484
Patent Number(s):
2856418
Assignee:
U.S. Atomic Energy Commission
Patent Classifications (CPCs):
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01G - COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
G - PHYSICS G21 - NUCLEAR PHYSICS G21C - NUCLEAR REACTORS
NSA Number:
NSA-13-008367
Resource Type:
Patent
Resource Relation:
Other Information: Orig. Receipt Date: 31-DEC-59
Country of Publication:
United States
Language:
English
Subject:
PATENTS; ACIDITY; ACIDS; ACTINIDES; CHELATES; FISSION PRODUCTS; KETONES; ORGANIC COMPOUNDS; ORGANIC FLUORINE COMPOUNDS; PLUTONIUM; QUANTITY RATIO; SEPARATION PROCESSES; SOLUTIONS; SOLVENTS; URANIUM; WATER

Citation Formats

Calvin, M. SEPARATION PROCESS FOR TRANSURANIC ELEMENT AND COMPOUNDS THEREOF. United States: N. p., 1958. Web.
Calvin, M. SEPARATION PROCESS FOR TRANSURANIC ELEMENT AND COMPOUNDS THEREOF. United States.
Calvin, M. Tue . "SEPARATION PROCESS FOR TRANSURANIC ELEMENT AND COMPOUNDS THEREOF". United States.
@article{osti_4247484,
title = {SEPARATION PROCESS FOR TRANSURANIC ELEMENT AND COMPOUNDS THEREOF},
author = {Calvin, M},
abstractNote = {S> A process is presented for the separation of pluto nium from uranium and fission products in an aqueous acidic solution by use of a chelating agent. The plutonium is maintained in the tetravalent state and the uranium in the hexavalent state, and the acidic concentration is adjusted to about 1 N bar. The aqueous solution is then contacted with a water-immiscible organic solvent solution and the chelating agent. The chelating agents covered by this invention comprise a group of compounds characterized as fluorinated beta-diketones.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1958},
month = {10}
}

Patent:
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