SEPARATION OF THORIUM FROM URANIUM BY EXTRACTION
Abstract
A method is presented for the recovery and separation of uranium and thorium values contained in an aqueous nitric acid solution which is more than 3 M in nitric acid. The uranium and thorium containing solution preferable about 7 M in nitric acid is contacted with tributyl phosphatekerosene mixture. Both U and Th are extracted by the immiscible organic. After phase separation the Th is selectively back extracted by contacting with an aqueous nitric acid solution preferably between 0.1 to 1.5 M in nitric acid. The uranium which is still in the organic extractant phase may be recovered by contacting with water.
- Inventors:
- Issue Date:
- OSTI Identifier:
- 4235978
- Patent Number(s):
- 2897046
- Assignee:
- U.S. Atomic Energy Commission
- Patent Classifications (CPCs):
-
C - CHEMISTRY C22 - METALLURGY C22B - PRODUCTION AND REFINING OF METALS
- NSA Number:
- NSA-14-002500
- Resource Type:
- Patent
- Resource Relation:
- Other Information: Orig. Receipt Date: 31-DEC-60
- Country of Publication:
- United States
- Language:
- English
- Subject:
- CHEMISTRY; BUTYL PHOSPHATES; HYDROCARBONS; NITRIC ACID; RECOVERY; SEPARATION PROCESSES; SOLUTIONS; SOLVENT EXTRACTION; THORIUM; URANIUM; WATER
Citation Formats
Bohlmann, E G. SEPARATION OF THORIUM FROM URANIUM BY EXTRACTION. United States: N. p., 1959.
Web.
Bohlmann, E G. SEPARATION OF THORIUM FROM URANIUM BY EXTRACTION. United States.
Bohlmann, E G. Tue .
"SEPARATION OF THORIUM FROM URANIUM BY EXTRACTION". United States.
@article{osti_4235978,
title = {SEPARATION OF THORIUM FROM URANIUM BY EXTRACTION},
author = {Bohlmann, E G},
abstractNote = {A method is presented for the recovery and separation of uranium and thorium values contained in an aqueous nitric acid solution which is more than 3 M in nitric acid. The uranium and thorium containing solution preferable about 7 M in nitric acid is contacted with tributyl phosphatekerosene mixture. Both U and Th are extracted by the immiscible organic. After phase separation the Th is selectively back extracted by contacting with an aqueous nitric acid solution preferably between 0.1 to 1.5 M in nitric acid. The uranium which is still in the organic extractant phase may be recovered by contacting with water.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1959},
month = {7}
}