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Title: ADSORPTION METHOD FOR SEPARATING THORIUM VALUES FROM URANIUM VALUES

Abstract

An improved ion exchange method is described for recovery of uranium and thorium values as separate functions from an aqueous acidic solution containing less than 10/sup -3/ M thorium ions and between 0.1 and 1 M uranyl ions. The solution is passed through a bed of cation exchange resin in the acid form to adsorb all the thorium ions and a portion of the uranyl ions. The uranium is eluted by means of aqueous 0.1 to 0.4 M sulfuric acid. The thorium may then be stripped from the resin by elution with aqueous 0.5 M oxalic acid.

Inventors:
; ;
Issue Date:
Research Org.:
Originating Research Org. not identified
OSTI Identifier:
4235976
Patent Number(s):
2898185
Assignee:
U.S. Atomic Energy Commission
Patent Classifications (CPCs):
C - CHEMISTRY C22 - METALLURGY C22B - PRODUCTION AND REFINING OF METALS
G - PHYSICS G21 - NUCLEAR PHYSICS G21C - NUCLEAR REACTORS
NSA Number:
NSA-14-002503
Resource Type:
Patent
Resource Relation:
Other Information: Orig. Receipt Date: 31-DEC-60
Country of Publication:
United States
Language:
English
Subject:
CHEMISTRY; ACIDS; ADSORPTION; CATIONS; ION EXCHANGE; IONS; OXALIC ACID; RECOVERY; RESINS; SEPARATION PROCESSES; SOLUTIONS; SULFURIC ACID; THORIUM; THORIUM COMPOUNDS; URANIUM; URANYL COMPOUNDS; WATER

Citation Formats

Boyd, G E, Russell, E R, and Schubert, J. ADSORPTION METHOD FOR SEPARATING THORIUM VALUES FROM URANIUM VALUES. United States: N. p., 1959. Web.
Boyd, G E, Russell, E R, & Schubert, J. ADSORPTION METHOD FOR SEPARATING THORIUM VALUES FROM URANIUM VALUES. United States.
Boyd, G E, Russell, E R, and Schubert, J. Sat . "ADSORPTION METHOD FOR SEPARATING THORIUM VALUES FROM URANIUM VALUES". United States.
@article{osti_4235976,
title = {ADSORPTION METHOD FOR SEPARATING THORIUM VALUES FROM URANIUM VALUES},
author = {Boyd, G E and Russell, E R and Schubert, J},
abstractNote = {An improved ion exchange method is described for recovery of uranium and thorium values as separate functions from an aqueous acidic solution containing less than 10/sup -3/ M thorium ions and between 0.1 and 1 M uranyl ions. The solution is passed through a bed of cation exchange resin in the acid form to adsorb all the thorium ions and a portion of the uranyl ions. The uranium is eluted by means of aqueous 0.1 to 0.4 M sulfuric acid. The thorium may then be stripped from the resin by elution with aqueous 0.5 M oxalic acid.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1959},
month = {8}
}

Patent:
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