Propenyl ether monomers for photopolymerization
Abstract
Propenyl ether monomers of formula A(OCH{double_bond}CHCH{sub 3}){sub n} wherein n is an integer from one to six and A is selected from cyclic ethers, polyether and alkanes are disclosed. The monomers are readily polymerized in the presence of cationic photoinitiators, when exposed to actinic radiation, to form poly(propenyl ethers) that are useful for coatings, sealants, varnishes and adhesives. Compositions for preparing polymeric coatings comprising the compounds of the above formula together with particular cationic photoinitiators are also disclosed, as are processes for making the monomers from allyl halides and readily available alcohols. The process involves rearranging the resulting allyl ethers to propenyl ethers.
- Inventors:
- Issue Date:
- Research Org.:
- Rensselaer Polytechnic Inst
- OSTI Identifier:
- 392639
- Patent Number(s):
- 5567858
- Application Number:
- PAN: 8-571,200
- Assignee:
- Rensselaer Polytechnic Inst., Troy, NY (United States)
- DOE Contract Number:
- FG02-91ER12117
- Resource Type:
- Patent
- Resource Relation:
- Other Information: PBD: 22 Oct 1996
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 40 CHEMISTRY; POLYETHYLENE GLYCOLS; POLYMERIZATION; ALKANES; ETHERS; COATINGS; SYNTHESIS; SEALING MATERIALS; ADHESIVES; PHOTOCHEMICAL REACTIONS; MOLECULAR STRUCTURE
Citation Formats
Crivello, J V. Propenyl ether monomers for photopolymerization. United States: N. p., 1996.
Web.
Crivello, J V. Propenyl ether monomers for photopolymerization. United States.
Crivello, J V. Tue .
"Propenyl ether monomers for photopolymerization". United States.
@article{osti_392639,
title = {Propenyl ether monomers for photopolymerization},
author = {Crivello, J V},
abstractNote = {Propenyl ether monomers of formula A(OCH{double_bond}CHCH{sub 3}){sub n} wherein n is an integer from one to six and A is selected from cyclic ethers, polyether and alkanes are disclosed. The monomers are readily polymerized in the presence of cationic photoinitiators, when exposed to actinic radiation, to form poly(propenyl ethers) that are useful for coatings, sealants, varnishes and adhesives. Compositions for preparing polymeric coatings comprising the compounds of the above formula together with particular cationic photoinitiators are also disclosed, as are processes for making the monomers from allyl halides and readily available alcohols. The process involves rearranging the resulting allyl ethers to propenyl ethers.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1996},
month = {10}
}
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