Inorganic-organic composite polymers and methods of making
Abstract
The invention is a composition of an inorganic-organic polymer composite and a method of making it. The inorganic portion of the fundamental polymer composite polymer repeat is a speciated inorganic heterocyclic compound, and the organic portion of the polymer repeat is a cyclic organic radical anion compound having at least two charged sites. The composition of the present invention is made by combining a cyclic organic radical anion compound with a speciated inorganic heterocyclic compound by a nucleophilic substitution thereby forming a polymer of an inorganic-organic composite. The cyclic organic radical anion compound is preferably generated electrochemically. The nucleophilic substitution is alternately carried out chemically or electrochemically. A preferred embodiment of the present invention includes performing the nucleophilic substitution at the cathode of an electrochemical cell. 2 figs.
- Inventors:
- Issue Date:
- Research Org.:
- Battelle Memorial Institute, Columbus, OH (United States)
- OSTI Identifier:
- 392635
- Patent Number(s):
- 5569736
- Application Number:
- PAN: 8-344,786
- Assignee:
- Battelle Memorial Inst., Richland, WA (United States)
- DOE Contract Number:
- AC06-76RL01830
- Resource Type:
- Patent
- Resource Relation:
- Other Information: PBD: 29 Oct 1996
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; COMPOSITE MATERIALS; CHEMICAL PREPARATION; POLYMERS; ORGANIC POLYMERS; CHEMICAL COMPOSITION; ELECTROCHEMICAL CELLS
Citation Formats
Josowicz, M A, and Exarhos, G J. Inorganic-organic composite polymers and methods of making. United States: N. p., 1996.
Web.
Josowicz, M A, & Exarhos, G J. Inorganic-organic composite polymers and methods of making. United States.
Josowicz, M A, and Exarhos, G J. Tue .
"Inorganic-organic composite polymers and methods of making". United States.
@article{osti_392635,
title = {Inorganic-organic composite polymers and methods of making},
author = {Josowicz, M A and Exarhos, G J},
abstractNote = {The invention is a composition of an inorganic-organic polymer composite and a method of making it. The inorganic portion of the fundamental polymer composite polymer repeat is a speciated inorganic heterocyclic compound, and the organic portion of the polymer repeat is a cyclic organic radical anion compound having at least two charged sites. The composition of the present invention is made by combining a cyclic organic radical anion compound with a speciated inorganic heterocyclic compound by a nucleophilic substitution thereby forming a polymer of an inorganic-organic composite. The cyclic organic radical anion compound is preferably generated electrochemically. The nucleophilic substitution is alternately carried out chemically or electrochemically. A preferred embodiment of the present invention includes performing the nucleophilic substitution at the cathode of an electrochemical cell. 2 figs.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Oct 29 00:00:00 EST 1996},
month = {Tue Oct 29 00:00:00 EST 1996}
}