Synthesis and use of (perfluoroaryl) fluoro-aluminate anion

Marks, T J; Chen, Y X

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Title: Synthesis and use of (perfluoroaryl) fluoro-aluminate anion

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Abstract

A trityl perfluorophenyl alumninate such as tris(2,2{prime},2{double_prime}nonafluorobiphenyl) fluoroaluminate (PBA{sup {minus}}) and its role as a cocatalyst in metallocene-mediated olefin polymerization is disclosed. 4 figs.

Inventors:: Marks, T J; Chen, Y X

Issue Date:: 1998-12-29

Research Org.:: Northwestern Univ., Evanston, IL (United States)

Sponsoring Org.:: USDOE, Washington, DC (United States)

OSTI Identifier:: 321159

Patent Number(s):: 5854166

Application Number:: PAN: 8-912,617

Assignee:: Northwestern Univ., Evanston, IL (United States)

DOE Contract Number:: FG02-86ER13511

Resource Type:: Patent

Resource Relation:: Other Information: PBD: 29 Dec 1998

Country of Publication:: United States

Language:: English

Subject:: 40 CHEMISTRY; CATALYSTS; CHEMICAL PREPARATION; ALUMINIUM COMPOUNDS; ORGANIC FLUORINE COMPOUNDS; CATALYTIC EFFECTS; ALKENES; POLYMERIZATION

Citation Formats


                    Marks, T J, and Chen, Y X. Synthesis and use of (perfluoroaryl) fluoro-aluminate anion.  United States: N. p., 1998. 
        Web.

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                    Marks, T J, & Chen, Y X. Synthesis and use of (perfluoroaryl) fluoro-aluminate anion.  United States.

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                    Marks, T J, and Chen, Y X. Tue .  
        "Synthesis and use of (perfluoroaryl) fluoro-aluminate anion".  United States.

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@article{osti_321159,

  title        = {Synthesis and use of (perfluoroaryl) fluoro-aluminate anion},

  author       = {Marks, T J and Chen, Y X},

  abstractNote = {A trityl perfluorophenyl alumninate such as tris(2,2{prime},2{double_prime}nonafluorobiphenyl) fluoroaluminate (PBA{sup {minus}}) and its role as a cocatalyst in metallocene-mediated olefin polymerization is disclosed. 4 figs.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {1998},

  month        = {12}

}

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A trityl perfluorophenyl alumninate such as tris(2,2',2"-nonafluorobiphenyl) fluoroaluminate (PBA.sup.-) and its role as a cocatalyst in metallocene-mediated olefin polymerization is disclosed.
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