Solvent-free processing of lithium lanthanum zirconium oxide coated-cathodes

Durham, Jessica L.; Libera, Joseph A.; Lipson, Albert L.; Liang, Yujia

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Title: Solvent-free processing of lithium lanthanum zirconium oxide coated-cathodes

Abstract

A dry process for coating Ni-rich cathode powder with cubic LLZO powder prepared by flame spray pyrolysis.

Inventors:: Durham, Jessica L.; Libera, Joseph A.; Lipson, Albert L.; Liang, Yujia

Issue Date:: 2023-11-21

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 2293883

Patent Number(s):: 11821091

Application Number:: 16/938,037

Assignee:: UChicago Argonne, LLC (Chicago, IL)

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B05 - SPRAYING OR ATOMISING IN GENERAL B05D - PROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL

C - CHEMISTRY C23 - COATING METALLIC MATERIAL C23C - COATING METALLIC MATERIAL

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B - PERFORMING OPERATIONS B05 - SPRAYING OR ATOMISING IN GENERAL B05D - PROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL
B05D1/08 - Flame spraying

C - CHEMISTRY C23 - COATING METALLIC MATERIAL C23C - COATING METALLIC MATERIAL
C23C4/11 - Oxides
C23C4/129 - Flame spraying

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M2004/028 - {Positive electrodes}
H01M2300/0068 - inorganic
H01M4/04 - Processes of manufacture in general
H01M4/0402 - {Methods of deposition of the material}
H01M4/0471 - {involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis}
H01M4/1391 - of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M4/366 - {as layered products}
H01M4/525 - of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
H01M4/62 - Selection of inactive substances as ingredients for active masses, e.g. binders, fillers

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

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DOE Contract Number:: AC02-06CH11357

Resource Type:: Patent

Resource Relation:: Patent File Date: 07/24/2020

Country of Publication:: United States

Language:: English

Citation Formats


                    Durham, Jessica L., Libera, Joseph A., Lipson, Albert L., and Liang, Yujia. Solvent-free processing of lithium lanthanum zirconium oxide coated-cathodes.  United States: N. p., 2023. 
        Web.

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                    Durham, Jessica L., Libera, Joseph A., Lipson, Albert L., & Liang, Yujia. Solvent-free processing of lithium lanthanum zirconium oxide coated-cathodes.  United States.

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                    Durham, Jessica L., Libera, Joseph A., Lipson, Albert L., and Liang, Yujia. Tue .  
        "Solvent-free processing of lithium lanthanum zirconium oxide coated-cathodes".  United States.  https://www.osti.gov/servlets/purl/2293883.

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@article{osti_2293883,

  title        = {Solvent-free processing of lithium lanthanum zirconium oxide coated-cathodes},

  author       = {Durham, Jessica L. and Libera, Joseph A. and Lipson, Albert L. and Liang, Yujia},

  abstractNote = {A dry process for coating Ni-rich cathode powder with cubic LLZO powder prepared by flame spray pyrolysis.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2023},

  month        = {11}

}

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A process for preparing doped-lithium lanthanum zirconium oxide (doped-LLZO) is described herein. The method involves dry doping of a co-precipitated lanthanum zirconium oxide (LZO) precursor. Dry doping is a process in which a dry powdered dopant is ground and mixed with a pre-prepared co-precipitated LZO precursor and a lithium salt to provide a LLZO precursor composition, which is subsequently calcined to form a doped-LLZO. The process described herein comprises calcining a dry, powdered (e.g., micron, sub-micron or nano-powdered) mixture of a co-precipitated LZO precursor, a dopant salt or oxide, and a lithium salt under an oxygen-containing atmosphere at a temperaturemore » « less
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Described herein are low or no-cobalt materials useful as electrode active materials in a cathode for lithium or lithium-ion batteries. For example, compositions of matter are described herein, such as electrode active materials that can be incorporated into an electrode, such as a cathode. The disclosed electrode active materials exhibit high specific energy and voltage, and can also exhibit high rate capability and/or long operational lifetime.
Full Text Available
Early transition metal stabilized high capacity cobalt free cathodes for lithium-ion batteries

Patent Nanda, Jagjit; Belharouak, Ilias; Self, Ethan C.; ...

A cathode for a lithium battery includes LiNi_0.5-x/2Mn_0.5-x/2M_xO₂ where M is at least one selected from the group consisting of Mo, Ti, Cr, Zr and V, and x is between 0.005-0.02. The LiNi_0.5-x/2Mn_0.5-x/2M_xO₂ can be coated with Mn₂P₂O₇. The Mn₂P₂O₇ can be 1-3 wt. %, based on the total weight of the LiNi_0.5-x/2Mn_0.5-x/2M_xO₂ and Mn₂P₂O₇. A cathode composition, a lithium battery, and a method of making a lithium battery are also disclosed.
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Al-doped Li7La3Zr2O12 synthesized by a polymerized complex method journal, October 2011

Nebulized spray pyrolysis of Al-doped Li7La3Zr2O12 solid electrolyte for battery applications journal, October 2014

High Temperature Vaporization Behavior of Oxides. I. Alkali Metal Binary Oxides journal, January 1984

The role of Al and Li concentration on the formation of cubic garnet solid electrolyte of nominal composition Li7La3Zr2O12 journal, January 2012

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High Temperature Properties and Decomposition of Inorganic Salts Part 3, Nitrates and Nitrites journal, July 1972

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Sol–gel synthesis and lithium ion conductivity of Li7La3Zr2O12 with garnet-related type structure journal, March 2011

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Flame-Made WO 3 /CeO x -TiO 2 Catalysts for Selective Catalytic Reduction of NO x by NH 3 journal, August 2015

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Impact of air exposure and surface chemistry on Li–Li 7 La 3 Zr 2 O 12 interfacial resistance journal, January 2017

Crystal Chemistry and Stability of “Li7La3Zr2O12 ” Garnet: A Fast Lithium-Ion Conductor journal, February 2011

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Al-doped Li₇La₃Zr₂O₁₂ synthesized by a polymerized complex method
journal, October 2011

Nebulized spray pyrolysis of Al-doped Li7La3Zr2O12 solid electrolyte for battery applications
journal, October 2014

High Temperature Vaporization Behavior of Oxides. I. Alkali Metal Binary Oxides
journal, January 1984

The role of Al and Li concentration on the formation of cubic garnet solid electrolyte of nominal composition Li₇La₃Zr₂O₁₂
journal, January 2012

A study of suppressed formation of low-conductivity phases in doped Li ₇ La ₃ Zr ₂ O ₁₂ garnets by in situ neutron diffraction
journal, January 2015

Experimental study and thermodynamic modelling of the ZrO2–LaO1.5 system
journal, March 2008

Aerosol Processing of Materials
journal, January 1993

Preparation of Nano- and Microstructured Garnet Li ₇ La ₃ Zr ₂ O ₁₂ Solid Electrolytes for Li-Ion Batteries via Cellulose Templating
journal, October 2016

A bird's-eye view of Li-stuffed garnet-type Li ₇ La ₃ Zr ₂ O ₁₂ ceramic electrolytes for advanced all-solid-state Li batteries
journal, January 2019

Hybrid Electrolyte for Lithium Metal Battery
patent-application, December 2021

Process for Preparing Doped Lithium Lanthanum Zirconium Oxide
patent-application, July 2021

Method of preparing a gallium-doped LLZO solid electrolyte for an all-solid-state lithium secondary battery
patent, October 2020

An experimental and modeling investigation of particle production by spray pyrolysis using a laminar flow aerosol reactor
journal, March 2000

Solid-state Electrolyte and Method of Manufacture Thereof
patent-application, February 2020

Structure and electrochemical performance of spinel LiMn1.95Ni0.05O3.98F0.02 coated with Li-La-Zr-O solid electrolyte
journal, October 2013

Key parameters governing the densification of cubic-Li7La3Zr2O12 Li+ conductors
journal, June 2017

Ionically-Conductive Amorphous Lithium Lanthanum Zirconium Oxide
patent-application, March 2011

Flame synthesis of metal salt nanoparticles, in particular calcium and phosphate comprising nanoparticles
patent, June 2014

Low Tortuosity Electrodes and Electrolytes, and Methods of Their Manufacture
patent-application, November 2020

Method of Tuning the Conversion Temperature of Cubic Phase of Aluminum-doped Lithium Lanthanum Zirconium Oxide
patent-application, December 2020

Colloidal spray pyrolysis: A new fabrication technology for nanostructured energy storage materials
journal, July 2018

All-solid-state Lithium Secondary Battery Containing LLZO Solid Electrolyte and Method for Preparing Same
patent-application, February 2019

Oxide Electrolytes for Lithium Batteries
journal, September 2015

Utmost limits of various solid electrolytes in all-solid-state lithium batteries: A critical review
journal, July 2019

High capacity solid state composite cathode, solid state composite separator, solid-state rechargeable lithium battery and methods of making same
patent, June 2019

Rapid Pyrolysis to Form Super Ionic Conducting Lithium Garnets
patent-application, August 2021

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journal, July 1972

Cu-Sn binary metal particle generation by spray pyrolysis
journal, December 2016

Flame made nanoparticles permit processing of dense, flexible, Li ⁺ conducting ceramic electrolyte thin films of cubic-Li ₇ La ₃ Zr ₂ O ₁₂ (c-LLZO)
journal, January 2016

Fast Li⊕ Conducting Ceramic Electrolytes
journal, February 1996

Electrochemical Properties of Composite Cathode Using Bimodal Sized Electrolyte for All-Solid-State Batteries
journal, January 2019

Solvent-Free Processing of Lithium Lanthanum Zirconium Oxide Coated-Cathodes
patent-application, January 2022

Sol–gel synthesis and lithium ion conductivity of Li7La3Zr2O12 with garnet-related type structure
journal, March 2011

Synthesis of garnet-type Li7−xLa3Zr2O12−1/2x and its stability in aqueous solutions
journal, February 2011

Flame-Made WO ₃ /CeO _x -TiO ₂ Catalysts for Selective Catalytic Reduction of NO _x by NH ₃
journal, August 2015

Flame made metal oxides
patent, May 2007

Fast Lithium Ion Conduction in Garnet-Type Li₇La₃Zr₂O₁₂
journal, October 2007

Lanthanum nitrate decomposition by both temperature programmed heating and citrate gel combustion
journal, February 2007

Lithium Solid Electrolyte and Method of Manufacture Thereof
patent-application, December 2020

Impact of air exposure and surface chemistry on Li–Li ₇ La ₃ Zr ₂ O ₁₂ interfacial resistance
journal, January 2017

Crystal Chemistry and Stability of “Li₇La₃Zr₂O₁₂ ” Garnet: A Fast Lithium-Ion Conductor
journal, February 2011

Controlled synthesis of nanostructured particles by flame spray pyrolysis
journal, February 2002

Rechargeable lithium battery
patent, December 1998

Process for Producing a Composite Material
patent-application, December 2019

Flame synthesis of functional nanostructured materials and devices: Surface growth and aggregation
journal, January 2017

Cathode Active Material for Lithium Ion Secondary Battery and Lithium Ion Secondary Battery
patent-application, September 2021

Influence of precursor calcination temperature on sintering and conductivity of Li _1.5 Al _0.5 Ti _1.5 (PO ₄ ) ₃ ceramics
journal, January 2019

Mechanism Study on the Interfacial Stability of a Lithium Garnet-Type Oxide Electrolyte against Cathode Materials
journal, October 2018

Multistep sintering to synthesize fast lithium garnets
journal, January 2016

Compositions and Methods for Energy Storage Devices Including Salts and/or Foams
patent-application, January 2022

Chemical compatibility between garnet-like solid state electrolyte Li6.75La3Zr1.75Ta0.25O12 and major commercial lithium battery cathode materials
journal, September 2016

Particle size distribution function of incipient soot in laminar premixed ethylene flames: effect of flame temperature
journal, January 2005

Design of Nanomaterial Synthesis by Aerosol Processes
journal, July 2012

Enhanced Electrochemical Performance of Ionic-Conductor Coated Li[Ni _0.7 Co _0.15 Mn _0.15 ]O ₂
journal, January 2017