Recovery of critical elements from end-of-life lithium ion batteries with supported membrane solvent extraction
Abstract
Single-stage and multi-stage systems and methods for the recovery of critical elements in substantially pure form from lithium ion batteries are provided. The systems and methods include supported membrane solvent extraction using an immobilized organic phase within the pores of permeable hollow fibers. The permeable hollow fibers are contacted by a feed solution on one side, and a strip solution on another side, to provide the simultaneous extraction and stripping of elements from dissolved lithium ion cathode materials, while rejecting other elements from the feed solution. The single- and multi-stage systems and methods can selectively recover cobalt, manganese, nickel, lithium, aluminum and other elements from spent battery cathodes and are not limited by equilibrium constraints as compared to traditional solvent extraction processes.
- Inventors:
- Issue Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 2293840
- Patent Number(s):
- 11811035
- Application Number:
- 16/884,189
- Assignee:
- UT-Battelle, LLC (Oak Ridge, TN)
- DOE Contract Number:
- AC05-00OR22725
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 05/27/2020
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Bhave, Ramesh R., Islam, Syed Z., and Wagh, Priyesh A. Recovery of critical elements from end-of-life lithium ion batteries with supported membrane solvent extraction. United States: N. p., 2023.
Web.
Bhave, Ramesh R., Islam, Syed Z., & Wagh, Priyesh A. Recovery of critical elements from end-of-life lithium ion batteries with supported membrane solvent extraction. United States.
Bhave, Ramesh R., Islam, Syed Z., and Wagh, Priyesh A. Tue .
"Recovery of critical elements from end-of-life lithium ion batteries with supported membrane solvent extraction". United States. https://www.osti.gov/servlets/purl/2293840.
@article{osti_2293840,
title = {Recovery of critical elements from end-of-life lithium ion batteries with supported membrane solvent extraction},
author = {Bhave, Ramesh R. and Islam, Syed Z. and Wagh, Priyesh A.},
abstractNote = {Single-stage and multi-stage systems and methods for the recovery of critical elements in substantially pure form from lithium ion batteries are provided. The systems and methods include supported membrane solvent extraction using an immobilized organic phase within the pores of permeable hollow fibers. The permeable hollow fibers are contacted by a feed solution on one side, and a strip solution on another side, to provide the simultaneous extraction and stripping of elements from dissolved lithium ion cathode materials, while rejecting other elements from the feed solution. The single- and multi-stage systems and methods can selectively recover cobalt, manganese, nickel, lithium, aluminum and other elements from spent battery cathodes and are not limited by equilibrium constraints as compared to traditional solvent extraction processes.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2023},
month = {11}
}
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Works referenced in this record:
Lithium-ion batteries recycling process
patent, November 2022
- Morin, Dominique; Gagne-Bourque, Charles; Nadeau, Emilie
- US Patent Document 11,508,999
Membrane assisted solvent extraction for rare earth element recovery
patent, May 2018
- Bhave, Ramesh R.; Kim, Daejin; Peterson, Eric S.
- US Patent Document 9,968,887
Clean process of recovering metals from waste lithium ion batteries
patent, February 2003
- Lin, Jiunn-Ren; Fan, Chang Meng; Chang, I-Long
- US Patent Document 6,514,311
Separation of Co(II) and Li(I) with Cyanex 272 using hollow fiber supported liquid membrane: A comparison with flat sheet supported liquid membrane and dispersive solvent extraction process
journal, July 2015
- Swain, Basudev; Mishra, Chinmayee; Jeong, Jinki
- Chemical Engineering Journal, Vol. 271
Extraction of metal ions from aqueous solution
patent, March 1984
- Baker, Richard W.
- US Patent Document 4,437,994
Lithium Recovery from Aqueous Resources and Batteries: A Brief Review
journal, April 2018
- Li, Ling; Deshmane, Vishwanath G.; Paranthaman, M. Parans
- Johnson Matthey Technology Review, Vol. 62, Issue 2
Processing of cobaltous sulpha/dithionate liquors derived from cobalt resource
patent, April 2019
- Chow, Norman; Jung, Joey; Nacu, Anca-Mihaela
- US Patent Document 10,246,343