Adsorption cooling system using metal organic frameworks

Baumann, Theodore F.; Satcher, Joe H.; Farmer, Joseph C.; Bandhauer, Todd

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Title: Adsorption cooling system using metal organic frameworks

Abstract

A highly adsorptive structure includes: a substrate; and a metal-organic framework (MOF) comprising a plurality of metal atoms coordinated to a plurality of organic spacer molecules; wherein the MOF is coupled to at least one surface of the substrate, wherein the MOF is configured to adsorb and desorb a refrigerant under predetermined thermodynamic conditions. The refrigerant includes one or more materials selected from the group consisting of: acid halides, alcohols, aldehydes, amines, chlorofluorocarbons, esters, ethers, fluorocarbons, perfluorocarbons, halocarbons, halogenated aldehydes, halogenated amines, halogenated hydrocarbons, halomethanes, hydrocarbons, hydrochlorofluorocarbons, hydrofluoroethers, hydrofluoroolefins, inorganic gases, ketones, nitrocarbon compounds, noble gases, organochlorine compounds, organofluorine compounds, organophosphorous compounds, organosilicon compounds, oxide gases, refrigerant blends and thiols.

Inventors:: Baumann, Theodore F.; Satcher, Jr., Joe H.; Farmer, Joseph C.; Bandhauer, Todd

Issue Date:: 2023-10-17

Research Org.:: Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 2293719

Patent Number(s):: 11786883

Application Number:: 17/199,251

Assignee:: Lawrence Livermore National Security, LLC (Livermore, CA)

DOE Contract Number:: AC52-07NA27344

Resource Type:: Patent

Resource Relation:: Patent File Date: 03/11/2021

Country of Publication:: United States

Language:: English

Citation Formats


                    Baumann, Theodore F., Satcher, Jr., Joe H., Farmer, Joseph C., and Bandhauer, Todd. Adsorption cooling system using metal organic frameworks.  United States: N. p., 2023. 
        Web.

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                    Baumann, Theodore F., Satcher, Jr., Joe H., Farmer, Joseph C., & Bandhauer, Todd. Adsorption cooling system using metal organic frameworks.  United States.

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                    Baumann, Theodore F., Satcher, Jr., Joe H., Farmer, Joseph C., and Bandhauer, Todd. Tue .  
        "Adsorption cooling system using metal organic frameworks".  United States.  https://www.osti.gov/servlets/purl/2293719.

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@article{osti_2293719,

  title        = {Adsorption cooling system using metal organic frameworks},

  author       = {Baumann, Theodore F. and Satcher, Jr., Joe H. and Farmer, Joseph C. and Bandhauer, Todd},

  abstractNote = {A highly adsorptive structure includes: a substrate; and a metal-organic framework (MOF) comprising a plurality of metal atoms coordinated to a plurality of organic spacer molecules; wherein the MOF is coupled to at least one surface of the substrate, wherein the MOF is configured to adsorb and desorb a refrigerant under predetermined thermodynamic conditions. The refrigerant includes one or more materials selected from the group consisting of: acid halides, alcohols, aldehydes, amines, chlorofluorocarbons, esters, ethers, fluorocarbons, perfluorocarbons, halocarbons, halogenated aldehydes, halogenated amines, halogenated hydrocarbons, halomethanes, hydrocarbons, hydrochlorofluorocarbons, hydrofluoroethers, hydrofluoroolefins, inorganic gases, ketones, nitrocarbon compounds, noble gases, organochlorine compounds, organofluorine compounds, organophosphorous compounds, organosilicon compounds, oxide gases, refrigerant blends and thiols.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2023},

  month        = {10}

}

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Works referenced in this record:

MOFs as Adsorbents for Low Temperature Heating and Cooling Applications
journal, March 2009

Henninger, Stefan K.; Habib, Hesham A.; Janiak, Christoph
Journal of the American Chemical Society, Vol. 131, Issue 8
https://doi.org/10.1021/ja808444z

Comparative Molecular Simulation Study of CO ₂ /N ₂ and CH ₄ /N ₂ Separation in Zeolites and Metal−Organic Frameworks
journal, May 2009

Liu, Bei; Smit, Berend
Langmuir, Vol. 25, Issue 10
https://doi.org/10.1021/la900823d

Natural gas storage apparatus and method of use
patent-application, November 2009

Farone, William A.
US Patent Application 12/134290; 20090283427
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090283427

High gas adsorption in a microporous metal-organic framework with open-metal sites
patent-application, November 2006

Yaghi, Omar; Chen, Banglin
US Patent Application 11/400478; 20060252641
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20060252641