Reactive membrane networks for CWA protection
Abstract
A membrane includes a first layer, and a second layer coupled to the first layer. The second layer includes a network of catalytic sites, each catalytic site having a catalytic center characterized by promoting a chemical reaction of a target material. A method of forming a chemically reactive membrane includes applying a first solution to a structure, the first solution includes a macrocyclic ligand having electron-donating ligands and a side functional group for crosslinking, crosslinking a plurality of the macrocyclic ligand to form a first network of crosslinked macrocyclic ligands, and applying a second solution to the structure, the second solution comprising a catalytic center. Each catalytic center complexes with the electron-donating ligands of each macrocyclic ligand to form catalytic sites in the first network of crosslinked macrocyclic ligands.
- Inventors:
- Issue Date:
- Research Org.:
- Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 2293683
- Patent Number(s):
- 11772087
- Application Number:
- 17/009,582
- Assignee:
- Lawrence Livermore National Security, LLC (Livermore, CA)
- DOE Contract Number:
- AC52-07NA27344
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 09/01/2020
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Fornasiero, Francesco, Lau, Edmond Y., and Valdez, Carlos A. Reactive membrane networks for CWA protection. United States: N. p., 2023.
Web.
Fornasiero, Francesco, Lau, Edmond Y., & Valdez, Carlos A. Reactive membrane networks for CWA protection. United States.
Fornasiero, Francesco, Lau, Edmond Y., and Valdez, Carlos A. Tue .
"Reactive membrane networks for CWA protection". United States. https://www.osti.gov/servlets/purl/2293683.
@article{osti_2293683,
title = {Reactive membrane networks for CWA protection},
author = {Fornasiero, Francesco and Lau, Edmond Y. and Valdez, Carlos A.},
abstractNote = {A membrane includes a first layer, and a second layer coupled to the first layer. The second layer includes a network of catalytic sites, each catalytic site having a catalytic center characterized by promoting a chemical reaction of a target material. A method of forming a chemically reactive membrane includes applying a first solution to a structure, the first solution includes a macrocyclic ligand having electron-donating ligands and a side functional group for crosslinking, crosslinking a plurality of the macrocyclic ligand to form a first network of crosslinked macrocyclic ligands, and applying a second solution to the structure, the second solution comprising a catalytic center. Each catalytic center complexes with the electron-donating ligands of each macrocyclic ligand to form catalytic sites in the first network of crosslinked macrocyclic ligands.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2023},
month = {10}
}
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