Diamine solvent system for CO2 capture
Abstract
Disclosed herein is a method and system for CO2 removal from a gas stream using a diamine solvent having a Formula I R1(R2)N-L1-NH—R3 Formula I. With respect to Formula I, each of R1 and R2 independently is aliphatic, cycloaliphatic, or R1 and R2 together with the nitrogen to which they are attached, form a heterocyclyl ring; L1 is aliphatic, cycloaliphatic, or L1 and R1 together with the nitrogen to which they are attached form a heterocyclyl ring; and R3 is aliphatic, cycloaliphatic, cycloalkylalkyl, or alkoxyalkyl. And/or the compound may have a viscosity of less than 75 cP at a CO2-loading of 40 mol % and at a temperature of 40° C.
- Inventors:
- Issue Date:
- Research Org.:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE; GE Global Research (United States)
- OSTI Identifier:
- 2222265
- Patent Number(s):
- 11745137
- Application Number:
- 17/584,597
- Assignee:
- Battelle Memorial Institute (Richland, WA)
- DOE Contract Number:
- AC05-76RL01830; CRADA 363
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 01/26/2022
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Malhotra, Deepika, Koech, Phillip K., Heldebrant, David J., Glezakou, Vassiliki-Alexandra, Rousseau, Roger J., Nguyen, Manh Thuong, Perry, Robert, Page, Jordan P., and Cantu, David C. Diamine solvent system for CO2 capture. United States: N. p., 2023.
Web.
Malhotra, Deepika, Koech, Phillip K., Heldebrant, David J., Glezakou, Vassiliki-Alexandra, Rousseau, Roger J., Nguyen, Manh Thuong, Perry, Robert, Page, Jordan P., & Cantu, David C. Diamine solvent system for CO2 capture. United States.
Malhotra, Deepika, Koech, Phillip K., Heldebrant, David J., Glezakou, Vassiliki-Alexandra, Rousseau, Roger J., Nguyen, Manh Thuong, Perry, Robert, Page, Jordan P., and Cantu, David C. Tue .
"Diamine solvent system for CO2 capture". United States. https://www.osti.gov/servlets/purl/2222265.
@article{osti_2222265,
title = {Diamine solvent system for CO2 capture},
author = {Malhotra, Deepika and Koech, Phillip K. and Heldebrant, David J. and Glezakou, Vassiliki-Alexandra and Rousseau, Roger J. and Nguyen, Manh Thuong and Perry, Robert and Page, Jordan P. and Cantu, David C.},
abstractNote = {Disclosed herein is a method and system for CO2 removal from a gas stream using a diamine solvent having a Formula I R1(R2)N-L1-NH—R3 Formula I. With respect to Formula I, each of R1 and R2 independently is aliphatic, cycloaliphatic, or R1 and R2 together with the nitrogen to which they are attached, form a heterocyclyl ring; L1 is aliphatic, cycloaliphatic, or L1 and R1 together with the nitrogen to which they are attached form a heterocyclyl ring; and R3 is aliphatic, cycloaliphatic, cycloalkylalkyl, or alkoxyalkyl. And/or the compound may have a viscosity of less than 75 cP at a CO2-loading of 40 mol % and at a temperature of 40° C.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2023},
month = {9}
}
Works referenced in this record:
Gas Capture Process
patent-application, May 2014
- Yang, Qi; James, Susan N.; Ballard, Mathew John
- US Patent Application 14/112,724; 2014/0127103 Al
Development of novel tertiary amine absorbents for CO2 capture
journal, February 2009
- Chowdhury, Firoz Alam; Okabe, Hiromichi; Shimizu, Shinkichi
- Energy Procedia, Vol. 1, Issue 1
Water-Lean Solvents for Post-Combustion CO 2 Capture: Fundamentals, Uncertainties, Opportunities, and Outlook
journal, May 2017
- Heldebrant, David J.; Koech, Phillip K.; Glezakou, Vassiliki-Alexandra
- Chemical Reviews, Vol. 117, Issue 14
New Amines for CO 2 Capture. IV. Degradation, Corrosion, and Quantitative Structure Property Relationship Model
journal, April 2012
- Martin, Sandrine; Lepaumier, Helene; Picq, Dominique
- Industrial & Engineering Chemistry Research, Vol. 51, Issue 18
Reversible zwitterionic liquids, the reaction of alkanol guanidines, alkanol amidines, and diamines with CO2
journal, January 2010
- Heldebrant, David J.; Koech, Phillip K.; Ang, M. Trisha C.
- Green Chemistry, Vol. 12, Issue 4, p. 713-721
Synthesis of new amines for enhanced carbon dioxide (CO2) capture performance: The effect of chemical structure on equilibrium solubility, cyclic capacity, kinetics of absorption and regeneration, and heats of absorption and regeneration
journal, July 2016
- Singto, Sudkanueng; Supap, Teeradet; Idem, Raphael
- Separation and Purification Technology, Vol. 167
New Amines for CO 2 Capture. I. Mechanisms of Amine Degradation in the Presence of CO 2
journal, October 2009
- Lepaumier, Helene; Picq, Dominique; Carrette, Pierre-Louis
- Industrial & Engineering Chemistry Research, Vol. 48, Issue 20
Method of removing acid compounds from a gaseous effluent with an absorbent solution based on I, II/III diamines
patent-application, January 2013
- Porcheron, Fabien; Jacquin, Marc; Delfort, Bruno
- US Patent Application 13/515334; 20130011314
Liquid for absorbing and collecting carbon dioxide in gas, and method for collecting carbon dioxide with use of same
patent-application, January 2016
- Higashii, Takayuki; Chowdhury, Firoz Alam; Goto, Kazuya
- US Patent Application 14/769972; 20160001220
Toward Intelligent CO 2 Capture Solvent Design through Experimental Solvent Development and Amine Synthesis
journal, August 2016
- Yang, Qi; Puxty, Graeme; James, Susan
- Energy & Fuels, Vol. 30, Issue 9
Carbon dioxide absorbent comprising triamine
patent-application, August 2017
- Hong, Sung Yun; Kim, Hoon Sik
- US Patent Application 15/519234; 20170246587
Acid gas absorbent composition
patent, July 2014
- Blair, Alan M.; Garside, Keith N.; Andrews, William J.
- US Patent Document 8,765,951
CO 2 Capture by Tertiary Amine Absorbents: A Performance Comparison Study
journal, June 2013
- Chowdhury, Firoz Alam; Yamada, Hidetaka; Higashii, Takayuki
- Industrial & Engineering Chemistry Research, Vol. 52, Issue 24