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Title: Diamine solvent system for CO2 capture

Abstract

Disclosed herein is a method and system for CO2 removal from a gas stream using a diamine solvent having a Formula I R1(R2)N-L1-NH—R3  Formula I. With respect to Formula I, each of R1 and R2 independently is aliphatic, cycloaliphatic, or R1 and R2 together with the nitrogen to which they are attached, form a heterocyclyl ring; L1 is aliphatic, cycloaliphatic, or L1 and R1 together with the nitrogen to which they are attached form a heterocyclyl ring; and R3 is aliphatic, cycloaliphatic, cycloalkylalkyl, or alkoxyalkyl. And/or the compound may have a viscosity of less than 75 cP at a CO2-loading of 40 mol % and at a temperature of 40° C.

Inventors:
; ; ; ; ; ; ; ;
Issue Date:
Research Org.:
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE; GE Global Research (United States)
OSTI Identifier:
2222265
Patent Number(s):
11745137
Application Number:
17/584,597
Assignee:
Battelle Memorial Institute (Richland, WA)
DOE Contract Number:  
AC05-76RL01830; CRADA 363
Resource Type:
Patent
Resource Relation:
Patent File Date: 01/26/2022
Country of Publication:
United States
Language:
English

Citation Formats

Malhotra, Deepika, Koech, Phillip K., Heldebrant, David J., Glezakou, Vassiliki-Alexandra, Rousseau, Roger J., Nguyen, Manh Thuong, Perry, Robert, Page, Jordan P., and Cantu, David C. Diamine solvent system for CO2 capture. United States: N. p., 2023. Web.
Malhotra, Deepika, Koech, Phillip K., Heldebrant, David J., Glezakou, Vassiliki-Alexandra, Rousseau, Roger J., Nguyen, Manh Thuong, Perry, Robert, Page, Jordan P., & Cantu, David C. Diamine solvent system for CO2 capture. United States.
Malhotra, Deepika, Koech, Phillip K., Heldebrant, David J., Glezakou, Vassiliki-Alexandra, Rousseau, Roger J., Nguyen, Manh Thuong, Perry, Robert, Page, Jordan P., and Cantu, David C. Tue . "Diamine solvent system for CO2 capture". United States. https://www.osti.gov/servlets/purl/2222265.
@article{osti_2222265,
title = {Diamine solvent system for CO2 capture},
author = {Malhotra, Deepika and Koech, Phillip K. and Heldebrant, David J. and Glezakou, Vassiliki-Alexandra and Rousseau, Roger J. and Nguyen, Manh Thuong and Perry, Robert and Page, Jordan P. and Cantu, David C.},
abstractNote = {Disclosed herein is a method and system for CO2 removal from a gas stream using a diamine solvent having a Formula I R1(R2)N-L1-NH—R3  Formula I. With respect to Formula I, each of R1 and R2 independently is aliphatic, cycloaliphatic, or R1 and R2 together with the nitrogen to which they are attached, form a heterocyclyl ring; L1 is aliphatic, cycloaliphatic, or L1 and R1 together with the nitrogen to which they are attached form a heterocyclyl ring; and R3 is aliphatic, cycloaliphatic, cycloalkylalkyl, or alkoxyalkyl. And/or the compound may have a viscosity of less than 75 cP at a CO2-loading of 40 mol % and at a temperature of 40° C.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2023},
month = {9}
}

Works referenced in this record:

Gas Capture Process
patent-application, May 2014


Development of novel tertiary amine absorbents for CO2 capture
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Water-Lean Solvents for Post-Combustion CO 2 Capture: Fundamentals, Uncertainties, Opportunities, and Outlook
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New Amines for CO 2 Capture. IV. Degradation, Corrosion, and Quantitative Structure Property Relationship Model
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Reversible zwitterionic liquids, the reaction of alkanol guanidines, alkanol amidines, and diamines with CO2
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New Amines for CO 2 Capture. I. Mechanisms of Amine Degradation in the Presence of CO 2
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Method of removing acid compounds from a gaseous effluent with an absorbent solution based on I, II/III diamines
patent-application, January 2013


Liquid for absorbing and collecting carbon dioxide in gas, and method for collecting carbon dioxide with use of same
patent-application, January 2016


Carbon dioxide absorbent comprising triamine
patent-application, August 2017


Acid gas absorbent composition
patent, July 2014


CO 2 Capture by Tertiary Amine Absorbents: A Performance Comparison Study
journal, June 2013