Methods for co-producing hydrocarbon products and ammonia
Abstract
A method of a hydrocarbon product and ammonia comprises introducing C2H6 to a positive electrode of an electrochemical cell comprising the positive electrode, a negative electrode, and a proton-conducting membrane between the positive electrode and the negative electrode. The proton-conducting membrane comprising an electrolyte material having an ionic conductivity greater than or equal to about 10−2 S/cm at one or more temperatures within a range of from about 150° C. to about 600° C. N2 is introduced to the negative electrode of the electrochemical cell. A potential difference is applied between the positive electrode and the negative electrode of the electrochemical cell. A system for co-producing higher hydrocarbons and NH3, and an electrochemical cell are also described.
- Inventors:
- Issue Date:
- Research Org.:
- Idaho National Laboratory (INL), Idaho Falls, ID (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 2222206
- Patent Number(s):
- 11731920
- Application Number:
- 16/532,276
- Assignee:
- Battelle Energy Alliance, LLC (Idaho Falls, ID)
- DOE Contract Number:
- AC07-05ID14517
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 08/05/2019
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Ding, Dong, Wu, Wei, Ding, Hanping, and Hua, Bin. Methods for co-producing hydrocarbon products and ammonia. United States: N. p., 2023.
Web.
Ding, Dong, Wu, Wei, Ding, Hanping, & Hua, Bin. Methods for co-producing hydrocarbon products and ammonia. United States.
Ding, Dong, Wu, Wei, Ding, Hanping, and Hua, Bin. Tue .
"Methods for co-producing hydrocarbon products and ammonia". United States. https://www.osti.gov/servlets/purl/2222206.
@article{osti_2222206,
title = {Methods for co-producing hydrocarbon products and ammonia},
author = {Ding, Dong and Wu, Wei and Ding, Hanping and Hua, Bin},
abstractNote = {A method of a hydrocarbon product and ammonia comprises introducing C2H6 to a positive electrode of an electrochemical cell comprising the positive electrode, a negative electrode, and a proton-conducting membrane between the positive electrode and the negative electrode. The proton-conducting membrane comprising an electrolyte material having an ionic conductivity greater than or equal to about 10−2 S/cm at one or more temperatures within a range of from about 150° C. to about 600° C. N2 is introduced to the negative electrode of the electrochemical cell. A potential difference is applied between the positive electrode and the negative electrode of the electrochemical cell. A system for co-producing higher hydrocarbons and NH3, and an electrochemical cell are also described.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2023},
month = {8}
}
Works referenced in this record:
Electrochemical Synthesis of Ammonia Using Proton Conducting Solid Electrolyte and Ru-doped BaCe0.9Y0.1O3-δElectrode Catalyst
journal, January 2017
- Kobayashi, Yusuke; Shimoda, Naohiro; Kimura, Yutaka
- ECS Transactions, Vol. 75, Issue 42
Reaction Analysis of Electrochemical Synthesis of Ammonia with Proton Conducting BaCe0.9Y0.1O3Solid Electrolyte
journal, January 2017
- Kosaka, Fumihiko; Nakamura, Takehisa; Otomo, Junichiro
- ECS Transactions, Vol. 75, Issue 43
Solid acids as electrolyte materials for proton exchange membrane (PEM) electrolysis: Review
journal, February 2012
- Goñi-Urtiaga, Asier; Presvytes, Dimitrios; Scott, Keith
- International Journal of Hydrogen Energy, Vol. 37, Issue 4
Ammonia synthesis at atmospheric pressure using a reactor with thin solid electrolyte BaCe0.85Y0.15O3−α membrane
journal, September 2010
- Wang, W. B.; Cao, X. B.; Gao, W. J.
- Journal of Membrane Science, Vol. 360, Issue 1-2
Process for producing compressed hydrogen in a membrane reactor and reactor therefor
patent-application, September 2019
- Kjolseth, Christian; Malerod-Fjeld, Harald; Vestre, Per Kristian
- US Patent Application 16/341691; 20190284048
Protonic membrane for fuel cell for co-generation of power and ethylene
journal, January 2008
- Shi, Zhicong; Luo, Jing-Li; Wang, Shouyan
- Journal of Power Sources, Vol. 176, Issue 1
Solid electrolyte fuel cell and method for manufacture of same
patent, September 1993
- Taniguchi, Noboru; Niikura, Junji; Hatoh, Kazuhito
- US Patent Document 5,244,753
Electrochemical Co-Production of Products with Carbon-Based Reactant Feed to Anode
patent-application, December 2014
- Teamey, Kyle; Kaczur, Jerry J.
- US Patent Application 14/463430; 20140357904
Methods and devices for the production of Hydrocarbons from Carbon and Hydrogen sources
patent-application, November 2008
- Eastman, Craif D.; Hole, Douglas R.
- US Patent Application 12/151206; 20080283411
Solid-state electrochemical synthesis of ammonia: a review
journal, April 2011
- Amar, Ibrahim A.; Lan, Rong; Petit, Christophe T. G.
- Journal of Solid State Electrochemistry, Vol. 15, Issue 9