Emulsion polymerization of nitriles and other compounds
Abstract
The present disclosure relates to a method that includes polymerizing a nitrile with an acrylate ester to form a copolymer, in a mixture that includes water and an alcohol (R2—OH), according to the following reaction where R1 includes at least one of a first aliphatic group or hydrogen, R2 comprises at least one of a second aliphatic group or hydrogen, 100≤m≤4000, and 1≤n≤4000. In some embodiments of the present disclosure, the mixture may be an emulsion.
- Inventors:
- Issue Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); National Renewable Energy Laboratory (NREL), Golden, CO (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 2222192
- Patent Number(s):
- 11732385
- Application Number:
- 16/396,862
- Assignee:
- Alliance for Sustainable Energy, LLC (Golden, CO); UT-BATTELLE, LLC (Oak Ridge, TN)
- DOE Contract Number:
- AC05-00OR22725; AC36-08GO028308
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 04/29/2019
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Meek, Kelly Marie, Eaton, Todd R., Rorrer, Nicholas A., Karp, Eric M., and Naskar, Amit Kumar. Emulsion polymerization of nitriles and other compounds. United States: N. p., 2023.
Web.
Meek, Kelly Marie, Eaton, Todd R., Rorrer, Nicholas A., Karp, Eric M., & Naskar, Amit Kumar. Emulsion polymerization of nitriles and other compounds. United States.
Meek, Kelly Marie, Eaton, Todd R., Rorrer, Nicholas A., Karp, Eric M., and Naskar, Amit Kumar. Tue .
"Emulsion polymerization of nitriles and other compounds". United States. https://www.osti.gov/servlets/purl/2222192.
@article{osti_2222192,
title = {Emulsion polymerization of nitriles and other compounds},
author = {Meek, Kelly Marie and Eaton, Todd R. and Rorrer, Nicholas A. and Karp, Eric M. and Naskar, Amit Kumar},
abstractNote = {The present disclosure relates to a method that includes polymerizing a nitrile with an acrylate ester to form a copolymer, in a mixture that includes water and an alcohol (R2—OH), according to the following reaction where R1 includes at least one of a first aliphatic group or hydrogen, R2 comprises at least one of a second aliphatic group or hydrogen, 100≤m≤4000, and 1≤n≤4000. In some embodiments of the present disclosure, the mixture may be an emulsion.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2023},
month = {8}
}
Works referenced in this record:
High performance carbon fibers from very high molecular weight polyacrylonitrile precursors
journal, May 2016
- Morris, E. Ashley; Weisenberger, Matthew C.; Abdallah, Mohamed G.
- Carbon, Vol. 101
Acid Resistant PBI Membrane for Pervaporation Dehydration of Acidic Solvents
patent-application, November 2013
- Wang, Yan; Gruender, Michael; Chung, Tai-Shung
- US Patent Application 13/480522; 20130313192
Synthesis, spinning, and properties of very high molecular weight poly(acrylonitrile-co-methyl acrylate) for high performance precursors for carbon fiber
journal, December 2014
- Morris, E. Ashley; Weisenberger, Matthew C.; Bradley, Stephanie B.
- Polymer, Vol. 55, Issue 25
Formation of melt-spun acrylic fibers possessing a highly uniform internal structure which are particularly suited for thermal conversion to quality carbon fibers
patent, June 1990
- Daumit, Gene P.; Ko, Yoon Seok; Slater, Christopher R.
- US Patent Document 4,935,180
Microbial Production of Chemical Products and Related Compositions, Methods and Systems
patent-application, November 2014
- Lynch, Michael D.; Lipscomb, Tanya E. W.; Trahan, Ashley D.
- US Patent Application 14/006014; 20140330032
Renewable acrylonitrile production
journal, December 2017
- Karp, Eric M.; Eaton, Todd R.; Sànchez i. Nogué, Violeta
- Science, Vol. 358, Issue 6368
Process for preparing acetonitrile
patent, December 1979
- Olive, Gisela; Olive, Salvador
- US Patent Document 4,179,462
Method for Cleaving Unsaturated Fatty Chains
patent-application, December 2014
- Brandhorst, Markus; Dubois, Jean-Luc
- US Patent Application 14/361391; 20140357880
Emulsion polymerization of acrylonitrile in aqueous methanol
journal, January 2018
- Meek, Kelly M.; Eaton, Todd R.; Rorrer, Nicholas A.
- Green Chemistry, Vol. 20, Issue 23
Magnetic recording medium comprising a styrene copolymer or an acrylic copolymer
patent, June 1994
- Nakamura, Eitaro; Takano, Fumio
- US Patent Document 5,320,914