Processes for the preparation of alkyl furans using bifunctional copper catalysts
Abstract
The present disclosure relates to the selective hydrodeoxygenation (HDO) of bio-based furanic ketones with a bifunctional copper-based catalyst in the presence of a solvent to prepare alkyl furans with high yield, purity, and scalability. The alkyl furans prepared herein are useful in the preparation of surfactants.
- Inventors:
- Issue Date:
- Research Org.:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 2222063
- Patent Number(s):
- 11718598
- Application Number:
- 17/032,777
- Assignee:
- Triad National Security, LLC (Los Alamos, NM)
- DOE Contract Number:
- 89233218CNA000001
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 09/25/2020
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Sutton, Andrew, Yang, Xiaokun, and Moore, Cameron M. Processes for the preparation of alkyl furans using bifunctional copper catalysts. United States: N. p., 2023.
Web.
Sutton, Andrew, Yang, Xiaokun, & Moore, Cameron M. Processes for the preparation of alkyl furans using bifunctional copper catalysts. United States.
Sutton, Andrew, Yang, Xiaokun, and Moore, Cameron M. Tue .
"Processes for the preparation of alkyl furans using bifunctional copper catalysts". United States. https://www.osti.gov/servlets/purl/2222063.
@article{osti_2222063,
title = {Processes for the preparation of alkyl furans using bifunctional copper catalysts},
author = {Sutton, Andrew and Yang, Xiaokun and Moore, Cameron M.},
abstractNote = {The present disclosure relates to the selective hydrodeoxygenation (HDO) of bio-based furanic ketones with a bifunctional copper-based catalyst in the presence of a solvent to prepare alkyl furans with high yield, purity, and scalability. The alkyl furans prepared herein are useful in the preparation of surfactants.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2023},
month = {8}
}
Works referenced in this record:
Structural Features for Furan-Derived Fruity and Meaty Aroma Impressions
journal, October 2016
- Wailzer, Bettina; Klocker, Johanna; Wolschann, Peter
- Natural Product Communications, Vol. 11, Issue 10
Production of p -Methylstyrene and p -Divinylbenzene from Furanic Compounds
journal, December 2016
- Koehle, Maura; Saraçi, Erisa; Dauenhauer, Paul
- ChemSusChem, Vol. 10, Issue 1
Constituents of the leaf essential oil of Persea indica (L.) K. Spreng.
journal, July 1993
- Weyerstahl, Peter; Marschall, Helga; Scora, Rainer W.
- Flavour and Fragrance Journal, Vol. 8, Issue 4
Lipidic furans useful for skin therapeutics
patent, November 1995
- Huber, S. Richard; Counts, David F.
- US Patent Document 5,468,490
Process for obtaining a furan lipid-rich unsaponifiable material from avocado
patent, February 2006
- Piccirilli, Antoine; Legrand, Jacques
- US Patent Document 6,994,875
Method for the Extraction of Furan Derivative Compounds from Seeds of Hass Avocado (Persea American Mill) at Low Temperature and Their Use as Repellants and Miticides Against Tetranychus Urticae, Tetranychus Cinnabarinus, Oligonychus Yothersi, Panonychus Citri, and Brevipalpus Chilensis
patent-application, October 2014
- Mesina, Robinson Vargas
- US Patent Application 14/310297; 20140303114
Alkylfurans: Effects of Alkyl Side-Chain Length on Insecticidal Activity
journal, November 1998
- Rodriguez-Saona, Cesar R.; Maynard, David F.; Phillips, Scott
- Journal of Natural Products, Vol. 62, Issue 1
Method for producing rosefuran precursor and intermediates therefor
patent, May 1997
- Fukawa, Hidemichi; Nishitani, Masamichi; Chiba, Mitsuo
- US Patent Document 5,627,288