Electrolytes for lithium-ion batteries operating at extreme conditions

Cao, Xia; Zhang, Ji-Guang; Xu, Wu

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Title: Electrolytes for lithium-ion batteries operating at extreme conditions

Abstract

Electrolytes for lithium ion batteries with carbon-based, silicon-based, or carbon- and silicon-based anodes include a lithium salt; a nonaqueous solvent comprising at least one of the following components: (i) an ester, (ii) a sulfur-containing solvent, (iii) a phosphorus-containing solvent, (iv) an ether, (v) a nitrile, or any combination thereof, wherein the lithium salt is soluble in the solvent; a diluent comprising a fluoroalkyl ether, a fluorinated orthoformate, a fluorinated carbonate, a fluorinated borate, a fluorinated phosphate, a fluorinated phosphite, or any combination thereof, wherein the lithium salt has a solubility in the diluent at least 10 times less than a solubility of the lithium salt in the solvent; and an additive having a different composition than the lithium salt, a different composition than the solvent, and a different composition than the diluent. In some electrolytes, the nonaqueous solvent comprises an ester.

Inventors:: Cao, Xia; Zhang, Ji-Guang; Xu, Wu

Issue Date:: 2023-07-18

Research Org.:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 2221987

Patent Number(s):: 11705580

Application Number:: 17/537,149

Assignee:: Battelle Memorial Institute (Richland, WA)

DOE Contract Number:: AC05-76RL01830; EE0008444

Resource Type:: Patent

Resource Relation:: Patent File Date: 11/29/2021

Country of Publication:: United States

Language:: English

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                    Cao, Xia, Zhang, Ji-Guang, and Xu, Wu. Electrolytes for lithium-ion batteries operating at extreme conditions.  United States: N. p., 2023. 
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                    Cao, Xia, Zhang, Ji-Guang, & Xu, Wu. Electrolytes for lithium-ion batteries operating at extreme conditions.  United States.

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                    Cao, Xia, Zhang, Ji-Guang, and Xu, Wu. Tue .  
        "Electrolytes for lithium-ion batteries operating at extreme conditions".  United States.  https://www.osti.gov/servlets/purl/2221987.

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@article{osti_2221987,

  title        = {Electrolytes for lithium-ion batteries operating at extreme conditions},

  author       = {Cao, Xia and Zhang, Ji-Guang and Xu, Wu},

  abstractNote = {Electrolytes for lithium ion batteries with carbon-based, silicon-based, or carbon- and silicon-based anodes include a lithium salt; a nonaqueous solvent comprising at least one of the following components: (i) an ester, (ii) a sulfur-containing solvent, (iii) a phosphorus-containing solvent, (iv) an ether, (v) a nitrile, or any combination thereof, wherein the lithium salt is soluble in the solvent; a diluent comprising a fluoroalkyl ether, a fluorinated orthoformate, a fluorinated carbonate, a fluorinated borate, a fluorinated phosphate, a fluorinated phosphite, or any combination thereof, wherein the lithium salt has a solubility in the diluent at least 10 times less than a solubility of the lithium salt in the solvent; and an additive having a different composition than the lithium salt, a different composition than the solvent, and a different composition than the diluent. In some electrolytes, the nonaqueous solvent comprises an ester.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2023},

  month        = {7}

}

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Works referenced in this record:

High rate and stable cycling of lithium metal anode
journal, February 2015

Qian, Jiangfeng; Henderson, Wesley A.; Xu, Wu
Nature Communications, Vol. 6, Issue 1
https://doi.org/10.1038/ncomms7362

Lithium-Ion Electrolytes Containing Flame-Retardant Additives for Increased Safety Characteristics
journal, August 2009

Smith, Kiah A.; Smart, Marshall C.; Prakash, G. K. Surya
ECS Transactions, Vol. 16, Issue 35
https://doi.org/10.1149/1.3123125

Method for Producing Lithium Fluorosulfonate, Lithium Fluorosulfonate, Nonaqueous Electrolytic Solution, and Nonaqueous Electrolytic Solution Secondary Battery
patent-application, February 2014

Kawakami, Daisuke; Yamaguchi, Ryo; Tokuda, Hiroyuki
US Patent Application 14/051883; 20140038062
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20140038062

Localized Superconcentrated Electrolytes for Stable Cycling of Electrochemical Devices
patent-application, September 2018

Zhang, Ji-Guang; Zheng, Jinaming; Chen, Shuru
US Patent Application 15/599298; 20180254524
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20180254524

Dimethyl methylphosphonate (DMMP) as an efficient flame retardant additive for the lithium-ion battery electrolytes
journal, November 2007

Xiang, H. F.; Xu, H. Y.; Wang, Z. Z.
Journal of Power Sources, Vol. 173, Issue 1
https://doi.org/10.1016/j.jpowsour.2007.05.001

Electrolyte for Stable Cycling of Rechargeable Alkali Metal and Alkali Ion Batteries
patent-application, May 2020

Cao, Xia; Xhang, Ji-Guang; Xu, Wu
US Patent Application 16/688929; 20200161706
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20200161706

Determining oxidative stability of battery electrolytes: validity of common electrochemical stability window (ESW) data and alternative strategies
journal, January 2017

Kasnatscheew, J.; Streipert, B.; Röser, S.
Physical Chemistry Chemical Physics, Vol. 19, Issue 24
https://doi.org/10.1039/C7CP03072J

Tris(2,2,2-trifluoroethyl) phosphite as a co-solvent for nonflammable electrolytes in Li-ion batteries
journal, January 2003

Zhang, S. S.; Xu, K.; Jow, T. R.
Journal of Power Sources, Vol. 113, Issue 1
https://doi.org/10.1016/S0378-7753(02)00537-2

Electrolyte additive enabled fast charging and stable cycling lithium metal batteries
journal, March 2017

Zheng, Jianming; Engelhard, Mark H.; Mei, Donghai
Nature Energy, Vol. 2, Issue 3
https://doi.org/10.1038/nenergy.2017.12

Electrochemical performance of lithium-ion batteries with triphenylphosphate as a flame-retardant additive
journal, October 2007

Shim, Eun-Gi; Nam, Tae-Heum; Kim, Jung-Gu
Journal of Power Sources, Vol. 172, Issue 2
https://doi.org/10.1016/j.jpowsour.2007.04.088

Secondary Battery; Solar Power Generation System, Wind Power Generation System, and Vehicle Provided Therewith; and Method for Fabrication of a Secondary Battery
patent-application, August 2011

Watanabe, Yuki; Nishimura, Naoto; Sakashita, Kazuya
US Patent Application 13/027631; 20110200855
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110200855

Electrolyte for a Lithium Ion Battery
patent-application, May 2011

Halalay, Ion C.; Frisch, Damon R.; Geiculescu, Olt E.
US Patent Application 12/902120; 20110111308
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110111308

Review—Superconcentrated Electrolytes for Lithium Batteries
journal, January 2015

Yamada, Yuki; Yamada, Atsuo
Journal of The Electrochemical Society, Vol. 162, Issue 14
https://doi.org/10.1149/2.0041514jes

Alkali metal/niobium triselenide cell having a dioxolane-based electrolyte
patent, April 1978

Whittingham, M. Stanley; Newman, Gerald H.
US Patent Document 4,086,403
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4086403

Electrolytes: Advanced Electrolytes for Fast‐Charging High‐Voltage Lithium‐Ion Batteries in Wide‐Temperature Range (Adv. Energy Mater. 22/2020)
journal, June 2020

Zhang, Xianhui; Zou, Lianfeng; Xu, Yaobin
Advanced Energy Materials, Vol. 10, Issue 22
https://doi.org/10.1002/aenm.202070098

Flame-retardant additives for lithium-ion batteries
journal, June 2003

Hyung, Yoo E.; Vissers, Donald R.; Amine, Khalil
Journal of Power Sources, Vol. 119-121
https://doi.org/10.1016/S0378-7753(03)00225-8

A Novel Flame-Retardant Additive for Lithium Batteries
journal, January 1999

Lee, Chang Woo
Electrochemical and Solid-State Letters, Vol. 3, Issue 2
https://doi.org/10.1149/1.1390959

The Evaluation of Triphenyl Phosphate as A Flame Retardant Additive to Improve The Safety of Lithium-Ion Battery Electrolytes
journal, April 2011

Smart, Marshall C.; Krause, Frederick C.; Hwang, Constanza
ECS Transactions, Vol. 35, Issue 13
https://doi.org/10.1149/1.3646164

Lithium-Ion Electrolytes with Improved Safety Tolerance to High Voltage Systems
patent-application, June 2012

Smart, Marshall C.; Bugga, Ratnakuma V.; Prakash, Surya G.
US Patent Application 13/396322; 20120141883
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120141883

Raman spectroscopic method for determining the ligand binding capacity of biologicals
patent, March 2000

Grow, Ann E.
US Patent Document 6,040,191
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6040191

Thermal Behavior of Charged Graphite and Li[sub x]CoO[sub 2] in Electrolytes Containing Alkyl Phosphate for Lithium-Ion Cells
journal, January 2009

Shigematsu, Yasuyuki; Ue, Makoto; Yamaki, Jun-ichi
Journal of The Electrochemical Society, Vol. 156, Issue 3
https://doi.org/10.1149/1.3056035

"Water-in-salt" electrolyte enables high-voltage aqueous lithium-ion chemistries
journal, November 2015

Suo, L.; Borodin, O.; Gao, T.
Science, Vol. 350, Issue 6263
https://doi.org/10.1126/science.aab1595

Lithium metal anodes for rechargeable batteries
journal, January 2014

Xu, Wu; Wang, Jiulin; Ding, Fei
Energy Environ. Sci., Vol. 7, Issue 2
https://doi.org/10.1039/C3EE40795K

A highly safe battery with a non-flammable triethyl-phosphate-based electrolyte
journal, January 2015

Matsumoto, Kazuaki; Inoue, Kazuhiko; Utsugi, Koji
Journal of Power Sources, Vol. 273
https://doi.org/10.1016/j.jpowsour.2014.09.086

Electrolyte Structure for Metal Batteries
patent-application, September 2016

Cai, Mei; Lu, Yunfeng; Yang, Li
US Patent Application 15/055306; 20160254567
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20160254567

Atomic structure of sensitive battery materials and interfaces revealed by cryo–electron microscopy
journal, October 2017

Li, Yuzhang; Li, Yanbin; Pei, Allen
Science, Vol. 358, Issue 6362
https://doi.org/10.1126/science.aam6014

High Salt Concentration Electrolytes For Rechargeable Lithium Battery
patent-application, August 2016

Tiruvannamalai, Arunkumar; Hwang, Jaehee; Li, Xiaobo
US Patent Application 15/018579; 20160233549
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20160233549

Nonflammable Electrolytes for Li-Ion Batteries Based on a Fluorinated Phosphate
journal, January 2002

Xu, Kang; Zhang, Shengshui; Allen, Jan L.
Journal of The Electrochemical Society, Vol. 149, Issue 8
https://doi.org/10.1149/1.1490356

Perfluoroalkyl-substituted ethylene carbonates: Novel electrolyte additives for high-voltage lithium-ion batteries
journal, January 2014

Zhu, Ye; Casselman, Matthew D.; Li, Yan
Journal of Power Sources, Vol. 246
https://doi.org/10.1016/j.jpowsour.2013.07.070

Negative Electrode for Lithium Battery and Lithium Battery Comprisin the Same
patent-application, November 2016

Lee, Yonggun; Sugimoto, Toshinori; Yang, Yooseong
US Patent Application 14/875951; 20160329567
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20160329567

Hydrofluoroether Compound, Nonaqueous Electrolyte Solution and Lithium Ion Secondary Battery
patent-application, April 2018

Maeda, Katsumi
US Patent Application 15/560807; 20180115020
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20180115020

Nonflammable Trimethyl Phosphate Solvent-Containing Electrolytes for Lithium-Ion Batteries: I. Fundamental Properties
journal, January 2001

Wang, Xianming; Yasukawa, Eiki; Kasuya, Shigeaki
Journal of The Electrochemical Society, Vol. 148, Issue 10
https://doi.org/10.1149/1.1397773

Electrolyte for Electrochemical Energy Storage Devices
patent-application, January 2016

Rhodes, Christopher P.; Mullings, Matthew E.
US Patent Application 14/708079; 20160020489
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20160020489

Nonflammable Trimethyl Phosphate Solvent-Containing Electrolytes for Lithium-Ion Batteries: II. The Use of an Amorphous Carbon Anode
journal, January 2001

Wang, Xianming; Yasukawa, Eiki; Kasuya, Shigeaki
Journal of The Electrochemical Society, Vol. 148, Issue 10
https://doi.org/10.1149/1.1397774

Enabling High-Voltage Lithium-Metal Batteries under Practical Conditions
journal, July 2019

Ren, Xiaodi; Zou, Lianfeng; Cao, Xia
Joule, Vol. 3, Issue 7
https://doi.org/10.1016/j.joule.2019.05.006

Fire-extinguishing organic electrolytes for safe batteries
journal, November 2017

Wang, Jianhui; Yamada, Yuki; Sodeyama, Keitaro
Nature Energy, Vol. 3, Issue 1
https://doi.org/10.1038/s41560-017-0033-8

Non-Aqueous Electrolyte Solution for Secondary Batteries, and Secondary Battery
patent-application, August 2012

Iwaya, Masao; Onozaki, Yu
US Patent Application 13/456787; 20120214073
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120214073

Synthesis and Evaluation of Difluorophosphate Salt Electrolyte Additives for Lithium-Ion Batteries
journal, January 2020

Hall, David S.; Hynes, Toren; Aiken, Connor P.
Journal of The Electrochemical Society, Vol. 167, Issue 10
https://doi.org/10.1149/1945-7111/ab9b96

Lithium Metal Battery
patent-application, March 2017

Ryu, Saebom; Lee, Yonggun; Park, Joungwon
US Patent Application 15/230593; 20170062829
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20170062829

Electrolyte for lithium secondary battery and lithium secondary battery including the same
patent, March 2021

Oh, Jeong Woo; Ahn, Kyoung Ho; Han, Jun Hyeok
US Patent Document 10,950,895
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/10950895

Cathode Additive for Rechargeable Sodium Batteries
patent-application, January 2017

Goodenough, John B.; Park, Kyusung
US Patent Application 15/196670; 20170005327
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20170005327

Electrolyte Solution and Secondary Battery Using Same
patent-application, June 2017

Katou, Yuukou; Noguchi, Takehiro; Takahashi, Makiko
US Patent Application 15/327205; 20170162910
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20170162910

Ionic Liquid Electrolyte and Fluorinated Carbon Electrode
patent-application, December 2015

Wijaya, Olivia; Yazami, Rachid
US Patent Application 14/761589; 20150364801
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20150364801

Self-extinguishing electrolytes using fluorinated alkyl phosphates for lithium batteries
journal, January 2017

Shiga, Tohru; Kato, Yuichi; Kondo, Hiroki
Journal of Materials Chemistry A, Vol. 5, Issue 10
https://doi.org/10.1039/C6TA09915G

LiPF ₆ Stabilizer and Transition-Metal Cation Scavenger: A Bifunctional Bipyridine-Based Ligand for Lithium-Ion Battery Application
journal, May 2019

Jia, Hao; Billmann, Bastian; Onishi, Hitoshi
Chemistry of Materials, Vol. 31, Issue 11
https://doi.org/10.1021/acs.chemmater.9b00555

Localized superconcentrated electrolytes for stable cycling of electrochemical devices
patent, July 2019

Zhang, Ji-Guang; Zheng, Jianming; Chen, Shuru
US Patent Document 10,367,232
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/10367232

Flame retardant battery
patent, August 2014

Tsukamoto, Hisashi
US Patent Document 8,815,453
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8815453

Electrolyte System for Lithium Metal Secondary Battery and Lithium Metal Secondary Battery Including the Same
patent-application, November 2018

Cho, Won Il; Kim, Mun Sek; Ryu, Ji Hynn
US Patent Application 15/975016; 20180331393
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20180331393

High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes
journal, March 2018

Chen, Shuru; Zheng, Jianming; Mei, Donghai
Advanced Materials, Vol. 30, Issue 21
https://doi.org/10.1002/adma.201706102

Dilution of Highly Concentrated LiBF ₄ /Propylene Carbonate Electrolyte Solution with Fluoroalkyl Ethers for 5-V LiNi _0.5 Mn _1.5 O ₄ Positive Electrodes
journal, January 2017

Doi, Takayuki; Shimizu, Yusuke; Hashinokuchi, Michihiro
Journal of The Electrochemical Society, Vol. 164, Issue 1
https://doi.org/10.1149/2.0611701jes

Nonaqueous Electrolyte Secondary Battery
patent-application, December 2012

Kawasaki, Daisuke; Kaneko, Shinako; Iriyama, Jiro
US Patent Application 13/579842; 20120321940
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120321940

Lithium Metal Battery
patent-application, November 2017

Kim, Youngsoo; Lee, Seoksoo; Yu, Taehwan
US Patent Application 15/398132; 20170331152
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20170331152

Localized Superconcentrated Electrolytes for Silicon Anodes
patent-application, May 2019

Zhang, Ji-Guang; Jia, Haiping; Li, Xiaolin
US Patent Application 16/247143; 20190148775
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20190148775

High Coulombic Efficiency Cycling of Metal Batteries
patent-application, August 2016

Zhang, Ji-Guang; Adams, Brian D. G.; Xu, Wu
US Patent Application 15/142322; 20160240896
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20160240896

Lithium Energy Storage Device
patent-application, May 2014

Best, Adam Samuel; Lane, George Hamilton
US Patent Application 14/064395; 20140125292
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20140125292

Battery Cell and Battery
patent-application, May 2017

Masuda, Hideki; Mizutami, Shunsuke; Kawasoe, Yudai
US Patent Application 15/343487; 20170133716
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20170133716

Low Flammability Electrolytes for Stable Operation of Lithium and Sodium Ion Batteries
patent-application, April 2019

Xu, Wu; Chen, Shuru; Zhang, Ji-Guang
US Patent Application 16/119641; 20190123390
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20190123390

Lithium Difluorophosphate as a Dendrite-Suppressing Additive for Lithium Metal Batteries
journal, June 2018

Shi, Pengcheng; Zhang, Linchao; Xiang, Hongfa
ACS Applied Materials & Interfaces, Vol. 10, Issue 26
https://doi.org/10.1021/acsami.8b05185

Electrolyte for Lithium Second Battery, and Lithium Second Battery Comprising the Electrolyte
patent-application, October 2016

Lee, Yonggun; Yang, Yooseong; Chang, Wonseok
US Patent Application 15/089051; 20160294005
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20160294005

Lithium Metal Battery
patent-application, November 2016

Chang, Wonseok; Mizumo, Tomonobu; Sugimoto, Toshinori
US Patent Application 15/047187; 20160344063
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20160344063

Low flammability electrolytes for stable operation of lithium and sodium ion batteries
patent, December 2020

Xu, Wu; Chen, Shuru; Zhang, Ji-Guang
US Patent Document 10,854,923
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/10854923

Lithium Secondary Batteries Containing Lithium Salt-ionic Liquid Solvent Electrolyte
patent-application, November 2014

He, Hui; Jang, Bor Z.; Wang, Yanbo
US Patent Application 13/986576; 20140342249
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20140342249

Comparative study of trimethyl phosphite and trimethyl phosphate as electrolyte additives in lithium ion batteries
journal, June 2005

Yao, X. L.; Xie, S.; Chen, C. H.
Journal of Power Sources, Vol. 144, Issue 1
https://doi.org/10.1016/j.jpowsour.2004.11.042

Low flammability electrolytes for stable operation of electrochemical devices
patent, November 2019

Zhang, Ji-Guang; Chen, Shuru; Xu, Wu
US Patent Document 10,472,571
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/10472571

High Efficiency Electrolytes for High Voltage Battery Systems
patent-application, May 2019

Ren, Xiaodi; Xu, Wu; Zhang, Ji-Guang
US Patent Application 16/230531; 20190140322
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20190140322

Low Flammability Electrolytes for Stable Operation of Electrochemical Devices
patent-application, September 2018

Zhang, Ji-Guang; Chen, Shuru; Xu, Wu
US Patent Application 15/788188; 20180251681
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20180251681

Flame Retardant Electrolyte for Rechargeable Lithium Battery and Rechargeable Lithium Battery Including the Same
patent-application, August 2010

Choi, Nam-Soon; Profatilova, Irina; Roh, Sae-Weon
US Patent Application 12/582668; 20100209782
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100209782

Li ⁺ -Desolvation Dictating Lithium-Ion Battery’s Low-Temperature Performances
journal, November 2017

Li, Qiuyan; Lu, Dongping; Zheng, Jianming
ACS Applied Materials & Interfaces, Vol. 9, Issue 49
https://doi.org/10.1021/acsami.7b13887

Lithium Metal Battery
patent-application, April 2017

Kim, Jusik; Kim, Hyunseok; Ryu, Saebom
US Patent Application 15/221743; 20170098858
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20170098858

Engineering Needs Immigration
journal, January 2019

Jan, Alexander
The Engineer, Vol. 298, Issue 7904
https://doi.org/10.12968/S0013-7758(23)90341-7

Lithium Difluorophosphate As a Promising Electrolyte Lithium Additive for High-Voltage Lithium-Ion Batteries
journal, May 2018

Wang, Chengyun; Yu, Le; Fan, Weizhen
ACS Applied Energy Materials, Vol. 1, Issue 6
https://doi.org/10.1021/acsaem.8b00342

Localized high concentration electrolyte behavior near a lithium–metal anode surface
journal, January 2019

Zheng, Yu; Soto, Fernando A.; Ponce, Victor
Journal of Materials Chemistry A, Vol. 7, Issue 43
https://doi.org/10.1039/C9TA08935G

An Attempt to Formulate Nonflammable Lithium Ion Electrolytes with Alkyl Phosphates and Phosphazenes
journal, January 2002

Xu, Kang; Ding, Michael S.; Zhang, Shengshui
Journal of The Electrochemical Society, Vol. 149, Issue 5
https://doi.org/10.1149/1.1467946

Lithium Secondary Battery
patent-application, June 2016

Kim, Dongyoung; Seo, Jinah; Park, Hosang
US Patent Application 14/982812; 20160190646
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20160190646

Electrolyte System for High Voltage Lithium Ion Battery
patent-application, August 2016

Hwang, Jaehee; Li, Xiaobo; Hu, Qichao
US Patent Application 15/049528; 20160248122
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20160248122

Superconcentrated electrolytes for a high-voltage lithium-ion battery
journal, June 2016

Wang, Jianhui; Yamada, Yuki; Sodeyama, Keitaro
Nature Communications, Vol. 7, Issue 1
https://doi.org/10.1038/ncomms12032

Effects of Carbonate Solvents and Lithium Salts on Morphology and Coulombic Efficiency of Lithium Electrode
journal, January 2013

Ding, Fei; Xu, Wu; Chen, Xilin
Journal of The Electrochemical Society, Vol. 160, Issue 10
https://doi.org/10.1149/2.100310jes

Rechargeable Lithium Ion Battery, and Manufacturing Method for Rechargeable Lithium Ion Battery
patent-application, April 2015

Takase, Hironari; Yokotsuji, Hokuto
US Patent Application 14/525736; 20150118581
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20150118581

Methylene ethylene carbonate: Novel additive to improve the high temperature performance of lithium ion batteries
journal, June 2012

Chalasani, Dinesh; Li, Jing; Jackson, Nicole M.
Journal of Power Sources, Vol. 208
https://doi.org/10.1016/j.jpowsour.2012.02.004

Nonaqueous Electrolyte Solution and Secondary Battery Using the Electrolyte Solution
patent-application, October 2007

Yamamoto, Kouhei; Suzuki, Satoru; Yamada, Manabu
US Patent Application 11/783961; 20070243470
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20070243470

Negative Electrode for Ltihium Metal Battery and Lithium Metal Battery Including the Same
patent-application, December 2016

Yang, Yooseong; Jeong, Joonseon
US Patent Application 15/189042; 20160380314
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20160380314

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Low flammability and nonflammable localized superconcentrated electrolytes (LSEs) for stable operation of lithium and sodium ion batteries are disclosed. Electrochemical devices including the low flammability and nonflammable LSEs are also disclosed. The low flammability and nonflammable LSEs include an active salt, a solvent comprising a flame retardant compound, wherein the active salt is soluble in the solvent, and a diluent in which the active salt is insoluble or poorly soluble. The LSE may further include a cosolvent, such as a carbonate, a sulfone, a sulfite, a sulfate, a carboxylate, an ether, a nitrogen-containing solvent, or any combination thereof. In certainmore » « less
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Electrolyte additives for lithium-ion batteries under high-voltage operation

Patent Liao, Chen; Peebles, Cameron; Abraham, Daniel; ...

A non-aqueous electrolyte for a lithium-ion battery comprises a lithium salt and an additive in an organic solvent. The additive comprises a di-substituted malonate silyl ester compound, in which the hydrogens of the malonate methylene group are replaced by substituents R1 (e.g., alkyl) and X (e.g., halogen). Each of the carboxylic acid groups of the malonate are esterified by a monovalent silyl group such as —Si(R4)3; or the two carboxylic acid groups are esterified by a single divalent silylene group such as —Si(R5)2— to form a ring therewith. Each R4 and R5 independently is alkyl, phenyl, or alkoxy; and eachmore » « less
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Heteroaromatic-based electrolytes for lithium and lithium-ion batteries

Patent Cheng, Gang; Abraham, Daniel P.

The present invention provides an electrolyte for lithium and/or lithium-ion batteries comprising a lithium salt in a liquid carrier comprising heteroaromatic compound including a five-membered or six-membered heteroaromatic ring moiety selected from the group consisting of a furan, a pyrazine, a triazine, a pyrrole, and a thiophene, the heteroaromatic ring moiety bearing least one carboxylic ester or carboxylic anhydride substituent bound to at least one carbon atom of the heteroaromatic ring. Preferred heteroaromatic ring moieties include pyridine compounds, pyrazine compounds, pyrrole compounds, furan compounds, and thiophene compounds.
Full Text Available
Electrolyte compositions for lithium and lithium-ion batteries

Patent Abraham, Daniel P.; Cheng, Gang

"The present invention provides an electrolyte composition for a lithium or lithium-ion battery comprising a lithium salt in a liquid carrier comprising (a) a linear alkyl carbonate solvent, a cyclic alkyl carbonate solvent, or a combination thereof, and (b) a glycerol carbonate derivative compound of Formula (I):wherein X is selected from O, O(CO)O, S, N, P, P(═O), B, and Si; n is 1 when X is O, O(CO)O, or S; n is 2 when x is N, P, P(═O), or B; n is 3 when X is Si; and each R independently is selected from alkyl, alkenyl, alkynyl, aryl, acyl,more » « less
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Dendrite-suppressing ion-conductors from aramid nanofibers withstanding extreme battery conditions

Patent Kotov, Nicholas A.; Tung, Siu-On; Ho, Szu-Shen; ...

Ion conducting membranes based on aramid nanofibers (ANFs) can be prepared using layer-by-layer assembly, sol-gel processing, evaporation, spin coating, doctor blading, or other methods. Porosity is controlled through choice of additives and processing.
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Title: Electrolytes for lithium-ion batteries operating at extreme conditions

Abstract

Citation Formats

High rate and stable cycling of lithium metal anode journal, February 2015

Lithium-Ion Electrolytes Containing Flame-Retardant Additives for Increased Safety Characteristics journal, August 2009

Method for Producing Lithium Fluorosulfonate, Lithium Fluorosulfonate, Nonaqueous Electrolytic Solution, and Nonaqueous Electrolytic Solution Secondary Battery patent-application, February 2014

Localized Superconcentrated Electrolytes for Stable Cycling of Electrochemical Devices patent-application, September 2018

Dimethyl methylphosphonate (DMMP) as an efficient flame retardant additive for the lithium-ion battery electrolytes journal, November 2007

Electrolyte for Stable Cycling of Rechargeable Alkali Metal and Alkali Ion Batteries patent-application, May 2020

Determining oxidative stability of battery electrolytes: validity of common electrochemical stability window (ESW) data and alternative strategies journal, January 2017

Tris(2,2,2-trifluoroethyl) phosphite as a co-solvent for nonflammable electrolytes in Li-ion batteries journal, January 2003

Electrolyte additive enabled fast charging and stable cycling lithium metal batteries journal, March 2017

Electrochemical performance of lithium-ion batteries with triphenylphosphate as a flame-retardant additive journal, October 2007

Secondary Battery; Solar Power Generation System, Wind Power Generation System, and Vehicle Provided Therewith; and Method for Fabrication of a Secondary Battery patent-application, August 2011

Electrolyte for a Lithium Ion Battery patent-application, May 2011

Review—Superconcentrated Electrolytes for Lithium Batteries journal, January 2015

Alkali metal/niobium triselenide cell having a dioxolane-based electrolyte patent, April 1978

Electrolytes: Advanced Electrolytes for Fast‐Charging High‐Voltage Lithium‐Ion Batteries in Wide‐Temperature Range (Adv. Energy Mater. 22/2020) journal, June 2020

Flame-retardant additives for lithium-ion batteries journal, June 2003

A Novel Flame-Retardant Additive for Lithium Batteries journal, January 1999

The Evaluation of Triphenyl Phosphate as A Flame Retardant Additive to Improve The Safety of Lithium-Ion Battery Electrolytes journal, April 2011

Lithium-Ion Electrolytes with Improved Safety Tolerance to High Voltage Systems patent-application, June 2012

Raman spectroscopic method for determining the ligand binding capacity of biologicals patent, March 2000

Thermal Behavior of Charged Graphite and Li[sub x]CoO[sub 2] in Electrolytes Containing Alkyl Phosphate for Lithium-Ion Cells journal, January 2009

"Water-in-salt" electrolyte enables high-voltage aqueous lithium-ion chemistries journal, November 2015

Lithium metal anodes for rechargeable batteries journal, January 2014

A highly safe battery with a non-flammable triethyl-phosphate-based electrolyte journal, January 2015

Electrolyte Structure for Metal Batteries patent-application, September 2016

Atomic structure of sensitive battery materials and interfaces revealed by cryo–electron microscopy journal, October 2017

High Salt Concentration Electrolytes For Rechargeable Lithium Battery patent-application, August 2016

Nonflammable Electrolytes for Li-Ion Batteries Based on a Fluorinated Phosphate journal, January 2002

Perfluoroalkyl-substituted ethylene carbonates: Novel electrolyte additives for high-voltage lithium-ion batteries journal, January 2014

Negative Electrode for Lithium Battery and Lithium Battery Comprisin the Same patent-application, November 2016

Hydrofluoroether Compound, Nonaqueous Electrolyte Solution and Lithium Ion Secondary Battery patent-application, April 2018

Nonflammable Trimethyl Phosphate Solvent-Containing Electrolytes for Lithium-Ion Batteries: I. Fundamental Properties journal, January 2001

Electrolyte for Electrochemical Energy Storage Devices patent-application, January 2016

Nonflammable Trimethyl Phosphate Solvent-Containing Electrolytes for Lithium-Ion Batteries: II. The Use of an Amorphous Carbon Anode journal, January 2001

Enabling High-Voltage Lithium-Metal Batteries under Practical Conditions journal, July 2019

Fire-extinguishing organic electrolytes for safe batteries journal, November 2017

Non-Aqueous Electrolyte Solution for Secondary Batteries, and Secondary Battery patent-application, August 2012

Synthesis and Evaluation of Difluorophosphate Salt Electrolyte Additives for Lithium-Ion Batteries journal, January 2020

Lithium Metal Battery patent-application, March 2017

Electrolyte for lithium secondary battery and lithium secondary battery including the same patent, March 2021

Cathode Additive for Rechargeable Sodium Batteries patent-application, January 2017

Electrolyte Solution and Secondary Battery Using Same patent-application, June 2017

Ionic Liquid Electrolyte and Fluorinated Carbon Electrode patent-application, December 2015

Self-extinguishing electrolytes using fluorinated alkyl phosphates for lithium batteries journal, January 2017

LiPF 6 Stabilizer and Transition-Metal Cation Scavenger: A Bifunctional Bipyridine-Based Ligand for Lithium-Ion Battery Application journal, May 2019

Localized superconcentrated electrolytes for stable cycling of electrochemical devices patent, July 2019

Flame retardant battery patent, August 2014

Electrolyte System for Lithium Metal Secondary Battery and Lithium Metal Secondary Battery Including the Same patent-application, November 2018

High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes journal, March 2018

Dilution of Highly Concentrated LiBF 4 /Propylene Carbonate Electrolyte Solution with Fluoroalkyl Ethers for 5-V LiNi 0.5 Mn 1.5 O 4 Positive Electrodes journal, January 2017

Nonaqueous Electrolyte Secondary Battery patent-application, December 2012

Lithium Metal Battery patent-application, November 2017

Localized Superconcentrated Electrolytes for Silicon Anodes patent-application, May 2019

High Coulombic Efficiency Cycling of Metal Batteries patent-application, August 2016

Lithium Energy Storage Device patent-application, May 2014

Battery Cell and Battery patent-application, May 2017

Low Flammability Electrolytes for Stable Operation of Lithium and Sodium Ion Batteries patent-application, April 2019

Lithium Difluorophosphate as a Dendrite-Suppressing Additive for Lithium Metal Batteries journal, June 2018

Electrolyte for Lithium Second Battery, and Lithium Second Battery Comprising the Electrolyte patent-application, October 2016

Lithium Metal Battery patent-application, November 2016

Low flammability electrolytes for stable operation of lithium and sodium ion batteries patent, December 2020

Lithium Secondary Batteries Containing Lithium Salt-ionic Liquid Solvent Electrolyte patent-application, November 2014

Comparative study of trimethyl phosphite and trimethyl phosphate as electrolyte additives in lithium ion batteries journal, June 2005

Low flammability electrolytes for stable operation of electrochemical devices patent, November 2019

High Efficiency Electrolytes for High Voltage Battery Systems patent-application, May 2019

Low Flammability Electrolytes for Stable Operation of Electrochemical Devices patent-application, September 2018

Flame Retardant Electrolyte for Rechargeable Lithium Battery and Rechargeable Lithium Battery Including the Same patent-application, August 2010

Li + -Desolvation Dictating Lithium-Ion Battery’s Low-Temperature Performances journal, November 2017

Lithium Metal Battery patent-application, April 2017

Engineering Needs Immigration journal, January 2019

Lithium Difluorophosphate As a Promising Electrolyte Lithium Additive for High-Voltage Lithium-Ion Batteries journal, May 2018

Localized high concentration electrolyte behavior near a lithium–metal anode surface journal, January 2019

An Attempt to Formulate Nonflammable Lithium Ion Electrolytes with Alkyl Phosphates and Phosphazenes journal, January 2002

Lithium Secondary Battery patent-application, June 2016

Electrolyte System for High Voltage Lithium Ion Battery patent-application, August 2016

Superconcentrated electrolytes for a high-voltage lithium-ion battery journal, June 2016

Effects of Carbonate Solvents and Lithium Salts on Morphology and Coulombic Efficiency of Lithium Electrode journal, January 2013

High rate and stable cycling of lithium metal anode
journal, February 2015

Lithium-Ion Electrolytes Containing Flame-Retardant Additives for Increased Safety Characteristics
journal, August 2009

Method for Producing Lithium Fluorosulfonate, Lithium Fluorosulfonate, Nonaqueous Electrolytic Solution, and Nonaqueous Electrolytic Solution Secondary Battery
patent-application, February 2014

Localized Superconcentrated Electrolytes for Stable Cycling of Electrochemical Devices
patent-application, September 2018

Dimethyl methylphosphonate (DMMP) as an efficient flame retardant additive for the lithium-ion battery electrolytes
journal, November 2007

Electrolyte for Stable Cycling of Rechargeable Alkali Metal and Alkali Ion Batteries
patent-application, May 2020

Determining oxidative stability of battery electrolytes: validity of common electrochemical stability window (ESW) data and alternative strategies
journal, January 2017

Tris(2,2,2-trifluoroethyl) phosphite as a co-solvent for nonflammable electrolytes in Li-ion batteries
journal, January 2003

Electrolyte additive enabled fast charging and stable cycling lithium metal batteries
journal, March 2017

Electrochemical performance of lithium-ion batteries with triphenylphosphate as a flame-retardant additive
journal, October 2007

Secondary Battery; Solar Power Generation System, Wind Power Generation System, and Vehicle Provided Therewith; and Method for Fabrication of a Secondary Battery
patent-application, August 2011

Electrolyte for a Lithium Ion Battery
patent-application, May 2011

Review—Superconcentrated Electrolytes for Lithium Batteries
journal, January 2015

Alkali metal/niobium triselenide cell having a dioxolane-based electrolyte
patent, April 1978

Electrolytes: Advanced Electrolytes for Fast‐Charging High‐Voltage Lithium‐Ion Batteries in Wide‐Temperature Range (Adv. Energy Mater. 22/2020)
journal, June 2020

Flame-retardant additives for lithium-ion batteries
journal, June 2003

A Novel Flame-Retardant Additive for Lithium Batteries
journal, January 1999

The Evaluation of Triphenyl Phosphate as A Flame Retardant Additive to Improve The Safety of Lithium-Ion Battery Electrolytes
journal, April 2011

Lithium-Ion Electrolytes with Improved Safety Tolerance to High Voltage Systems
patent-application, June 2012

Raman spectroscopic method for determining the ligand binding capacity of biologicals
patent, March 2000

Thermal Behavior of Charged Graphite and Li[sub x]CoO[sub 2] in Electrolytes Containing Alkyl Phosphate for Lithium-Ion Cells
journal, January 2009

"Water-in-salt" electrolyte enables high-voltage aqueous lithium-ion chemistries
journal, November 2015

Lithium metal anodes for rechargeable batteries
journal, January 2014

A highly safe battery with a non-flammable triethyl-phosphate-based electrolyte
journal, January 2015

Electrolyte Structure for Metal Batteries
patent-application, September 2016

Atomic structure of sensitive battery materials and interfaces revealed by cryo–electron microscopy
journal, October 2017

High Salt Concentration Electrolytes For Rechargeable Lithium Battery
patent-application, August 2016

Nonflammable Electrolytes for Li-Ion Batteries Based on a Fluorinated Phosphate
journal, January 2002

Perfluoroalkyl-substituted ethylene carbonates: Novel electrolyte additives for high-voltage lithium-ion batteries
journal, January 2014

Negative Electrode for Lithium Battery and Lithium Battery Comprisin the Same
patent-application, November 2016

Hydrofluoroether Compound, Nonaqueous Electrolyte Solution and Lithium Ion Secondary Battery
patent-application, April 2018

Nonflammable Trimethyl Phosphate Solvent-Containing Electrolytes for Lithium-Ion Batteries: I. Fundamental Properties
journal, January 2001

Electrolyte for Electrochemical Energy Storage Devices
patent-application, January 2016

Nonflammable Trimethyl Phosphate Solvent-Containing Electrolytes for Lithium-Ion Batteries: II. The Use of an Amorphous Carbon Anode
journal, January 2001

Enabling High-Voltage Lithium-Metal Batteries under Practical Conditions
journal, July 2019

Fire-extinguishing organic electrolytes for safe batteries
journal, November 2017

Non-Aqueous Electrolyte Solution for Secondary Batteries, and Secondary Battery
patent-application, August 2012

Synthesis and Evaluation of Difluorophosphate Salt Electrolyte Additives for Lithium-Ion Batteries
journal, January 2020

Lithium Metal Battery
patent-application, March 2017

Electrolyte for lithium secondary battery and lithium secondary battery including the same
patent, March 2021

Cathode Additive for Rechargeable Sodium Batteries
patent-application, January 2017

Electrolyte Solution and Secondary Battery Using Same
patent-application, June 2017

Ionic Liquid Electrolyte and Fluorinated Carbon Electrode
patent-application, December 2015

Self-extinguishing electrolytes using fluorinated alkyl phosphates for lithium batteries
journal, January 2017

LiPF ₆ Stabilizer and Transition-Metal Cation Scavenger: A Bifunctional Bipyridine-Based Ligand for Lithium-Ion Battery Application
journal, May 2019

Localized superconcentrated electrolytes for stable cycling of electrochemical devices
patent, July 2019

Flame retardant battery
patent, August 2014

Electrolyte System for Lithium Metal Secondary Battery and Lithium Metal Secondary Battery Including the Same
patent-application, November 2018

High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes
journal, March 2018

Dilution of Highly Concentrated LiBF ₄ /Propylene Carbonate Electrolyte Solution with Fluoroalkyl Ethers for 5-V LiNi _0.5 Mn _1.5 O ₄ Positive Electrodes
journal, January 2017

Nonaqueous Electrolyte Secondary Battery
patent-application, December 2012

Lithium Metal Battery
patent-application, November 2017

Localized Superconcentrated Electrolytes for Silicon Anodes
patent-application, May 2019

High Coulombic Efficiency Cycling of Metal Batteries
patent-application, August 2016

Lithium Energy Storage Device
patent-application, May 2014

Battery Cell and Battery
patent-application, May 2017

Low Flammability Electrolytes for Stable Operation of Lithium and Sodium Ion Batteries
patent-application, April 2019

Lithium Difluorophosphate as a Dendrite-Suppressing Additive for Lithium Metal Batteries
journal, June 2018

Electrolyte for Lithium Second Battery, and Lithium Second Battery Comprising the Electrolyte
patent-application, October 2016

Lithium Metal Battery
patent-application, November 2016

Low flammability electrolytes for stable operation of lithium and sodium ion batteries
patent, December 2020

Lithium Secondary Batteries Containing Lithium Salt-ionic Liquid Solvent Electrolyte
patent-application, November 2014

Comparative study of trimethyl phosphite and trimethyl phosphate as electrolyte additives in lithium ion batteries
journal, June 2005

Low flammability electrolytes for stable operation of electrochemical devices
patent, November 2019

High Efficiency Electrolytes for High Voltage Battery Systems
patent-application, May 2019

Low Flammability Electrolytes for Stable Operation of Electrochemical Devices
patent-application, September 2018

Flame Retardant Electrolyte for Rechargeable Lithium Battery and Rechargeable Lithium Battery Including the Same
patent-application, August 2010

Li ⁺ -Desolvation Dictating Lithium-Ion Battery’s Low-Temperature Performances
journal, November 2017

Lithium Metal Battery
patent-application, April 2017

Engineering Needs Immigration
journal, January 2019

Lithium Difluorophosphate As a Promising Electrolyte Lithium Additive for High-Voltage Lithium-Ion Batteries
journal, May 2018

Localized high concentration electrolyte behavior near a lithium–metal anode surface
journal, January 2019

An Attempt to Formulate Nonflammable Lithium Ion Electrolytes with Alkyl Phosphates and Phosphazenes
journal, January 2002

Lithium Secondary Battery
patent-application, June 2016

Electrolyte System for High Voltage Lithium Ion Battery
patent-application, August 2016

Superconcentrated electrolytes for a high-voltage lithium-ion battery
journal, June 2016

Effects of Carbonate Solvents and Lithium Salts on Morphology and Coulombic Efficiency of Lithium Electrode
journal, January 2013

Rechargeable Lithium Ion Battery, and Manufacturing Method for Rechargeable Lithium Ion Battery
patent-application, April 2015

Methylene ethylene carbonate: Novel additive to improve the high temperature performance of lithium ion batteries
journal, June 2012

Nonaqueous Electrolyte Solution and Secondary Battery Using the Electrolyte Solution
patent-application, October 2007