Metal-ligand catalysts for selective promotion of electrochemical CO2RR
Abstract
The electrochemical carbon dioxide reduction reaction (CO2RR) provides opportunities to synthesize value-added products from this greenhouse gas in a sustainable manner. Efficient catalysts for this reaction are provided that selectively drive CO2 reduction over the thermodynamic and kinetically competitive hydrogen evolution reaction (HER) in organic or aqueous electrolytes. The catalysts are metal-polypyridyl coordination complexes of a redox non-innocent terpyridine-based pentapyridine ligand and a first-row transition metal. The metal-ligand cooperativity in [Fe(tpyPY2Me)]2+ drives the electrochemical reduction of CO2 to CO at low overpotentials with high selectivity for CO2RR (>90%).
- Inventors:
- Issue Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 2221959
- Patent Number(s):
- 11697663
- Application Number:
- 17/164,281
- Assignee:
- The Regents of the University of California (Oakland, CA)
- DOE Contract Number:
- AC02-05CH11231
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 02/01/2021
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Derrick, Jeffrey S., Loipersberger, Matthias, Long, Jeffrey R., Head-Gordon, Martin, and Chang, Christopher J. Metal-ligand catalysts for selective promotion of electrochemical CO2RR. United States: N. p., 2023.
Web.
Derrick, Jeffrey S., Loipersberger, Matthias, Long, Jeffrey R., Head-Gordon, Martin, & Chang, Christopher J. Metal-ligand catalysts for selective promotion of electrochemical CO2RR. United States.
Derrick, Jeffrey S., Loipersberger, Matthias, Long, Jeffrey R., Head-Gordon, Martin, and Chang, Christopher J. Tue .
"Metal-ligand catalysts for selective promotion of electrochemical CO2RR". United States. https://www.osti.gov/servlets/purl/2221959.
@article{osti_2221959,
title = {Metal-ligand catalysts for selective promotion of electrochemical CO2RR},
author = {Derrick, Jeffrey S. and Loipersberger, Matthias and Long, Jeffrey R. and Head-Gordon, Martin and Chang, Christopher J.},
abstractNote = {The electrochemical carbon dioxide reduction reaction (CO2RR) provides opportunities to synthesize value-added products from this greenhouse gas in a sustainable manner. Efficient catalysts for this reaction are provided that selectively drive CO2 reduction over the thermodynamic and kinetically competitive hydrogen evolution reaction (HER) in organic or aqueous electrolytes. The catalysts are metal-polypyridyl coordination complexes of a redox non-innocent terpyridine-based pentapyridine ligand and a first-row transition metal. The metal-ligand cooperativity in [Fe(tpyPY2Me)]2+ drives the electrochemical reduction of CO2 to CO at low overpotentials with high selectivity for CO2RR (>90%).},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2023},
month = {7}
}
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