Methods for producing hydrocarbon products and hydrogen gas through electrochemical activation of methane

Ding, Dong; He, Ting; Wu, Wei; Zhang, Yunya

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Title: Methods for producing hydrocarbon products and hydrogen gas through electrochemical activation of methane

Abstract

A method of forming a hydrocarbon product and hydrogen gas comprises introducing CH₄ to a positive electrode of an electrochemical cell comprising the positive electrode, a negative electrode, and a proton-conducting membrane between the positive electrode and the negative electrode. The proton-conducting membrane comprises an electrolyte material having an ionic conductivity greater than or equal to about 10⁻² S/cm at one or more temperatures within a range of from about 150° C. to about 600° C. A potential difference is applied between the positive electrode and the negative electrode of the electrochemical cell to produce the hydrocarbon product and the hydrogen gas. A CH₄ activation system and an electrochemical cell are also described.

Inventors:: Ding, Dong; He, Ting; Wu, Wei; Zhang, Yunya

Issue Date:: 2023-06-06

Research Org.:: Idaho National Laboratory (INL), Idaho Falls, ID (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1998450

Patent Number(s):: 11668012

Application Number:: 16/196,283

Assignee:: Battelle Energy Alliance, LLC (Idaho Falls, ID)

DOE Contract Number:: AC07-05ID14517

Resource Type:: Patent

Resource Relation:: Patent File Date: 11/20/2018

Country of Publication:: United States

Language:: English

Citation Formats


                    Ding, Dong, He, Ting, Wu, Wei, and Zhang, Yunya. Methods for producing hydrocarbon products and hydrogen gas through electrochemical activation of methane.  United States: N. p., 2023. 
        Web.

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                    Ding, Dong, He, Ting, Wu, Wei, & Zhang, Yunya. Methods for producing hydrocarbon products and hydrogen gas through electrochemical activation of methane.  United States.

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                    Ding, Dong, He, Ting, Wu, Wei, and Zhang, Yunya. Tue .  
        "Methods for producing hydrocarbon products and hydrogen gas through electrochemical activation of methane".  United States.  https://www.osti.gov/servlets/purl/1998450.

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@article{osti_1998450,

  title        = {Methods for producing hydrocarbon products and hydrogen gas through electrochemical activation of methane},

  author       = {Ding, Dong and He, Ting and Wu, Wei and Zhang, Yunya},

  abstractNote = {A method of forming a hydrocarbon product and hydrogen gas comprises introducing CH4 to a positive electrode of an electrochemical cell comprising the positive electrode, a negative electrode, and a proton-conducting membrane between the positive electrode and the negative electrode. The proton-conducting membrane comprises an electrolyte material having an ionic conductivity greater than or equal to about 10−2 S/cm at one or more temperatures within a range of from about 150° C. to about 600° C. A potential difference is applied between the positive electrode and the negative electrode of the electrochemical cell to produce the hydrocarbon product and the hydrogen gas. A CH4 activation system and an electrochemical cell are also described.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2023},

  month        = {6}

}

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Title: Methods for producing hydrocarbon products and hydrogen gas through electrochemical activation of methane

Abstract

Citation Formats

Evaluation of molybdenum carbide as anode catalyst for proton-conducting hydrogen and ethane solid oxide fuel cells journal, February 2012

Electrode-support type of gas-separation membrane module, tubular structure of same, production method for tubular structure, and hydrocarbon reforming method using same patent, August 2017

High Total Proton Conductivity in Large-Grained Yttrium-Doped Barium Zirconate journal, July 2009

Solid multi-component membranes, electrochemical reactor components, electrochemical reactors and use of membranes, reactor components, and reactor for oxidation reactions patent, December 2001

Protonic membrane for fuel cell for co-generation of power and ethylene journal, January 2008

BaCe0.5Zr0.3Y0.2–xYbxO3–δ proton-conducting electrolytes for intermediate-temperature solid oxide fuel cells journal, October 2017

Triple Conducting Cathode Material for Intermediate Temperature Protonic Ceramic Electrochemical Devices patent-application, July 2016

Properties and applications of perovskite proton conductors journal, September 2010

BaZr 0.1 Ce 0.7 Y 0.1 Yb 0.1 O 3−δ as highly active and carbon tolerant anode for direct hydrocarbon solid oxide fuel cells journal, September 2014

Solid-state electrochemical synthesis of ammonia: a review journal, April 2011

A methane-fueled SOFC based on a thin BaZr 0.1 Ce 0.7 Y 0.1 Yb 0.1 O 3−δ electrolyte film and a LaNi 0.6 Co 0.4 O 3 anode functional layer journal, January 2016

System and Method for Oxidizing Organic Compounds While Reducing Carbon Dioxide patent-application, May 2013

Proton Conducting Electrolyte Membranes Having Nano-Grain YSZ as Protective Layers, and Membrane Electrode Assemblies and Ceramic Fuel Cells Comprising Same patent-application, October 2011

Design and fabrication of a chemically-stable proton conductor bilayer electrolyte for intermediate temperature solid oxide fuel cells (IT-SOFCs) journal, January 2008

Electrochemical Conversion of Hydrocarbons patent-application, April 2015

Solid electrolyte fuel cell and method for manufacture of same patent, September 1993

Ethane dehydrogenation over nano-Cr2O3 anode catalyst in proton ceramic fuel cell reactors to co-produce ethylene and electricity journal, February 2011

Proton-conducting oxide and applications to hydrogen energy devices journal, November 2012

Electrochemical conversion of CO.sub.2 and CH.sub.4 to C.sub.2 hydrocarbons in a single cell patent, November 1991

CO2 emission free co-generation of energy and ethylene in hydrocarbon SOFC reactors with a dehydrogenation anode journal, January 2011

Catalytic Layer for Oxygen Activation on Ionic Solid Electrolytes at High Temperature patent-application, July 2011

Triple-Conducting Layered Perovskites as Cathode Materials for Proton-Conducting Solid Oxide Fuel Cells journal, August 2014

Methods for Conversion of a Light Alkane to a Higher Hydrocarbon, Method of Dehydrogenating an Alkane, and Method of Reactivating a Catalyst Layer patent-application, December 2008

Ba-Sr-Co-Fe-O Based Perovskite Mixed Conducting Materials as Cathode Materials for Intermediate Temperature Solid Oxide Fuel Cells Both in Dual Chamber and Single Chamber Configuration patent-application, September 2014

Propane Dehydrogenation in a Proton-conducting Fuel Cell journal, June 2008

Electrochemical Production of Water Using Mixed Ionically and Electronically Conductive Membranes patent-application, December 2018

Catalytic Upgrading of Methane to Higher Hydrocarbon in a Nonoxidative Chemical Conversion journal, March 2016

Membrane Electrode Assembly and Solid Oxide Fuel Cell patent-application, October 2017

Process for producing compressed hydrogen in a membrane reactor and reactor therefor patent-application, September 2019

Method for the production of light hydrocarbons from gas with high methane content, a solid oxide fuel cell used for the production of light hydrocarbons from gas with high methane content, and a catalyst for the production of light hydrocarbons from gas with high methane content patent, March 2016

Paraffin Fuel Cell patent-application, September 2010

Perovskite-based mixed protonic–electronic conducting membranes for hydrogen separation: Recent status and advances journal, April 2018

Methods and devices for the production of Hydrocarbons from Carbon and Hydrogen sources patent-application, November 2008

Ba-Sr-Co-Fe-O Based Perovskite Mixed Conducting Materials as Cathode Materials for Intermediate Temperature Solid Oxide Fuel Cells Both in Dual Chamber and Single Chamber Configuration patent-application, February 2005

Evaluation of molybdenum carbide as anode catalyst for proton-conducting hydrogen and ethane solid oxide fuel cells
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Electrode-support type of gas-separation membrane module, tubular structure of same, production method for tubular structure, and hydrocarbon reforming method using same
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High Total Proton Conductivity in Large-Grained Yttrium-Doped Barium Zirconate
journal, July 2009

Solid multi-component membranes, electrochemical reactor components, electrochemical reactors and use of membranes, reactor components, and reactor for oxidation reactions
patent, December 2001

Protonic membrane for fuel cell for co-generation of power and ethylene
journal, January 2008

BaCe0.5Zr0.3Y0.2–xYbxO3–δ proton-conducting electrolytes for intermediate-temperature solid oxide fuel cells
journal, October 2017

Triple Conducting Cathode Material for Intermediate Temperature Protonic Ceramic Electrochemical Devices
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Properties and applications of perovskite proton conductors
journal, September 2010

BaZr 0.1 Ce 0.7 Y 0.1 Yb 0.1 O 3−δ as highly active and carbon tolerant anode for direct hydrocarbon solid oxide fuel cells
journal, September 2014

Solid-state electrochemical synthesis of ammonia: a review
journal, April 2011

A methane-fueled SOFC based on a thin BaZr _0.1 Ce _0.7 Y _0.1 Yb _0.1 O _3−δ electrolyte film and a LaNi _0.6 Co _0.4 O ₃ anode functional layer
journal, January 2016

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Electrochemical conversion of CO.sub.2 and CH.sub.4 to C.sub.2 hydrocarbons in a single cell
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Methods for Conversion of a Light Alkane to a Higher Hydrocarbon, Method of Dehydrogenating an Alkane, and Method of Reactivating a Catalyst Layer
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journal, June 2008

Electrochemical Production of Water Using Mixed Ionically and Electronically Conductive Membranes
patent-application, December 2018

Catalytic Upgrading of Methane to Higher Hydrocarbon in a Nonoxidative Chemical Conversion
journal, March 2016

Membrane Electrode Assembly and Solid Oxide Fuel Cell
patent-application, October 2017

Process for producing compressed hydrogen in a membrane reactor and reactor therefor
patent-application, September 2019

Method for the production of light hydrocarbons from gas with high methane content, a solid oxide fuel cell used for the production of light hydrocarbons from gas with high methane content, and a catalyst for the production of light hydrocarbons from gas with high methane content
patent, March 2016

Paraffin Fuel Cell
patent-application, September 2010

Perovskite-based mixed protonic–electronic conducting membranes for hydrogen separation: Recent status and advances
journal, April 2018

Methods and devices for the production of Hydrocarbons from Carbon and Hydrogen sources
patent-application, November 2008

Ba-Sr-Co-Fe-O Based Perovskite Mixed Conducting Materials as Cathode Materials for Intermediate Temperature Solid Oxide Fuel Cells Both in Dual Chamber and Single Chamber Configuration
patent-application, February 2005