Anionic redox active lithium iron oxide based cathode materials for rechargeable lithium ion batteries

Wolverton, Christopher M.; Yao, Zhenpeng; Zhan, Chun; Lu, Jun; Amine, Khalil

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Title: Anionic redox active lithium iron oxide based cathode materials for rechargeable lithium ion batteries

Abstract

Cathode materials for lithium ion batteries, lithium ion batteries incorporating the cathode materials, and methods of operating the lithium ion batteries are provided. The materials, which are composed of lithium iron oxides, are able to undergo reversible anionic and cationic redox reactions with no O2(g) generation.

Inventors:: Wolverton, Christopher M.; Yao, Zhenpeng; Zhan, Chun; Lu, Jun; Amine, Khalil

Issue Date:: Tue May 30 00:00:00 EDT 2023

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States); Northwestern Univ., Evanston, IL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1998428

Patent Number(s):: 11664526

Application Number:: 16/769,340

Assignee:: Northwestern University (Evanston, IL); UChicago Argonne, LLC (Chicago, IL)

DOE Contract Number:: AC02-06CH11357

Resource Type:: Patent

Resource Relation:: Patent File Date: 12/06/2018

Country of Publication:: United States

Language:: English

Citation Formats


                    Wolverton, Christopher M., Yao, Zhenpeng, Zhan, Chun, Lu, Jun, and Amine, Khalil. Anionic redox active lithium iron oxide based cathode materials for rechargeable lithium ion batteries.  United States: N. p., 2023. 
        Web.

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                    Wolverton, Christopher M., Yao, Zhenpeng, Zhan, Chun, Lu, Jun, & Amine, Khalil. Anionic redox active lithium iron oxide based cathode materials for rechargeable lithium ion batteries.  United States.

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                    Wolverton, Christopher M., Yao, Zhenpeng, Zhan, Chun, Lu, Jun, and Amine, Khalil. Tue .  
        "Anionic redox active lithium iron oxide based cathode materials for rechargeable lithium ion batteries".  United States.  https://www.osti.gov/servlets/purl/1998428.

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@article{osti_1998428,

  title        = {Anionic redox active lithium iron oxide based cathode materials for rechargeable lithium ion batteries},

  author       = {Wolverton, Christopher M. and Yao, Zhenpeng and Zhan, Chun and Lu, Jun and Amine, Khalil},

  abstractNote = {Cathode materials for lithium ion batteries, lithium ion batteries incorporating the cathode materials, and methods of operating the lithium ion batteries are provided. The materials, which are composed of lithium iron oxides, are able to undergo reversible anionic and cationic redox reactions with no O2(g) generation.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Tue May 30 00:00:00 EDT 2023},

  month        = {Tue May 30 00:00:00 EDT 2023}

}

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Similar Records

Title: Anionic redox active lithium iron oxide based cathode materials for rechargeable lithium ion batteries

Abstract

Citation Formats

Reversible anionic redox chemistry in high-capacity layered-oxide electrodes journal, July 2013

Electron paramagnetic resonance imaging for real-time monitoring of Li-ion batteries journal, February 2015

Electrochemical properties and Mössbauer effect of anti-fluorite type compound, LiFeO journal, November 2005

Activated Lithium-Metal-Oxides as Catalytic Electrodes for Li–O2 Cells journal, January 2011

Electrochemical reactions and cathode properties of Fe-doped Li2O for the hermetically sealed lithium peroxide battery journal, August 2016

Understanding the Roles of Anionic Redox and Oxygen Release during Electrochemical Cycling of Lithium-Rich Layered Li 4 FeSbO 6 journal, April 2015

Anionic redox processes for electrochemical devices journal, January 2016

Enabling the high capacity of lithium-rich anti-fluorite lithium iron oxide by simultaneous anionic and cationic redox journal, December 2017

A new active Li–Mn–O compound for high energy density Li-ion batteries journal, November 2015

Evidence for anionic redox activity in a tridimensional-ordered Li-rich positive electrode β-Li2IrO3 journal, February 2017

The structural and chemical origin of the oxygen redox activity in layered and cation-disordered Li-excess cathode materials journal, May 2016

Vision for Designing High-Energy, Hybrid Li Ion/Li–O 2 Cells journal, October 2013

Alkali metal ion battery electrode material patent, February 1998

Lithium-Oxygen (Air) Electrochemical Cells and Batteries patent-application, September 2010

Visualization of O-O peroxo-like dimers in high-capacity layered oxides for Li-ion batteries journal, December 2015

Anti-fluorite type Li6CoO4, Li5FeO4, and Li6MnO4 as the cathode for lithium secondary batteries journal, July 1999

Synthesis and Characterization of Novel Cathode Material Li5FeO4 for Li-ion Batteries journal, May 2013

Li 2 O Removal from Li 5 FeO 4 : A Cathode Precursor for Lithium-Ion Batteries † journal, February 2010

Charge-compensation in 3d-transition-metal-oxide intercalation cathodes through the generation of localized electron holes on oxygen journal, March 2016

Antifluorite compounds, Li5+xFe1−xCoxO4, as a lithium intercalation host journal, August 2005

Electrolyte or Electrode Additives for Increasing Metal Contents in Metal-Ion Batteries patent-application, March 2015

Role of Li 6 CoO 4 Cathode Additive in Li-Ion Cells Containing Low Coulombic Efficiency Anode Material journal, January 2012

Positive Electrodes for Lithium Batteries patent-application, January 2015

Lithium-oxygen (AIR) electrochemical cells and batteries patent, November 2012

Reversible anionic redox chemistry in high-capacity layered-oxide electrodes
journal, July 2013

Electron paramagnetic resonance imaging for real-time monitoring of Li-ion batteries
journal, February 2015

Electrochemical properties and Mössbauer effect of anti-fluorite type compound, LiFeO
journal, November 2005

Activated Lithium-Metal-Oxides as Catalytic Electrodes for Li–O2 Cells
journal, January 2011

Electrochemical reactions and cathode properties of Fe-doped Li2O for the hermetically sealed lithium peroxide battery
journal, August 2016

Understanding the Roles of Anionic Redox and Oxygen Release during Electrochemical Cycling of Lithium-Rich Layered Li ₄ FeSbO ₆
journal, April 2015

Anionic redox processes for electrochemical devices
journal, January 2016

Enabling the high capacity of lithium-rich anti-fluorite lithium iron oxide by simultaneous anionic and cationic redox
journal, December 2017

A new active Li–Mn–O compound for high energy density Li-ion batteries
journal, November 2015

Evidence for anionic redox activity in a tridimensional-ordered Li-rich positive electrode β-Li2IrO3
journal, February 2017

The structural and chemical origin of the oxygen redox activity in layered and cation-disordered Li-excess cathode materials
journal, May 2016

Vision for Designing High-Energy, Hybrid Li Ion/Li–O ₂ Cells
journal, October 2013

Alkali metal ion battery electrode material
patent, February 1998

Lithium-Oxygen (Air) Electrochemical Cells and Batteries
patent-application, September 2010

Visualization of O-O peroxo-like dimers in high-capacity layered oxides for Li-ion batteries
journal, December 2015

Anti-fluorite type Li6CoO4, Li5FeO4, and Li6MnO4 as the cathode for lithium secondary batteries
journal, July 1999

Synthesis and Characterization of Novel Cathode Material Li5FeO4 for Li-ion Batteries
journal, May 2013

Li ₂ O Removal from Li ₅ FeO ₄ : A Cathode Precursor for Lithium-Ion Batteries ^†
journal, February 2010

Charge-compensation in 3d-transition-metal-oxide intercalation cathodes through the generation of localized electron holes on oxygen
journal, March 2016

Antifluorite compounds, Li5+xFe1−xCoxO4, as a lithium intercalation host
journal, August 2005

Electrolyte or Electrode Additives for Increasing Metal Contents in Metal-Ion Batteries
patent-application, March 2015

Role of Li ₆ CoO ₄ Cathode Additive in Li-Ion Cells Containing Low Coulombic Efficiency Anode Material
journal, January 2012

Positive Electrodes for Lithium Batteries
patent-application, January 2015

Lithium-oxygen (AIR) electrochemical cells and batteries
patent, November 2012