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Title: Bioderived fuels and methods of making the same

Abstract

The present disclosure relates to a composition that includes a first oxide having a phosphate, a ratio of Brønsted acid sites to Lewis acid sites between 0.05 and 1.00, and a total acidity between 50 μmol/g and 300 μmol/g, where the phosphate is at least one of a functional group covalently bonded to the first oxide and/or an anion ionically bonded to the first oxide.

Inventors:
; ; ;
Issue Date:
Research Org.:
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1998385
Patent Number(s):
11649410
Application Number:
17/379,477
Assignee:
Alliance for Sustainable Energy, LLC (Golden, CO)
DOE Contract Number:  
AC36-08GO28308
Resource Type:
Patent
Resource Relation:
Patent File Date: 07/19/2021
Country of Publication:
United States
Language:
English

Citation Formats

Hafenstine, Glenn Richard, Vardon, Derek Richard, Huo, Xiangchen, and Huq, Nabila Asem. Bioderived fuels and methods of making the same. United States: N. p., 2023. Web.
Hafenstine, Glenn Richard, Vardon, Derek Richard, Huo, Xiangchen, & Huq, Nabila Asem. Bioderived fuels and methods of making the same. United States.
Hafenstine, Glenn Richard, Vardon, Derek Richard, Huo, Xiangchen, and Huq, Nabila Asem. Tue . "Bioderived fuels and methods of making the same". United States. https://www.osti.gov/servlets/purl/1998385.
@article{osti_1998385,
title = {Bioderived fuels and methods of making the same},
author = {Hafenstine, Glenn Richard and Vardon, Derek Richard and Huo, Xiangchen and Huq, Nabila Asem},
abstractNote = {The present disclosure relates to a composition that includes a first oxide having a phosphate, a ratio of Brønsted acid sites to Lewis acid sites between 0.05 and 1.00, and a total acidity between 50 μmol/g and 300 μmol/g, where the phosphate is at least one of a functional group covalently bonded to the first oxide and/or an anion ionically bonded to the first oxide.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2023},
month = {5}
}

Works referenced in this record:

Solid-Acid-Catalyzed Etherification of Glycerol to Potential Fuel Additives
journal, October 2017


Effect of Alcohol Structure on the Kinetics of Etherification and Dehydration over Tungstated Zirconia
journal, August 2018


Kinetics of 1-hexanol etherification on Amberlyst 70
journal, June 2014


Cooperative action of Brønsted and Lewis acid sites of niobium phosphate catalysts for cellobiose conversion in water
journal, September 2016


Catalyst for Hydrodeoxygenation of Oxygenated Hydrocarbons
patent-application, February 2014


Copper- and Borinic Acid-catalyzed Propargylic Etherification of Propargylic Carbonates with Benzyl Alcohols
journal, May 2018


Introduction: Next generation biofuels
journal, June 2011


Correction: Catalytic synthesis of distillate-range ethers and olefins from ethanol through Guerbet coupling and etherification
journal, January 2019


Ketonization of carboxylic acids over CeO2-based composite oxides
journal, March 2005


Solid Acid Catalysts for Biodiesel Production –-Towards Sustainable Energy
journal, January 2006


High-Throughput Screening of Heterogeneous Catalysts for the Conversion of Furfural to Bio-Based Fuel Components
journal, December 2015


Dehydrative Etherification Reactions of Glycerol with Alcohols Catalyzed by Recyclable Nanoporous Aluminosilicates: Telescoped Routes to Glyceryl Ethers
journal, December 2015


A Convenient Catalytic Method for the Synthesis of Ethers from Alcohols and Carbonyl Compounds
journal, March 2005


Ether Formation in the Hydrogenolysis of Hydroxymethylfurfural over Palladium Catalysts in Alcoholic Solution
journal, January 2009


Production of Biomass-Based Automotive Lubricants by Reductive Etherification
journal, May 2017


Production of alkanes from biomass derived carbohydrates on bi-functional catalysts employing niobium-based supports
journal, July 2009


Role of Lewis and Brønsted Acid Sites in the Dehydration of Glycerol over Niobia
journal, August 2014


Catalytic coupling of carboxylic acids by ketonization as a processing step in biomass conversion
journal, August 2009


Hydrothermally stable heterogeneous catalysts for conversion of biorenewables
journal, January 2014


Etherification of aldehydes, alcohols and their mixtures on Pd/SiO2 catalysts
journal, May 2010


Ether synthesis from alcohol and aldehyde in the presence of hydrogen and palladium deposited on charcoal
journal, March 2000


An alternative catalytic method to the Williamson's synthesis of ethers
journal, June 1995


Comparative performance of niobium phosphates in liquid phase anisole benzylation with benzyl alcohol
journal, June 2008


Nb2O5·nH2O as a Heterogeneous Catalyst with Water-Tolerant Lewis Acid Sites
journal, March 2011


Intrinsic and Effective Acidity Study of Niobic Acid and Niobium Phosphate by a Multitechnique Approach
journal, October 2005


Bioderived fuels and methods of making the same
patent, August 2021


Screening of Potential Biomass-Derived Streams as Fuel Blendstocks for Mixing Controlled Compression Ignition Combustion
conference, April 2019


One-Pot Synthesis of Alkyl 4-Alkoxypentanoates by Esterification and Reductive Etherification of Levulinic Acid in Alcoholic Solutions
journal, July 2016


Catalytic synthesis of distillate-range ethers and olefins from ethanol through Guerbet coupling and etherification
journal, January 2019


Silica–niobia oxides as viable acid catalysts in water: Effective vs. intrinsic acidity
journal, July 2010


Direct Hydrogenation of Biomass-Derived Butyric Acid to n -Butanol over a Ruthenium-Tin Bimetallic Catalyst
journal, August 2014


Transforming Methyl Levulinate into Biosurfactants and Biolubricants by Chemoselective Reductive Etherification with Fatty Alcohols
journal, January 2020


Water-Tolerant Solid Acid Catalysts
journal, October 2002


High Lubricity Fuel Reformulation to Increase Mileage and Reduce Emissions
patent-application, June 2015