Bioderived fuels and methods of making the same
Abstract
The present disclosure relates to a composition that includes a first oxide having a phosphate, a ratio of Brønsted acid sites to Lewis acid sites between 0.05 and 1.00, and a total acidity between 50 μmol/g and 300 μmol/g, where the phosphate is at least one of a functional group covalently bonded to the first oxide and/or an anion ionically bonded to the first oxide.
- Inventors:
- Issue Date:
- Research Org.:
- National Renewable Energy Laboratory (NREL), Golden, CO (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1998385
- Patent Number(s):
- 11649410
- Application Number:
- 17/379,477
- Assignee:
- Alliance for Sustainable Energy, LLC (Golden, CO)
- DOE Contract Number:
- AC36-08GO28308
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 07/19/2021
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Hafenstine, Glenn Richard, Vardon, Derek Richard, Huo, Xiangchen, and Huq, Nabila Asem. Bioderived fuels and methods of making the same. United States: N. p., 2023.
Web.
Hafenstine, Glenn Richard, Vardon, Derek Richard, Huo, Xiangchen, & Huq, Nabila Asem. Bioderived fuels and methods of making the same. United States.
Hafenstine, Glenn Richard, Vardon, Derek Richard, Huo, Xiangchen, and Huq, Nabila Asem. Tue .
"Bioderived fuels and methods of making the same". United States. https://www.osti.gov/servlets/purl/1998385.
@article{osti_1998385,
title = {Bioderived fuels and methods of making the same},
author = {Hafenstine, Glenn Richard and Vardon, Derek Richard and Huo, Xiangchen and Huq, Nabila Asem},
abstractNote = {The present disclosure relates to a composition that includes a first oxide having a phosphate, a ratio of Brønsted acid sites to Lewis acid sites between 0.05 and 1.00, and a total acidity between 50 μmol/g and 300 μmol/g, where the phosphate is at least one of a functional group covalently bonded to the first oxide and/or an anion ionically bonded to the first oxide.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2023},
month = {5}
}
Works referenced in this record:
Catalytic Reductive Etherification of Ketones with Alcohols at Ambient Hydrogen Pressure: A Practical, Waste-Minimized Synthesis of Dialkyl Ethers
journal, December 2006
- Gooßen, Lukas; Linder, Christophe
- Synlett, Vol. 2006, Issue 20
Solid-Acid-Catalyzed Etherification of Glycerol to Potential Fuel Additives
journal, October 2017
- Magar, Subhash; Kamble, Sumit; Mohanraj, Govindraj Thangaraj
- Energy & Fuels, Vol. 31, Issue 11
Effect of Alcohol Structure on the Kinetics of Etherification and Dehydration over Tungstated Zirconia
journal, August 2018
- Rorrer, Julie; Pindi, Suresh; Toste, F. Dean
- ChemSusChem, Vol. 11, Issue 18
Kinetics of 1-hexanol etherification on Amberlyst 70
journal, June 2014
- Bringué, R.; Ramírez, E.; Iborra, M.
- Chemical Engineering Journal, Vol. 246
Cooperative action of Brønsted and Lewis acid sites of niobium phosphate catalysts for cellobiose conversion in water
journal, September 2016
- Carniti, Paolo; Gervasini, Antonella; Bossola, Filippo
- Applied Catalysis B: Environmental, Vol. 193
Etherification and reductive etherification of 5-(hydroxymethyl)furfural: 5-(alkoxymethyl)furfurals and 2,5-bis(alkoxymethyl)furans as potential bio-diesel candidates
journal, January 2012
- Balakrishnan, Madhesan; Sacia, Eric R.; Bell, Alexis T.
- Green Chemistry, Vol. 14, Issue 6
Catalyst for Hydrodeoxygenation of Oxygenated Hydrocarbons
patent-application, February 2014
- Blank, Brian; Cortright, Randy; Beck, Taylor
- US Patent Application 13/586499; 20140051872
Copper- and Borinic Acid-catalyzed Propargylic Etherification of Propargylic Carbonates with Benzyl Alcohols
journal, May 2018
- Tsuchida, Kohei; Yuki, Masahiro; Nakajima, Kazunari
- Chemistry Letters, Vol. 47, Issue 5
Introduction: Next generation biofuels
journal, June 2011
- Fairley, Peter
- Nature, Vol. 474, Issue 7352
Correction: Catalytic synthesis of distillate-range ethers and olefins from ethanol through Guerbet coupling and etherification
journal, January 2019
- Eagan, Nathaniel M.; Moore, Benjamin M.; McClelland, Daniel J.
- Green Chemistry, Vol. 21, Issue 18
Investigation on performance of a spark-ignition engine fueled with dimethyl ether and gasoline mixtures under idle and stoichiometric conditions
journal, May 2017
- Ji, Changwei; Shi, Lei; Wang, Shuofeng
- Energy, Vol. 126
Ketonization of carboxylic acids over CeO2-based composite oxides
journal, March 2005
- Nagashima, Osamu; Sato, Satoshi; Takahashi, Ryoji
- Journal of Molecular Catalysis A: Chemical, Vol. 227, Issue 1-2
Solid Acid Catalysts for Biodiesel Production –-Towards Sustainable Energy
journal, January 2006
- Kiss, Anton A.; Dimian, Alexandre C.; Rothenberg, Gadi
- Advanced Synthesis & Catalysis, Vol. 348, Issue 1-2
High-Throughput Screening of Heterogeneous Catalysts for the Conversion of Furfural to Bio-Based Fuel Components
journal, December 2015
- Pizzi, Roberto; van Putten, Robert-Jan; Brust, Hanneke
- Catalysts, Vol. 5, Issue 4
Dehydrative Etherification Reactions of Glycerol with Alcohols Catalyzed by Recyclable Nanoporous Aluminosilicates: Telescoped Routes to Glyceryl Ethers
journal, December 2015
- Davies, Thomas E.; Kondrat, Simon A.; Nowicka, Ewa
- ACS Sustainable Chemistry & Engineering, Vol. 4, Issue 3
Production of jet fuel and green diesel range biohydrocarbons by hydroprocessing of soybean oil over niobium phosphate catalyst
journal, June 2019
- Scaldaferri, Cristiane Almeida; Pasa, Vânya Márcia Duarte
- Fuel, Vol. 245
A Convenient Catalytic Method for the Synthesis of Ethers from Alcohols and Carbonyl Compounds
journal, March 2005
- Fujii, Yasuyuki; Furugaki, Hisakazu; Tamura, Eiko
- Bulletin of the Chemical Society of Japan, Vol. 78, Issue 3
Ether Formation in the Hydrogenolysis of Hydroxymethylfurfural over Palladium Catalysts in Alcoholic Solution
journal, January 2009
- Maat, Leendert; van Bekkum, Herman; C. A. Luijkx, Gerard
- HETEROCYCLES, Vol. 77, Issue 2
Production of Biomass-Based Automotive Lubricants by Reductive Etherification
journal, May 2017
- Jadhav, Deepak; Grippo, Adam M.; Shylesh, Sankaranarayanapillai
- ChemSusChem, Vol. 10, Issue 11
Production of alkanes from biomass derived carbohydrates on bi-functional catalysts employing niobium-based supports
journal, July 2009
- West, Ryan M.; Tucker, Mark H.; Braden, Drew J.
- Catalysis Communications, Vol. 10, Issue 13
Niobic acid and niobium phosphate as highly acidic viable catalysts in aqueous medium: Fructose dehydration reaction
journal, December 2006
- Carniti, P.; Gervasini, A.; Biella, S.
- Catalysis Today, Vol. 118, Issue 3-4
Role of Lewis and Brønsted Acid Sites in the Dehydration of Glycerol over Niobia
journal, August 2014
- Foo, Guo Shiou; Wei, Daniel; Sholl, David S.
- ACS Catalysis, Vol. 4, Issue 9
Catalytic coupling of carboxylic acids by ketonization as a processing step in biomass conversion
journal, August 2009
- Gaertner, Christian A.; Serrano-Ruiz, Juan Carlos; Braden, Drew J.
- Journal of Catalysis, Vol. 266, Issue 1, p. 71-78
Hydrothermally stable heterogeneous catalysts for conversion of biorenewables
journal, January 2014
- Xiong, Haifeng; Pham, Hien N.; Datye, Abhaya K.
- Green Chem., Vol. 16, Issue 11
A cobalt catalyst for reductive etherification of 5-hydroxymethyl-furfural to 2,5-bis(methoxymethyl)furan under mild conditions
journal, January 2018
- Li, Xing-Long; Zhang, Kun; Chen, Shi-Yan
- Green Chemistry, Vol. 20, Issue 5
Facile synthesis of furfuryl ethyl ether in high yield via the reductive etherification of furfural in ethanol over Pd/C under mild conditions
journal, January 2018
- Wang, Yun; Cui, Qianqian; Guan, Yejun
- Green Chemistry, Vol. 20, Issue 9
Etherification of aldehydes, alcohols and their mixtures on Pd/SiO2 catalysts
journal, May 2010
- Pham, Trung T.; Crossley, Steven. P.; Sooknoi, Tawan
- Applied Catalysis A: General, Vol. 379, Issue 1-2
Ether synthesis from alcohol and aldehyde in the presence of hydrogen and palladium deposited on charcoal
journal, March 2000
- Bethmont, V.; Montassier, C.; Marecot, P.
- Journal of Molecular Catalysis A: Chemical, Vol. 152, Issue 1-2
An alternative catalytic method to the Williamson's synthesis of ethers
journal, June 1995
- Bethmont, Valérie; Fache, Fabienne; Lemaire, Marc
- Tetrahedron Letters, Vol. 36, Issue 24
Comparative performance of niobium phosphates in liquid phase anisole benzylation with benzyl alcohol
journal, June 2008
- Rocha, Angela S.; Forrester, Aline M. S.; de la Cruz, Marcus H. C.
- Catalysis Communications, Vol. 9, Issue 10
Nb2O5·nH2O as a Heterogeneous Catalyst with Water-Tolerant Lewis Acid Sites
journal, March 2011
- Nakajima, Kiyotaka; Baba, Yusuke; Noma, Ryouhei
- Journal of the American Chemical Society, Vol. 133, Issue 12, p. 4224-4227
Intrinsic and Effective Acidity Study of Niobic Acid and Niobium Phosphate by a Multitechnique Approach
journal, October 2005
- Carniti, Paolo; Gervasini, Antonella; Biella, Serena
- Chemistry of Materials, Vol. 17, Issue 24
Bioderived fuels and methods of making the same
patent, August 2021
- Hafenstine, Glenn Richard; Vardon, Derek Richard; Huo, Xiangchen
- US Patent Document 11,098,257
Screening of Potential Biomass-Derived Streams as Fuel Blendstocks for Mixing Controlled Compression Ignition Combustion
conference, April 2019
- Fioroni, Gina; Fouts, Lisa; Luecke, Jon
- WCX SAE World Congress Experience, SAE Technical Paper Series
One-Pot Synthesis of Alkyl 4-Alkoxypentanoates by Esterification and Reductive Etherification of Levulinic Acid in Alcoholic Solutions
journal, July 2016
- Tulchinsky, Michael L.; Briggs, John R.
- ACS Sustainable Chemistry & Engineering, Vol. 4, Issue 8
Doping Pd/SiO 2 with Na + : changing the reductive etherification of CO to furan ring hydrogenation of furfural in ethanol
journal, January 2019
- Long, Yinshuang; Wang, Yun; Wu, Haihong
- RSC Advances, Vol. 9, Issue 44
Catalytic synthesis of distillate-range ethers and olefins from ethanol through Guerbet coupling and etherification
journal, January 2019
- Eagan, Nathaniel M.; Moore, Benjamin M.; McClelland, Daniel J.
- Green Chemistry, Vol. 21, Issue 12
Silica–niobia oxides as viable acid catalysts in water: Effective vs. intrinsic acidity
journal, July 2010
- Carniti, Paolo; Gervasini, Antonella; Marzo, Matteo
- Catalysis Today, Vol. 152, Issue 1-4
The effects of MTBE blends on engine performance and exhaust emissions in a spark ignition engine
journal, October 2015
- Topgül, Tolga
- Fuel Processing Technology, Vol. 138
Direct Hydrogenation of Biomass-Derived Butyric Acid to n -Butanol over a Ruthenium-Tin Bimetallic Catalyst
journal, August 2014
- Lee, Jong-Min; Upare, Pravin P.; Chang, Jong-San
- ChemSusChem, Vol. 7, Issue 11
Transforming Methyl Levulinate into Biosurfactants and Biolubricants by Chemoselective Reductive Etherification with Fatty Alcohols
journal, January 2020
- Garcia‐Ortiz, Andrea; Arias, Karen S.; Climent, Maria J.
- ChemSusChem, Vol. 13, Issue 4
Water-Tolerant Solid Acid Catalysts
journal, October 2002
- Okuhara, Toshio
- Chemical Reviews, Vol. 102, Issue 10
High Lubricity Fuel Reformulation to Increase Mileage and Reduce Emissions
patent-application, June 2015
- Ford, Don Ricardo Oniel
- US Patent Application 14/632576; 20150166918