Nonprecious metal catalyst for hydrogen production from neutral solutions
Abstract
Catalysts comprising MoP and MoP2 are disclosed, wherein the catalyst is a composite. The catalyst may have a molar ratio of MoP:MoP2 within a range of 5:95 to 95:5. The catalyst may be used as a cathode active material for hydrogen generation from neutral pH solutions, such as wastewater or seawater. Methods of making the catalyst also are disclosed.
- Inventors:
- Issue Date:
- Research Org.:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1998299
- Patent Number(s):
- 11628421
- Application Number:
- 16/653,487
- Assignee:
- Battelle Memorial Institute (Richland, WA)
- DOE Contract Number:
- AC05-76RL01830
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 10/15/2019
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Shao, Yuyan, and Xie, Xiaohong. Nonprecious metal catalyst for hydrogen production from neutral solutions. United States: N. p., 2023.
Web.
Shao, Yuyan, & Xie, Xiaohong. Nonprecious metal catalyst for hydrogen production from neutral solutions. United States.
Shao, Yuyan, and Xie, Xiaohong. Tue .
"Nonprecious metal catalyst for hydrogen production from neutral solutions". United States. https://www.osti.gov/servlets/purl/1998299.
@article{osti_1998299,
title = {Nonprecious metal catalyst for hydrogen production from neutral solutions},
author = {Shao, Yuyan and Xie, Xiaohong},
abstractNote = {Catalysts comprising MoP and MoP2 are disclosed, wherein the catalyst is a composite. The catalyst may have a molar ratio of MoP:MoP2 within a range of 5:95 to 95:5. The catalyst may be used as a cathode active material for hydrogen generation from neutral pH solutions, such as wastewater or seawater. Methods of making the catalyst also are disclosed.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2023},
month = {4}
}
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Works referenced in this record:
Synthesis of Molybdenum Catalyst Formulations for Hydrogen Generation
patent-application, June 2015
- Vaden, Timothy D.; Ramanujachary, Kandalam V.; Mugweru, Amos
- US Patent Application 14/108292; 20150167181
Designing an improved transition metal phosphide catalyst for hydrogen evolution using experimental and theoretical trends
journal, January 2015
- Kibsgaard, Jakob; Tsai, Charlie; Chan, Karen
- Energy & Environmental Science, Vol. 8, Issue 10
Flexible molybdenum phosphide nanosheet array electrodes for hydrogen evolution reaction in a wide pH range
journal, November 2016
- Pu, Zonghua; Wei, Shiyong; Chen, Zhibao
- Applied Catalysis B: Environmental, Vol. 196
Closely Interconnected Network of Molybdenum Phosphide Nanoparticles: A Highly Efficient Electrocatalyst for Generating Hydrogen from Water
journal, June 2014
- Xing, Zhicai; Liu, Qian; Asiri, Abdullah M.
- Advanced Materials, Vol. 26, Issue 32
Electrocatalytic Hydrogen Evolution in Neutral pH Solutions: Dual-Phase Synergy
journal, August 2019
- Xie, Xiaohong; Song, Miao; Wang, Luguang
- ACS Catalysis, Vol. 9, Issue 9
Electrode Material
patent-application, November 2018
- Wang, Xiaoguang; Liu, Lifeng
- US Patent Application 15/777523; 20180327918
Alternative catalytic materials: carbides, nitrides, phosphides and amorphous boron alloys
journal, January 2010
- Alexander, Anne-Marie; Hargreaves, Justin S. J.
- Chemical Society Reviews, Vol. 39, Issue 11
Molybdenum Phosphosulfide: An Active, Acid-Stable, Earth-Abundant Catalyst for the Hydrogen Evolution Reaction
journal, October 2014
- Kibsgaard, Jakob; Jaramillo, Thomas F.
- Angewandte Chemie International Edition, Vol. 53, Issue 52
Three-dimensional porous structural MoP2 nanoparticles as a novel and superior catalyst for electrochemical hydrogen evolution
journal, October 2016
- Wu, Tianli; Pi, Mingyu; Zhang, Dingke
- Journal of Power Sources, Vol. 328
Molybdenum phosphide as an efficient electrocatalyst for the hydrogen evolution reaction
journal, January 2014
- Xiao, Peng; Sk, Mahasin Alam; Thia, Larissa
- Energy Environ. Sci., Vol. 7, Issue 8
MoP nanosheets supported on biomass-derived carbon flake: One-step facile preparation and application as a novel high-active electrocatalyst toward hydrogen evolution reaction
journal, March 2015
- Cui, Wei; Liu, Qian; Xing, Zhicai
- Applied Catalysis B: Environmental, Vol. 164
Recent advances in transition metal phosphide nanomaterials: synthesis and applications in hydrogen evolution reaction
journal, January 2016
- Shi, Yanmei; Zhang, Bin
- Chemical Society Reviews, Vol. 45, Issue 6, p. 1529-1541
Molybdenum Boride and Carbide Catalyze Hydrogen Evolution in both Acidic and Basic Solutions
journal, November 2012
- Vrubel, Heron; Hu, Xile
- Angewandte Chemie International Edition, Vol. 51, Issue 51
Transition metal phosphide hydroprocessing catalysts: A review
journal, May 2009
- Oyama, S. Ted; Gott, Travis; Zhao, Haiyan
- Catalysis Today, Vol. 143, Issue 1-2, p. 94-107
Templated-preparation of a three-dimensional molybdenum phosphide sponge as a high performance electrode for hydrogen evolution
journal, January 2016
- Deng, Chen; Ding, Fei; Li, Xinyuan
- Journal of Materials Chemistry A, Vol. 4, Issue 1
MoP nanoparticles with a P-rich outermost atomic layer embedded in N-doped porous carbon nanofibers: Self-supported electrodes for efficient hydrogen generation
journal, April 2018
- Wang, Minqiang; Ye, Cui; Xu, Maowen
- Nano Research, Vol. 11, Issue 9
Novel porous molybdenum tungsten phosphide hybrid nanosheets on carbon cloth for efficient hydrogen evolution
journal, January 2016
- Wang, Xu-Dong; Xu, Yang-Fan; Rao, Hua-Shang
- Energy & Environmental Science, Vol. 9, Issue 4
General urea-assisted synthesis of carbon-coated metal phosphide nanoparticles for efficient hydrogen evolution electrocatalysis
journal, May 2016
- Gao, Shuang; Liu, Yipu; Li, Guo-Dong
- Electrochimica Acta, Vol. 199