Graphene nanoribbons grown from aromatic molecular seeds

Arnold, Michael Scott; Way, Austin James; Jacobberger, Robert Michael

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Title: Graphene nanoribbons grown from aromatic molecular seeds

Abstract

Methods for the bottom-up growth of graphene nanoribbons are provided. The methods utilize small aromatic molecular seeds to initiate the anisotropic chemical vapor deposition (CVD) growth of graphene nanoribbons having low size polydispersities on the surface of a growth substrate. The aromatic molecular seeds include polycyclic aromatic hydrocarbons (PAHs), functionalized derivatives of PAHs, heterocyclic aromatic molecules, and metal complexes of heterocyclic aromatic molecules.

Inventors:: Arnold, Michael Scott; Way, Austin James; Jacobberger, Robert Michael

Issue Date:: 2023-04-04

Research Org.:: Univ. of Wisconsin, Madison, WI (United States)

Sponsoring Org.:: USDOE; US Army Research Office (ARO)

OSTI Identifier:: 1998254

Patent Number(s):: 11618681

Application Number:: 17/360,108

Assignee:: Wisconsin Alumni Research Foundation (Madison, WI)

DOE Contract Number:: SC0016007; W911NF-12-1-0025

Resource Type:: Patent

Resource Relation:: Patent File Date: 06/28/2021

Country of Publication:: United States

Language:: English

Citation Formats


                    Arnold, Michael Scott, Way, Austin James, and Jacobberger, Robert Michael. Graphene nanoribbons grown from aromatic molecular seeds.  United States: N. p., 2023. 
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                    Arnold, Michael Scott, Way, Austin James, & Jacobberger, Robert Michael. Graphene nanoribbons grown from aromatic molecular seeds.  United States.

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                    Arnold, Michael Scott, Way, Austin James, and Jacobberger, Robert Michael. Tue .  
        "Graphene nanoribbons grown from aromatic molecular seeds".  United States.  https://www.osti.gov/servlets/purl/1998254.

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@article{osti_1998254,

  title        = {Graphene nanoribbons grown from aromatic molecular seeds},

  author       = {Arnold, Michael Scott and Way, Austin James and Jacobberger, Robert Michael},

  abstractNote = {Methods for the bottom-up growth of graphene nanoribbons are provided. The methods utilize small aromatic molecular seeds to initiate the anisotropic chemical vapor deposition (CVD) growth of graphene nanoribbons having low size polydispersities on the surface of a growth substrate. The aromatic molecular seeds include polycyclic aromatic hydrocarbons (PAHs), functionalized derivatives of PAHs, heterocyclic aromatic molecules, and metal complexes of heterocyclic aromatic molecules.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2023},

  month        = {4}

}

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Title: Graphene nanoribbons grown from aromatic molecular seeds

Abstract

Citation Formats

Material potential and scalability challenges of germanium CMOS conference, December 2011

Strained-Germanium Nanostructures for Infrared Photonics journal, March 2014

Graphene Processing for Device and Sensor Applications patent-application, January 2012

Silicon-based molecular nanotechnology journal, June 2000

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Process for Preparing Graphene Nanoribbons patent-application, August 2015

Electronic states of graphene nanoribbons studied with the Dirac equation journal, June 2006

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Methods of Preparing a Graphene Sheet patent-application, October 2010

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Transistor Having Graphene Base patent-application, March 2012

Channel-Last Methods for Making FETs patent-application, September 2014

Oriented bottom-up growth of armchair graphene nanoribbons on germanium patent, March 2016

Graphene-on-semiconductor substrates for analog electronics patent, April 2016

Graphene nanoribbons with zigzag and armchair edges prepared by scanning tunneling microscope lithography on gold substrates journal, February 2014

Broadband Absorptive Neutral Density Optical Filter patent-application, January 2013

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Experimental Review of Graphene journal, January 2012

Mechanism of photo-stimulated processes in GeOx films journal, January 1995

Recent progress of Germanium MOSFETs conference, May 2012

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Synthesis of Graphene Nanoribbons Encapsulated in Single-Walled Carbon Nanotubes journal, October 2011

Germanium MOSFET Devices: Advances in Materials Understanding, Process Development, and Electrical Performance journal, May 2008

Homogeneous Multiple Band Gap Devices patent-application, April 2013

Graphene-Based Transistor patent-application, August 2010

(Invited) Novel Electronic and Optoelectronic Devices in Germanium Integrated on Silicon conference, January 2010

Anisotropic Synthesis of Armchair Graphene Nanoribbon Arrays from Sub-5 nm Seeds at Variable Pitches on Germanium journal, July 2019

Load Sensing System patent-application, September 2015

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Direct Formation of Graphene on Semiconductor Substrates patent-application, April 2013

High-k/Ge MOSFETs for future nanoelectronics journal, January 2008

Ethene to Graphene: Surface Catalyzed Chemical Pathways, Intermediates, and Assembly journal, March 2017

High-Quality Large-Area Graphene from Dehydrogenated Polycyclic Aromatic Hydrocarbons journal, October 2012

Semiconductor Structure and Circuit Including Ordered Arrangement of Graphene Nanoribbons, and Methods of Forming Same patent-application, July 2012

Graphene Nanoribbons, Method of Fabrication and their Use in Electronic Devices patent-application, April 2012

Nanostructured Graphene with Atomically-Smooth Edges patent-application, May 2013

Growth of Single Crystal Graphene Arrays by Locally Controlling Nucleation on Polycrystalline Cu Using Chemical Vapor Deposition journal, September 2011

Nanopatterning of graphene with crystallographic orientation control journal, August 2010

Germanium nanowire field-effect transistors with SiO2 and high-κ HfO2 gate dielectrics journal, September 2003

Method of Manufacturing Graphene by Using Germanium Layer patent-application, October 2011

Direct Growth of Graphene Film on Germanium Substrate journal, August 2013

Structure and Method of Making Graphene Nanoribbons patent-application, October 2012

Ambient stability of chemically passivated germanium interfaces journal, October 2003

Etching and narrowing of graphene from the edges journal, June 2010

Distinctly different thermal decomposition pathways of ultrathin oxide layer on Ge and Si surfaces journal, April 2000

Extended iron phthalocyanine islands self-assembled on a Ge(001):H surface journal, March 2021

Graphene Transistors and Photodetectors journal, January 2013

Seed-mediated growth of patterned graphene nanoribbon arrays patent, September 2017

Film on graphene on a substrate and method and devices therefor patent-application, June 2012

Synthesis, Characterization, and Properties of Large-Area Graphene Films journal, January 2009

Metal Phthalocyanine Nanoribbons and Nanowires journal, August 2006

Material potential and scalability challenges of germanium CMOS
conference, December 2011

Strained-Germanium Nanostructures for Infrared Photonics
journal, March 2014

Graphene Processing for Device and Sensor Applications
patent-application, January 2012

Silicon-based molecular nanotechnology
journal, June 2000

Control and characterization of individual grains and grain boundaries in graphene grown by chemical vapour deposition
journal, May 2011

Process for Preparing Graphene Nanoribbons
patent-application, August 2015

Electronic states of graphene nanoribbons studied with the Dirac equation
journal, June 2006

Controlling the Orientation, Edge Geometry, and Thickness of Chemical Vapor Deposition Graphene
journal, January 2013

Methods of Preparing a Graphene Sheet
patent-application, October 2010

Seed-Assisted Synthesis of Graphene Films on Insulating Substrate
journal, April 2019

Exploration of edge-dependent optical selection rules for graphene nanoribbons
journal, January 2011

Transistor Having Graphene Base
patent-application, March 2012

Channel-Last Methods for Making FETs
patent-application, September 2014

Oriented bottom-up growth of armchair graphene nanoribbons on germanium
patent, March 2016

Graphene-on-semiconductor substrates for analog electronics
patent, April 2016

Graphene nanoribbons with zigzag and armchair edges prepared by scanning tunneling microscope lithography on gold substrates
journal, February 2014

Broadband Absorptive Neutral Density Optical Filter
patent-application, January 2013

Barrier Guided Growth of Microstructured and Nanostructured Graphene and Graphite
patent-application, June 2013

Experimental Review of Graphene
journal, January 2012

Mechanism of photo-stimulated processes in GeO_x films
journal, January 1995

Recent progress of Germanium MOSFETs
conference, May 2012

Low Voltage Photodetectors
patent-application, February 2015

Synthesis of Graphene Nanoribbons Encapsulated in Single-Walled Carbon Nanotubes
journal, October 2011

Germanium MOSFET Devices: Advances in Materials Understanding, Process Development, and Electrical Performance
journal, May 2008

Homogeneous Multiple Band Gap Devices
patent-application, April 2013

Graphene-Based Transistor
patent-application, August 2010

(Invited) Novel Electronic and Optoelectronic Devices in Germanium Integrated on Silicon
conference, January 2010

Anisotropic Synthesis of Armchair Graphene Nanoribbon Arrays from Sub-5 nm Seeds at Variable Pitches on Germanium
journal, July 2019

Load Sensing System
patent-application, September 2015

Wafer-Scale Growth of Single-Crystal Monolayer Graphene on Reusable Hydrogen-Terminated Germanium
journal, April 2014

High performance germanium MOSFETs
journal, December 2006

Seed-Initiated Anisotropic Growth of Unidirectional Armchair Graphene Nanoribbon Arrays on Germanium
journal, January 2018

Self-Aligned Graphene Transistor
patent-application, May 2011

Direct oriented growth of armchair graphene nanoribbons on germanium
journal, August 2015

Direct Formation of Graphene on Semiconductor Substrates
patent-application, April 2013

High-k/Ge MOSFETs for future nanoelectronics
journal, January 2008

Ethene to Graphene: Surface Catalyzed Chemical Pathways, Intermediates, and Assembly
journal, March 2017

High-Quality Large-Area Graphene from Dehydrogenated Polycyclic Aromatic Hydrocarbons
journal, October 2012

Semiconductor Structure and Circuit Including Ordered Arrangement of Graphene Nanoribbons, and Methods of Forming Same
patent-application, July 2012

Graphene Nanoribbons, Method of Fabrication and their Use in Electronic Devices
patent-application, April 2012

Nanostructured Graphene with Atomically-Smooth Edges
patent-application, May 2013

Growth of Single Crystal Graphene Arrays by Locally Controlling Nucleation on Polycrystalline Cu Using Chemical Vapor Deposition
journal, September 2011

Nanopatterning of graphene with crystallographic orientation control
journal, August 2010

Germanium nanowire field-effect transistors with SiO2 and high-κ HfO2 gate dielectrics
journal, September 2003

Method of Manufacturing Graphene by Using Germanium Layer
patent-application, October 2011

Direct Growth of Graphene Film on Germanium Substrate
journal, August 2013

Structure and Method of Making Graphene Nanoribbons
patent-application, October 2012

Ambient stability of chemically passivated germanium interfaces
journal, October 2003

Etching and narrowing of graphene from the edges
journal, June 2010

Distinctly different thermal decomposition pathways of ultrathin oxide layer on Ge and Si surfaces
journal, April 2000

Extended iron phthalocyanine islands self-assembled on a Ge(001):H surface
journal, March 2021

Graphene Transistors and Photodetectors
journal, January 2013

Seed-mediated growth of patterned graphene nanoribbon arrays
patent, September 2017

Film on graphene on a substrate and method and devices therefor
patent-application, June 2012

Synthesis, Characterization, and Properties of Large-Area Graphene Films
journal, January 2009

Metal Phthalocyanine Nanoribbons and Nanowires
journal, August 2006