High temperature steam separation membrane
Abstract
Ceramic proton-conducting oxide membranes are described herein, which are useful for separating steam from organic chemicals under process conditions. The membranes have a layered structure, with a dense film of the perovskite over a porous composite substrate comprising the perovskite material and a metallic material (e.g., Ni, Cu, or Pt). The perovskite comprises an ABO3-type structure, where “A” is Ba and “B” is a specified combination of Ce, Zr, and Y. The perovskite ceramic materials described herein have an empirical formula of Ba(CexZr1-x-nYn)O3-δ, wherein 0<x<0.8 (e.g., 0.1≤x≤0.7 or 0.2≤x≤0.5); and 0.05≤n≤0.2; and δ=n/2. In some embodiments n is about 0.2. In some other embodiments 0.6≤x≤0.8; and n is about 0.2, such as Ba(Ce0.7Zr0.1Y0.2)O3-δ, also referred to herein as BCZY712.
- Inventors:
- Issue Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1998250
- Patent Number(s):
- 11617992
- Application Number:
- 17/168,646
- Assignee:
- UChicago Argonne, LLC (Chicago, IL)
- DOE Contract Number:
- AC02-06CH11357
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 02/05/2021
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Lee, Tae H., and Balachandran, Uthamalingam. High temperature steam separation membrane. United States: N. p., 2023.
Web.
Lee, Tae H., & Balachandran, Uthamalingam. High temperature steam separation membrane. United States.
Lee, Tae H., and Balachandran, Uthamalingam. Tue .
"High temperature steam separation membrane". United States. https://www.osti.gov/servlets/purl/1998250.
@article{osti_1998250,
title = {High temperature steam separation membrane},
author = {Lee, Tae H. and Balachandran, Uthamalingam},
abstractNote = {Ceramic proton-conducting oxide membranes are described herein, which are useful for separating steam from organic chemicals under process conditions. The membranes have a layered structure, with a dense film of the perovskite over a porous composite substrate comprising the perovskite material and a metallic material (e.g., Ni, Cu, or Pt). The perovskite comprises an ABO3-type structure, where “A” is Ba and “B” is a specified combination of Ce, Zr, and Y. The perovskite ceramic materials described herein have an empirical formula of Ba(CexZr1-x-nYn)O3-δ, wherein 0<x<0.8 (e.g., 0.1≤x≤0.7 or 0.2≤x≤0.5); and 0.05≤n≤0.2; and δ=n/2. In some embodiments n is about 0.2. In some other embodiments 0.6≤x≤0.8; and n is about 0.2, such as Ba(Ce0.7Zr0.1Y0.2)O3-δ, also referred to herein as BCZY712.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2023},
month = {4}
}
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Works referenced in this record:
Development of a multi-species transport space theory and its application to permeation behavior in proton-conducting doped perovskites
journal, January 2010
- Sanders, Michael; O'Hayre, Ryan
- Journal of Materials Chemistry, Vol. 20, Issue 30
Novel Chemically Stable Ceramic-Metal Composite Membrane for Hydrogen Separation
patent-application, November 2015
- Chen, Fanglin; Fang, Shumin; Brinkman, Kyle S.
- US Patent Application 14/678,372; 2015/0314232 Al
Proton-Conducting Oxides
journal, August 2003
- Kreuer, K. D.
- Annual Review of Materials Research, Vol. 33, Issue 1, p. 333-359
Galvanic hydrogen pumping in the protonic ceramic perovskite
journal, November 2013
- Robinson, Shay; Manerbino, Anthony; Grover Coors, W.
- Journal of Membrane Science, Vol. 446
Water vapour solubility and conductivity study of the proton conductor BaCe(0.9−x)ZrxY0.1O(3−δ)
journal, June 2009
- Ricote, S.; Bonanos, N.; Caboche, G.
- Solid State Ionics, Vol. 180, Issue 14-16
Composite Solid Oxide Fuel Cell Electrolyte
patent-application, June 2013
- Liu, Mingfei; Liu, Meilin; He, Ting
- US Patent Application 13/596787; 20130143142
Formation of Solid Oxide Fuel Cells by Spraying
patent-application, November 2019
- Liu, Ying; Liu, Mingfei; Bierschenk, David M.
- US Patent Application 16/526416; 20190356008
Fabrication and Performance of Tubular, Electrode-Supported BaCe 0.2 Zr 0.7 Y 0.1 O 3-δ Fuel Cells
journal, April 2013
- Robinson, S.; Manerbino, A.; Grover Coors, W.
- Fuel Cells, Vol. 13, Issue 4
Formation of Solid Oxide Fuel Cells by Spraying
patent-application, April 2015
- Liu, Ying; Liu, Mingfei; Bierschenk, David M.
- US Patent Application 14/506743; 20150099209
Electrolyte materials for intermediate-temperature solid oxide fuel cells
journal, December 2020
- Shi, Huangang; Su, Chao; Ran, Ran
- Progress in Natural Science: Materials International, Vol. 30, Issue 6
Recovery of Water Vapor Using a Water Vapor Permeable Mixed Ion Conducting Membrane
patent-application, August 2007
- Coors, W. Grover
- US Patent Application 11/616721; 20070186768
Chemical Compositions, Methods of Making the Chemical Compositions, and Structures Made from the Chemical Compositions
patent-application, May 2010
- Yang, Lei; Cheng, Zhe; Liu, Ze
- US Patent Application 12/609179; 20100112408
Method of Producing Layers for Solid Oxide Fuel Cells
patent-application, April 2015
- Liu, Ying; Sirmon, Timothy L.; Melton, Ralph
- US Patent Application 14/507122; 20150099063
The Kinetics of Hydration and H/D Isotope Exchange of Y-Doped Barium Cerate and Lanthanum Tungstate Studied by Transient Thermogravimetry
journal, January 2013
- Hancke, Ragnhild; Li, Zuoan; Haugsrud, Reidar
- Journal of The Electrochemical Society, Vol. 160, Issue 8
Hydrogen Transport Membranes for Dehydrogenation Reactions
patent-application, October 2005
- Balachandran, Uthamalingam
- US Patent Application 10/814210; 20050222479
Gas Phase Modification of Solid Oxide Fuel Cells
patent-application, April 2015
- Bierschenk, David M.; Liu, Ying; Liu, Mingfei
- US Patent Application 14/504774; 20150099212
Liquid Phase Modification of Solid Oxide Fuel Cells
patent-application, April 2015
- Bierschenk, David M.; Liu, Ying; Liu, Mingfei
- US Patent Application 14/505958; 20150099211
Graphene-Ceramic Composite Membrane for Hydrogen Separation Membranes
patent-application, April 2019
- Chen, Fanglin; Fang, Shumin; Brinkman, Kyle
- US Patent Application 16/158366; 20190119110
Formation of solid oxide fuel cells
patent-application, April 2015
- Liu, Ying; Liu, Mingfei; Bierschenk, David M.
- US Patent Application 14/506983; 20150099061
Protonic ceramic steam-permeable membranes
journal, April 2007
- Coors, W.
- Solid State Ionics, Vol. 178, Issue 7-10
Solid Oxide Fuel Cell Reactor
patent-application, August 2011
- Luo, Jing-li; Xian, Xian-zhu; Danilovic, Nemanja
- US Patent Application 12/903063; 20110195342
The Role of Metal Catalyst on Water Permeation and Stability of BaCe0.8Y0.2O3-δ
journal, September 2018
- Al, S.; Zhang, G.
- Journal of Electrochemical Science and Technology, Vol. 9, Issue 3