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Title: Solution-assisted densification of NaSICON ceramics

Abstract

A sodium-ion conducting NaSICON ceramic can be densified via the addition of a solvent to a NaSICON powder and subsequent pressing under high pressure and mild heat. Densification to ˜90% relative density can be achieved, providing a path toward low-temperature fabrication of Na-ion conductors.

Inventors:
; ; ;
Issue Date:
Research Org.:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1987211
Patent Number(s):
11600856
Application Number:
17/153,607
Assignee:
National Technology & Engineering Solutions of Sandia, LLC (Albuquerque, NM)
Patent Classifications (CPCs):
C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
DOE Contract Number:  
NA0003525
Resource Type:
Patent
Resource Relation:
Patent File Date: 01/20/2021
Country of Publication:
United States
Language:
English

Citation Formats

Bock, Jonathan Anton, Spoerke, Erik David, Brown-Shaklee, Harlan James, and Small, Leo J. Solution-assisted densification of NaSICON ceramics. United States: N. p., 2023. Web.
Bock, Jonathan Anton, Spoerke, Erik David, Brown-Shaklee, Harlan James, & Small, Leo J. Solution-assisted densification of NaSICON ceramics. United States.
Bock, Jonathan Anton, Spoerke, Erik David, Brown-Shaklee, Harlan James, and Small, Leo J. Tue . "Solution-assisted densification of NaSICON ceramics". United States. https://www.osti.gov/servlets/purl/1987211.
@article{osti_1987211,
title = {Solution-assisted densification of NaSICON ceramics},
author = {Bock, Jonathan Anton and Spoerke, Erik David and Brown-Shaklee, Harlan James and Small, Leo J.},
abstractNote = {A sodium-ion conducting NaSICON ceramic can be densified via the addition of a solvent to a NaSICON powder and subsequent pressing under high pressure and mild heat. Densification to ˜90% relative density can be achieved, providing a path toward low-temperature fabrication of Na-ion conductors.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2023},
month = {3}
}

Works referenced in this record:

Cold Sintering: A Paradigm Shift for Processing and Integration of Ceramics
journal, August 2016


Sodium zirconium phosphate (NZP) as a host structure for nuclear waste immobilization: A review
journal, January 1994


Densification of a Solid-State NASICON Sodium-Ion Electrolyte Below 400 °C by Cold Sintering With a Fused Hydroxide Solvent
journal, April 2020