Ultra-hard carbon film from epitaxial two-layer graphene

Gao, Yang; Cao, Tengfei; Cellini, Filippo; Riedo, Elisa; Bongiorno, Angelo

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Title: Ultra-hard carbon film from epitaxial two-layer graphene

Abstract

An ultra-hard carbon film is formed by the uniaxial compression of thin films of graphene. The graphene films are two or three layers thick (2-L or 3-L). High pressure compression forms a diamond-like film and provides improved properties to the coated substrates.

Inventors:: Gao, Yang; Cao, Tengfei; Cellini, Filippo; Riedo, Elisa; Bongiorno, Angelo

Issue Date:: 2023-02-28

Research Org.:: City Univ. of New York (CUNY), NY (United States); New York Univ. (NYU), NY (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1987173

Patent Number(s):: 11591716

Application Number:: 16/757,306

Assignee:: Research Foundation of the City University of New York (New York, NY); New York University (New York, NY)

DOE Contract Number:: SC0016204

Resource Type:: Patent

Resource Relation:: Patent File Date: 10/22/2018

Country of Publication:: United States

Language:: English

Citation Formats


                    Gao, Yang, Cao, Tengfei, Cellini, Filippo, Riedo, Elisa, and Bongiorno, Angelo. Ultra-hard carbon film from epitaxial two-layer graphene.  United States: N. p., 2023. 
        Web.

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                    Gao, Yang, Cao, Tengfei, Cellini, Filippo, Riedo, Elisa, & Bongiorno, Angelo. Ultra-hard carbon film from epitaxial two-layer graphene.  United States.

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                    Gao, Yang, Cao, Tengfei, Cellini, Filippo, Riedo, Elisa, and Bongiorno, Angelo. Tue .  
        "Ultra-hard carbon film from epitaxial two-layer graphene".  United States.  https://www.osti.gov/servlets/purl/1987173.

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@article{osti_1987173,

  title        = {Ultra-hard carbon film from epitaxial two-layer graphene},

  author       = {Gao, Yang and Cao, Tengfei and Cellini, Filippo and Riedo, Elisa and Bongiorno, Angelo},

  abstractNote = {An ultra-hard carbon film is formed by the uniaxial compression of thin films of graphene. The graphene films are two or three layers thick (2-L or 3-L). High pressure compression forms a diamond-like film and provides improved properties to the coated substrates.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2023},

  month        = {2}

}

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Similar Records

Title: Ultra-hard carbon film from epitaxial two-layer graphene

Abstract

Citation Formats

Lonsdaleite Films with Nanometer Thickness journal, January 2014

Generalized Gradient Approximation Made Simple journal, October 1996

Pressure-Induced Transformation Path of Graphite to Diamond journal, May 1995

The pressure-temperature phase and transformation diagram for carbon; updated through 1994 journal, January 1996

Clothing for protection against stab and bullet wounds patent, March 1999

On the thermodynamic path enabling a room-temperature, laser-assisted graphite to nanodiamond transformation journal, October 2016

Semiempirical GGA-type density functional constructed with a long-range dispersion correction journal, January 2006

Radial Elasticity of Multiwalled Carbon Nanotubes journal, May 2005

Nanoindentation of diamond, graphite and fullerene films journal, March 2000

Mechanical Behavior of Multilayered Nanoscale Metal-Ceramic Composites journal, December 2005

Electronic Confinement and Coherence in Patterned Epitaxial Graphene journal, May 2006

Local work function measurements of epitaxial graphene journal, September 2008

Thickness-Dependent Reversible Hydrogenation of Graphene Layers journal, June 2009

Osmium has the Lowest Experimentally Determined Compressibility journal, March 2002

High-pressure Raman spectroscopy of graphene journal, August 2009

Amorphous carbon film, process for producing the same and amorphous carbon film-coated material patent, August 2008

Morphology dependence of radial elasticity in multiwalled boron nitride nanotubes journal, September 2012

Hard Carbon Coating and Method of Forming the Same patent-application, October 2011

Wafer transfer plate patent, September 1997

Formation of Large Scale Single Crystalline Graphene patent-application, August 2015

Method of Making Scratch Resistant Coated Glass Article Including Layer(s) Resistant to Fluoride-Based Etchant(s) patent-application, January 2006

Structural and electronic properties of cubic, 2 H , 4 H , and 6 H SiC journal, February 1994

Nanoscale Tunable Reduction of Graphene Oxide for Graphene Electronics journal, June 2010

Large area and structured epitaxial graphene produced by confinement controlled sublimation of silicon carbide journal, September 2011

Nucleation mechanism for the direct graphite-to-diamond phase transition journal, July 2011

Synergetic interplay between pressure and surface chemistry for the conversion of sp2-bonded carbon layers into sp3-bonded carbon films journal, September 2016

Multiple π-bands and Bernal stacking of multilayer graphene on C-face SiC, revealed by nano-Angle Resolved Photoemission journal, February 2014

Diamond-like C2H nanolayer, diamane: Simulation of the structure and properties journal, September 2009

Elastic coupling between layers in two-dimensional materials journal, June 2015

The electronic properties of graphene journal, January 2009

Hardness and elastic modulus of amorphous and nanocrystalline SiC and Si films journal, February 2008

Interlayer Carbon Bond Formation Induced by Hydrogen Adsorption in Few-Layer Supported Graphene journal, August 2013

Switchable friction enabled by nanoscale self-assembly on graphene journal, February 2016

Phase Diagram of Quasi-Two-Dimensional Carbon, From Graphene to Diamond journal, January 2014

Process for producing graphene/SiC composite material and graphene/SiC composite material obtained thereby patent, January 2016

Aspect Ratio Dependence of the Elastic Properties of ZnO Nanobelts journal, May 2007

Tip size effects on atomic force microscopy nanoindentation of a gold single crystal journal, December 2008

Processes for Shaping Nanomaterials patent-application, September 2017

Structural and electronic properties of epitaxial graphene on SiC(0 0 0 1): a review of growth, characterization, transfer doping and hydrogen intercalation journal, September 2010

Room-Temperature Compression-Induced Diamondization of Few-Layer Graphene journal, May 2011

Laser Method for Synthesis and Processing of Continuous Diamond Films on Nondiamond Substrates journal, April 1991

Biaxial Strain Transfer in Supported Graphene journal, December 2016

Composite Materials with Viscoelastic Stiffness Greater Than Diamond journal, February 2007

Mechanism for direct graphite-to-diamond phase transition journal, August 2014

Raman spectroscopy of epitaxial graphene on a SiC substrate journal, March 2008

Conversion of multilayer graphene into continuous ultrathin sp3-bonded carbon films on metal surfaces journal, November 2013

Carbon: A New Crystalline Phase journal, May 1963

Strain Shielding from Mechanically Activated Covalent Bond Formation during Nanoindentation of Graphene Delays the Onset of Failure journal, February 2015

Armor patent-application, December 2017

Torsional frequency response of cantilever beams immersed in viscous fluids with applications to the atomic force microscope journal, November 2002

QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials journal, September 2009

Calibration of rectangular atomic force microscope cantilevers journal, October 1999

Bonding Changes in Compressed Superhard Graphite journal, October 2003

Lonsdaleite Films with Nanometer Thickness
journal, January 2014

Generalized Gradient Approximation Made Simple
journal, October 1996

Pressure-Induced Transformation Path of Graphite to Diamond
journal, May 1995

The pressure-temperature phase and transformation diagram for carbon; updated through 1994
journal, January 1996

Clothing for protection against stab and bullet wounds
patent, March 1999

On the thermodynamic path enabling a room-temperature, laser-assisted graphite to nanodiamond transformation
journal, October 2016

Semiempirical GGA-type density functional constructed with a long-range dispersion correction
journal, January 2006

Radial Elasticity of Multiwalled Carbon Nanotubes
journal, May 2005

Nanoindentation of diamond, graphite and fullerene films
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Mechanical Behavior of Multilayered Nanoscale Metal-Ceramic Composites
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Electronic Confinement and Coherence in Patterned Epitaxial Graphene
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Local work function measurements of epitaxial graphene
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Thickness-Dependent Reversible Hydrogenation of Graphene Layers
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Osmium has the Lowest Experimentally Determined Compressibility
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High-pressure Raman spectroscopy of graphene
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Amorphous carbon film, process for producing the same and amorphous carbon film-coated material
patent, August 2008

Morphology dependence of radial elasticity in multiwalled boron nitride nanotubes
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Hard Carbon Coating and Method of Forming the Same
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Wafer transfer plate
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Formation of Large Scale Single Crystalline Graphene
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Method of Making Scratch Resistant Coated Glass Article Including Layer(s) Resistant to Fluoride-Based Etchant(s)
patent-application, January 2006

Structural and electronic properties of cubic, 2 H , 4 H , and 6 H SiC
journal, February 1994

Nanoscale Tunable Reduction of Graphene Oxide for Graphene Electronics
journal, June 2010

Large area and structured epitaxial graphene produced by confinement controlled sublimation of silicon carbide
journal, September 2011

Nucleation mechanism for the direct graphite-to-diamond phase transition
journal, July 2011

Synergetic interplay between pressure and surface chemistry for the conversion of sp2-bonded carbon layers into sp3-bonded carbon films
journal, September 2016

Multiple π-bands and Bernal stacking of multilayer graphene on C-face SiC, revealed by nano-Angle Resolved Photoemission
journal, February 2014

Diamond-like C2H nanolayer, diamane: Simulation of the structure and properties
journal, September 2009

Elastic coupling between layers in two-dimensional materials
journal, June 2015

The electronic properties of graphene
journal, January 2009

Hardness and elastic modulus of amorphous and nanocrystalline SiC and Si films
journal, February 2008

Interlayer Carbon Bond Formation Induced by Hydrogen Adsorption in Few-Layer Supported Graphene
journal, August 2013

Switchable friction enabled by nanoscale self-assembly on graphene
journal, February 2016

Phase Diagram of Quasi-Two-Dimensional Carbon, From Graphene to Diamond
journal, January 2014

Process for producing graphene/SiC composite material and graphene/SiC composite material obtained thereby
patent, January 2016

Aspect Ratio Dependence of the Elastic Properties of ZnO Nanobelts
journal, May 2007

Tip size effects on atomic force microscopy nanoindentation of a gold single crystal
journal, December 2008

Processes for Shaping Nanomaterials
patent-application, September 2017

Structural and electronic properties of epitaxial graphene on SiC(0 0 0 1): a review of growth, characterization, transfer doping and hydrogen intercalation
journal, September 2010

Room-Temperature Compression-Induced Diamondization of Few-Layer Graphene
journal, May 2011

Laser Method for Synthesis and Processing of Continuous Diamond Films on Nondiamond Substrates
journal, April 1991

Biaxial Strain Transfer in Supported Graphene
journal, December 2016

Composite Materials with Viscoelastic Stiffness Greater Than Diamond
journal, February 2007

Mechanism for direct graphite-to-diamond phase transition
journal, August 2014

Raman spectroscopy of epitaxial graphene on a SiC substrate
journal, March 2008

Conversion of multilayer graphene into continuous ultrathin sp3-bonded carbon films on metal surfaces
journal, November 2013

Carbon: A New Crystalline Phase
journal, May 1963

Strain Shielding from Mechanically Activated Covalent Bond Formation during Nanoindentation of Graphene Delays the Onset of Failure
journal, February 2015

Armor
patent-application, December 2017

Torsional frequency response of cantilever beams immersed in viscous fluids with applications to the atomic force microscope
journal, November 2002

QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials
journal, September 2009

Calibration of rectangular atomic force microscope cantilevers
journal, October 1999

Bonding Changes in Compressed Superhard Graphite
journal, October 2003