Energy storage material and method of producing the same
Abstract
The instant invention includes a spherical porous secondary silicon-based particle and methods for producing the same. The spherical porous secondary silicon-based particle is comprised of agglomerated primary silicon-based nanoparticles. The secondary particle comprises a carbon coating that reduces the effective exposed surface area of the primary particles to the electrolyte, thus improving first cycle efficiency. The secondary particle further comprises porous regions that enable the silicon nanoparticles to expand during lithiation. Advantages include ease of castability with micron-sized spherical particles, ease of mixing spherical particles, ease of flow for spherical particles in various processing steps, and ease with obtaining higher loading, which translates to higher areal capacity and overall energy density of the cell. A readily scalable process for producing the particles using low-cost materials and low-cost processing methods is disclosed.
- Inventors:
- Issue Date:
- Research Org.:
- pH Matter, LLC, Columbus, OH (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1987108
- Patent Number(s):
- 11575126
- Application Number:
- 16/411,421
- Assignee:
- pH Matter, LLC (Columbus, OH)
- DOE Contract Number:
- SC0017724
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 05/14/2019
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Holt, Christopher T., Cramer, Mary C., and Matter, Paul H. Energy storage material and method of producing the same. United States: N. p., 2023.
Web.
Holt, Christopher T., Cramer, Mary C., & Matter, Paul H. Energy storage material and method of producing the same. United States.
Holt, Christopher T., Cramer, Mary C., and Matter, Paul H. Tue .
"Energy storage material and method of producing the same". United States. https://www.osti.gov/servlets/purl/1987108.
@article{osti_1987108,
title = {Energy storage material and method of producing the same},
author = {Holt, Christopher T. and Cramer, Mary C. and Matter, Paul H.},
abstractNote = {The instant invention includes a spherical porous secondary silicon-based particle and methods for producing the same. The spherical porous secondary silicon-based particle is comprised of agglomerated primary silicon-based nanoparticles. The secondary particle comprises a carbon coating that reduces the effective exposed surface area of the primary particles to the electrolyte, thus improving first cycle efficiency. The secondary particle further comprises porous regions that enable the silicon nanoparticles to expand during lithiation. Advantages include ease of castability with micron-sized spherical particles, ease of mixing spherical particles, ease of flow for spherical particles in various processing steps, and ease with obtaining higher loading, which translates to higher areal capacity and overall energy density of the cell. A readily scalable process for producing the particles using low-cost materials and low-cost processing methods is disclosed.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2023},
month = {2}
}
Works referenced in this record:
Additive for lithium ion rechageable battery cells
patent, February 2015
- Coowar, Fazlil; Abdelsalam, Mamdouh Elsayed; Lain, Michael Jonathan
- US Patent Document 8,945,774
Citric Acid Based Pre-SEI for Improvement of Silicon Electrodes in Lithium Ion Batteries
journal, January 2018
- Chandrasiri, K. W. D. Kaveendi; Nguyen, Cao Cuong; Parimalam, Bharathy S.
- Journal of The Electrochemical Society, Vol. 165, Issue 10
Designing nanostructured Si anodes for high energy lithium ion batteries
journal, October 2012
- Wu, Hui; Cui, Yi
- Nano Today, Vol. 7, Issue 5
Porous Silicon Composite Cluster Structure, Method of Preparing the Same, Carbon Composite Using the Same, and Electrode, Lithium Battery, and Device Each Including the Same
patent-application, May 2018
- Moon, Jongseok; Kim, Mijong; Kim, Sewon
- US Patent Application 15/816095; 20180145316
Achieving High-Performance Silicon Anodes of Lithium-Ion Batteries via Atomic and Molecular Layer Deposited Surface Coatings: an Overview
journal, October 2017
- Zhu, Chenyuan; Han, Kai; Geng, Dongsheng
- Electrochimica Acta, Vol. 251
A pomegranate-inspired nanoscale design for large-volume-change lithium battery anodes
journal, February 2014
- Liu, Nian; Lu, Zhenda; Zhao, Jie
- Nature Nanotechnology, Vol. 9, Issue 3
Thin-film lithium and lithium-ion batteries
journal, November 2000
- Bates, J.
- Solid State Ionics, Vol. 135, Issue 1-4
Scalable Fabrication of Silicon Nanotubes and their Application to Energy Storage
journal, July 2012
- Yoo, Jung-Keun; Kim, Jongsoon; Jung, Yeon Sik
- Advanced Materials, Vol. 24, Issue 40
Negative Electrode Active Material for Lithium Secondary Battery and Method of Preparing the Same
patent-application, May 2018
- Kim, Hyun Chul; Lee, Yong Ju; Kim, Eun Kyung
- US Patent Application 15/577233; 20180151874
Artificial Solid Electrolyte Interphase-Protected Li x Si Nanoparticles: An Efficient and Stable Prelithiation Reagent for Lithium-Ion Batteries
journal, June 2015
- Zhao, Jie; Lu, Zhenda; Wang, Haotian
- Journal of the American Chemical Society, Vol. 137, Issue 26
Self-Assembled Nanocomposite of Silicon Nanoparticles Encapsulated in Graphene through Electrostatic Attraction for Lithium-Ion Batteries
journal, April 2012
- Zhou, Xiaosi; Yin, Ya-Xia; Wan, Li-Jun
- Advanced Energy Materials, Vol. 2, Issue 9
Silicon Nanotube Battery Anodes
journal, November 2009
- Park, Mi-Hee; Kim, Min Gyu; Joo, Jaebum
- Nano Letters, Vol. 9, Issue 11, p. 3844-3847
A Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery Alloy Anodes
journal, May 2012
- Liu, Nian; Wu, Hui; McDowell, Matthew T.
- Nano Letters, Vol. 12, Issue 6
Porous Silicon Based Anode Material Formed Using Metal Reduction
patent-application, July 2013
- Anguchamy, Yogesh Kumar; Masarapu, Charan; Deng, Haixia
- US Patent Application 13/354096; 20130189575
High-performance lithium battery anodes using silicon nanowires
journal, December 2007
- Chan, Candace K.; Peng, Hailin; Liu, Gao
- Nature Nanotechnology, Vol. 3, Issue 1, p. 31-35
A vacuum deposited Si film having a Li extraction capacity over 2000 mAh/g with a long cycle life
journal, April 2004
- Takamura, Tsutomu; Ohara, Shigeki; Uehara, Makiko
- Journal of Power Sources, Vol. 129, Issue 1, p. 96-100
Porous Doped Silicon Nanowires for Lithium Ion Battery Anode with Long Cycle Life
journal, April 2012
- Ge, Mingyuan; Rong, Jiepeng; Fang, Xin
- Nano Letters, Vol. 12, Issue 5
Si/C composite, anode active materials, and lithium battery including the same
patent, December 2013
- Mah, Sang-kook; Kim, Han-su
- US Patent Document 8,617,746
Three-Dimensional Porous Silicon Particles for Use in High-Performance Lithium Secondary Batteries
journal, December 2008
- Kim, Hyunjung; Han, Byunghee; Choo, Jaebum
- Angewandte Chemie International Edition, Vol. 47, Issue 52, p. 10151-10154
SI/C Composite, Anode Active Materials, and Lithium Battery Including the Same
patent-application, December 2012
- Mah, Sang-kook; Kim, Han-su
- US Patent Application 13/603844; 20120328943
Manufacturing Method for Catalyst Electrode, Catalyst Electrode Manufactured by Means of Method, and Battery Comprising Same
patent-application, March 2014
- Kim, Jungbae; Lee, Jinwoo; Jeon, Chulmin
- US Patent Application 14/113442; 20140080011
Method of Forming Particulate Material
patent, December 1970
- Monforte, Frank R.; Schnettler, Frank J.
- US Patent Document 3551533