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Title: Transfer hydrogenation of heavy hydrocarbons with hydrogen-donor solvents

Abstract

Processes for converting the coal-derived heavy-oil fraction of syncrude to polyols are described. The processes involve mixing a feed stream comprising the coal-derived heavy-oil fraction with an alcohol and aqueous sulfuric acid, heating the mixture, reacting the coal-derived heavy-oil fraction with ozone, and reacting the ozonated heavy-oil fraction with glycerin to form the polyol. In some cases, the ozonated heavy-oil fraction can be neutralized before reacting the ozonated heavy-oil fraction with the glycerin.

Inventors:
;
Issue Date:
Research Org.:
Battelle Memorial Institute, Columbus, OH (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1987063
Patent Number(s):
11560519
Application Number:
17/654,076
Assignee:
Battelle Memorial Institute (Columbus, OH)
Patent Classifications (CPCs):
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08H - DERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08L - COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
DOE Contract Number:  
FE0023963
Resource Type:
Patent
Resource Relation:
Patent File Date: 03/09/2022
Country of Publication:
United States
Language:
English

Citation Formats

Chauhan, Satya P., and Garbark, Daniel B. Transfer hydrogenation of heavy hydrocarbons with hydrogen-donor solvents. United States: N. p., 2023. Web.
Chauhan, Satya P., & Garbark, Daniel B. Transfer hydrogenation of heavy hydrocarbons with hydrogen-donor solvents. United States.
Chauhan, Satya P., and Garbark, Daniel B. Tue . "Transfer hydrogenation of heavy hydrocarbons with hydrogen-donor solvents". United States. https://www.osti.gov/servlets/purl/1987063.
@article{osti_1987063,
title = {Transfer hydrogenation of heavy hydrocarbons with hydrogen-donor solvents},
author = {Chauhan, Satya P. and Garbark, Daniel B.},
abstractNote = {Processes for converting the coal-derived heavy-oil fraction of syncrude to polyols are described. The processes involve mixing a feed stream comprising the coal-derived heavy-oil fraction with an alcohol and aqueous sulfuric acid, heating the mixture, reacting the coal-derived heavy-oil fraction with ozone, and reacting the ozonated heavy-oil fraction with glycerin to form the polyol. In some cases, the ozonated heavy-oil fraction can be neutralized before reacting the ozonated heavy-oil fraction with the glycerin.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2023},
month = {1}
}

Works referenced in this record:

Temperature-Optimized Conversion of Lignocellulosic Biomass
patent-application, December 2012


Organosolv and Ozone Treatment of Biomass to Enhance Enzymatic Saccharification
patent-application, June 2010


Alternative paths to alcohols and hydrocarbons from biomass
patent, August 2013


Process for Conversion of a Cellulosic Material
patent-application, September 2013


Systems and Methods for the Depolymerization of a Biopolymer
patent-application, May 2016


Methods for the Conversion of Asphaltenes to Light Fractions
patent-application, February 2016


Extraction of Hydrocarbons from Hydrocarbon-Containing Materials and/or Processing of Hydrocarbon-Containing Materials
patent-application, October 2009


Rapid thermal conversion of biomass
patent, March 2011


Method for Extracting Heavy Oil and Bitumen from Tar Sands
patent-application, June 2008


Compositions and Methods for Extracting Hydrocarbons from Oil Sands
patent-application, February 2008


Hydrogenated Vegetable Oil Coal Liquification
patent-application, April 2012


Liquefaction of Carbonaceous Material and Biomass to Produce a Synthetic Fuel
patent-application, December 2013


Char-handling processes in a pyrolysis system
patent, August 2013


Lignin to liquid fuels and polyols using biomass-derived solvents
patent, March 2022


Process for the Liquefaction of Lignocellulosic Material
patent-application, May 2007


Coal liquefaction process
patent, December 1981


Solvent-Enhanced Biomass Liquefaction
patent-application, January 2012


Vapor Phase Catalytic Reactor for Upgrade of Fuels Produced by Fast Pyrolysis of Biomass
patent-application, February 2016


Conversion of lignocellulosic biomass to chemicals and fuels
patent, June 2011


Rapid thermal conversion of biomass
patent, February 2015


Use of Fatty Acids as Feed Material in Polyol Process
patent-application, November 2011