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Title: Extending the lifetime of organic flow batteries via redox state management

Abstract

The invention provides flow batteries including an anthraquinone and methods of discharging the batteries that reduce loss of capacity. The loss of capacity of anthraquinones may be mitigated by controlling the state of charge and/or oxidizing the negolyte.

Inventors:
; ; ;
Issue Date:
Research Org.:
Harvard Univ., Cambridge, MA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1987041
Patent Number(s):
11557786
Application Number:
17/281,767
Assignee:
President and Fellows of Harvard College (Cambridge, MA)
DOE Contract Number:  
AC05-76RL01830; AR0000348
Resource Type:
Patent
Resource Relation:
Patent File Date: 10/01/2019
Country of Publication:
United States
Language:
English

Citation Formats

Goulet, Marc-Antoni, Gordon, Roy G., Aziz, Michael J., and Tong, Liuchuan. Extending the lifetime of organic flow batteries via redox state management. United States: N. p., 2023. Web.
Goulet, Marc-Antoni, Gordon, Roy G., Aziz, Michael J., & Tong, Liuchuan. Extending the lifetime of organic flow batteries via redox state management. United States.
Goulet, Marc-Antoni, Gordon, Roy G., Aziz, Michael J., and Tong, Liuchuan. Tue . "Extending the lifetime of organic flow batteries via redox state management". United States. https://www.osti.gov/servlets/purl/1987041.
@article{osti_1987041,
title = {Extending the lifetime of organic flow batteries via redox state management},
author = {Goulet, Marc-Antoni and Gordon, Roy G. and Aziz, Michael J. and Tong, Liuchuan},
abstractNote = {The invention provides flow batteries including an anthraquinone and methods of discharging the batteries that reduce loss of capacity. The loss of capacity of anthraquinones may be mitigated by controlling the state of charge and/or oxidizing the negolyte.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2023},
month = {1}
}

Works referenced in this record:

CO2 Reduction at Low Overpotential on Cu Electrodes Resulting from the Reduction of Thick Cu2O Films
journal, April 2012


Recording medium and information recording and reproducing method using the same
patent-application, August 2006


Reduction Potentials Of Quinones. II. The Potentials Of Certain Derivatives Of Benzoquinone, Naphthoquinone And Anthraquinone
journal, August 1924


Flow battery with electrolyte rebalancing system
patent, November 2020


Quinone 1 e and 2 e /2 H + Reduction Potentials: Identification and Analysis of Deviations from Systematic Scaling Relationships
journal, November 2016


Reduction potentials for 2,2'-bipyridine and 1,10-phenanthroline couples in aqueous solutions
journal, August 1983


Electrochromic Compounds with Improved Color Stability in Their Radical States
patent-application, August 2016


Simple preparative synthesis of spinochrome e, a pigment from sea urchins of the genus Echinothrix
journal, May 2012


Fuel cells
patent, July 2013


Flow-through electrolytic cell
patent, March 1987


Alkaline Quinone Flow Battery with Long Lifetime at pH 12
journal, September 2018


Information recording medium
patent, February 2000


Long-Cycling Aqueous Organic Redox Flow Battery (AORFB) toward Sustainable and Safe Energy Storage
journal, January 2017


Method and Apparatus of Generating Electric Power
patent-application, June 2007


Analytical applications of 1,10-anthraquinones: A review
journal, June 1991


Transport Property Requirements for Flow Battery Separators
journal, July 2015


High-Performance Aqueous Organic Flow Battery with Quinone-Based Redox Couples at Both Electrodes
journal, January 2016


Small Organic Molecule Based Flow Battery
patent-application, February 2016


Voltammetry of Quinones in Unbuffered Aqueous Solution: Reassessing the Roles of Proton Transfer and Hydrogen Bonding in the Aqueous Electrochemistry of Quinones
journal, October 2007


Novel organic redox flow batteries using soluble quinonoid compounds as positive materials
conference, September 2009


Redox Flow Cell Comprising High Molecular Weight Compounds as Redox Pair and Semipermeable Membrane for Storage of Electrical Energy
patent-application, July 2015


Materials for use in an aqueous organic redox flow battery
patent, March 2021


Systems and methods for series battery charging
patent, December 2018


Self-assembled surfactant structures
patent, March 2020


1,1′,8,8′-Tetramethoxy-10,10′-bianthrone
journal, November 2004


Rebalancing Electrolytes in Redox Flow Battery Systems
patent-application, April 2015


A study of tiron in aqueous solutions for redox flow battery application
journal, January 2010


Fluid-surfaced electrode
patent-application, February 2011


Novel Quinone-Based Couples for Flow Batteries
journal, May 2013


Flow Battery Molecular Reactant Stability Determined by Symmetric Cell Cycling Methods
journal, January 2018


Electrical Energy Storage Apparatus
patent, November 1966


134. Ferrocene derivatives. Part VII. Some sulphur derivatives
journal, January 1958


Reduction Potentials Of Quinones. I. The Effect Of The Solvent On The Potentials Of Certain Benzoquinones
journal, September 1923


Quinone and hydroquinone based flow battery
patent, November 2020


Oxidoreductase reaction control and use thereof
patent, October 2017


The pH-Rate Profile for the Hydrolysis of a Peptide Bond
journal, September 1998


Systems and Methods for Series Battery Charging
patent-application, April 2016


Quinones Having High Capacity Retention for Use as Electrolytes in Aqueous Redox Flow Batteries
patent-application, January 2021


Alkaline quinone flow battery
journal, September 2015


Redox Flow Battery and Method of Operating the Same
patent-application, June 2013


Evolution of nanoporosity in dealloying
journal, March 2001


Redox Flow Battery System for Distributed Energy Storage
patent-application, February 2011


Benzoquinone-Hydroquinone Couple for Flow Battery
journal, January 2013


Fuel cell using quinones to oxidize hydroxylic compounds
patent, March 1986


Small organic molecule based flow battery
patent, May 2018


Cycling of a Quinone-Bromide Flow Battery for Large-Scale Electrochemical Energy Storage
journal, September 2014


Solubility and Aggregation of Gly 5 in Water
journal, July 2014


Anthraquinone with tailored structure for a nonaqueous metal–organic redox flow battery
journal, January 2012


Cooking method for pulp
patent-application, July 2002


High pH Organic Flow Battery
patent-application, February 2018


Charge Transfer Mediator Based Systems for Electrocatalytic Oxygen Reduction
patent-application, September 2017


High-capacity organic positive-electrode material based on a benzoquinone derivative for use in rechargeable lithium batteries
journal, December 2010


Methods for use of a photobiofuel cell in production of hydrogen and other materials
patent-application, August 2007


Electrochemical CO2 Reduction on Metal Electrodes
book, January 2008


Self-Assembled Surfactant Structures
patent-application, November 2011


Electrochromic compounds with improved color stability in their radical states
patent, August 2018


Charge transfer mediator based systems for electrocatalytic oxygen reduction
patent, November 2017


Substituted anthraquinones and use thereof in epoxy resins
patent, May 1990


Quinone and Hydroquinone Based Flow Battery
patent-application, August 2016


Cascade Redox Flow Battery Systems
patent-application, September 2011


Alloy Oxide Electrocatalysts for Regenerative Hydrogen-Halogen Fuel Cell
journal, January 2011


Fuel Cells
patent-application, May 2010


Oxidoreductase Reaction Control and Use Thereof
patent-application, June 2015


A high power density, high efficiency hydrogen–chlorine regenerative fuel cell with a low precious metal content catalyst
journal, January 2012


A metal-free organic–inorganic aqueous flow battery
journal, January 2014


Redox flow battery system for distributed energy storage
patent, December 2014


High Solubility Iron Hexacyanides
patent-application, February 2014


Operating A Redox Flow Battery With A Negative Electrolyte Imbalance
patent-application, July 2014


Small Organic Molecule Based Flow Battery
patent-application, August 2015


Evaluation of organic battery electrodes: Voltammetric study of the redox behaviour of solid quinones
journal, August 1972


Mitigation of latency disparity in a transaction processing system
patent, September 2019


Differential pH as a method for increasing cell potential in organic aqueous flow batteries
journal, January 2017


Electrochemistry of the viologens
journal, January 1981


Redox flow battery and method of operating the same
patent, January 2014


The electrochemical reduction of anthraquinone to anthrone in concentrated H2SO4
journal, September 1985


Computational design of molecules for an all-quinone redox flow battery
journal, January 2015


Anthraquinone Derivatives in Aqueous Flow Batteries
journal, December 2016


Cascade redox flow battery systems
patent, July 2014


Air-Breathing Aqueous Sulfur Rechargeable Batteries
patent-application, August 2018


A redox-flow battery with an alloxazine-based organic electrolyte
journal, July 2016


A Neutral pH Aqueous Organic–Organometallic Redox Flow Battery with Extremely High Capacity Retention
journal, February 2017


High solubility iron hexacyanides
patent, March 2018


Molecularly Tunable Heterogeneous Catalysts by Edge Functionalization of Graphitic Carbons
patent-application, February 2017


Quinone and Hydroquinone Based Flow Battery
patent-application, March 2021


Operating a redox flow battery with a negative electrolyte imbalance
patent, March 2015


Methyl viologen reactions. 5. Rates and mechanism of cation-radical formation in aqueous base
journal, April 1988


Electrochromic materials
journal, January 1997


Mitigation of Latency Disparity in a Transaction Processing System
patent-application, February 2017


Redox flow batteries a review
journal, September 2011


Fluid-surfaced electrode
patent, June 2013


Inexpensive Metal-Free Organic Redox Flow Battery (Orbat) for Grid-Scale Storage
patent-application, December 2014


Cooking method for pulp
patent, June 2006


A Quinone-Bromide Flow Battery with 1 W/cm2 Power Density
journal, July 2015


A Total Organic Aqueous Redox Flow Battery Employing a Low Cost and Sustainable Methyl Viologen Anolyte and 4-HO-TEMPO Catholyte
journal, December 2015


Secondary Battery, Power Supply System Using Same and Usage of Power Supply System
patent-application, January 2009


High Energy Density Redox Flow Device
patent-application, August 2011


Reversible hydrogen storage using CO2 and a proton-switchable iridium catalyst in aqueous media under mild temperatures and pressures
journal, March 2012


Free And Total Energy Changes In The Reduction Of Quinones
journal, November 1922


Carbon monoxide-oxygen fuel cell
patent, December 1987


High energy density redox flow device
patent, May 2014