Sodium electrochemical interfaces with NaSICON-type ceramics

Spoerke, Erik David; Gross, Martha; Percival, Stephen; Rodriguez, Mark A.; Small, Leo J.

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Title: Sodium electrochemical interfaces with NaSICON-type ceramics

Abstract

The present invention is directed to the modification of sodium electrochemical interfaces to improve performance of NaSICON-type ceramics in a variety of electrochemical applications. Enhanced mating of the separator-sodium interface by means of engineered coatings or other surface modifications results in lower interfacial resistance and higher performance at increased current densities, enabling the effective operation of molten sodium batteries and other electrochemical technologies at low and high temperatures.

Inventors:: Spoerke, Erik David; Gross, Martha; Percival, Stephen; Rodriguez, Mark A.; Small, Leo J.

Issue Date:: 2023-01-03

Research Org.:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Sponsoring Org.:: USDOE National Nuclear Security Administration (NNSA)

OSTI Identifier:: 1987002

Patent Number(s):: 11545723

Application Number:: 17/104,306

Assignee:: National Technology & Engineering Solutions of Sandia, LLC (Albuquerque, NM)

Patent Classifications (CPCs):: H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

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H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/054 - Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
H01M4/381 - {Alkaline or alkaline earth metals elements

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

Show less

DOE Contract Number:: NA0003525

Resource Type:: Patent

Resource Relation:: Patent File Date: 11/25/2020

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Spoerke, Erik David, Gross, Martha, Percival, Stephen, Rodriguez, Mark A., and Small, Leo J. Sodium electrochemical interfaces with NaSICON-type ceramics.  United States: N. p., 2023. 
        Web.

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                    Spoerke, Erik David, Gross, Martha, Percival, Stephen, Rodriguez, Mark A., & Small, Leo J. Sodium electrochemical interfaces with NaSICON-type ceramics.  United States.

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                    Spoerke, Erik David, Gross, Martha, Percival, Stephen, Rodriguez, Mark A., and Small, Leo J. Tue .  
        "Sodium electrochemical interfaces with NaSICON-type ceramics".  United States.  https://www.osti.gov/servlets/purl/1987002.

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@article{osti_1987002,

  title        = {Sodium electrochemical interfaces with NaSICON-type ceramics},

  author       = {Spoerke, Erik David and Gross, Martha and Percival, Stephen and Rodriguez, Mark A. and Small, Leo J.},

  abstractNote = {The present invention is directed to the modification of sodium electrochemical interfaces to improve performance of NaSICON-type ceramics in a variety of electrochemical applications. Enhanced mating of the separator-sodium interface by means of engineered coatings or other surface modifications results in lower interfacial resistance and higher performance at increased current densities, enabling the effective operation of molten sodium batteries and other electrochemical technologies at low and high temperatures.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2023},

  month        = {1}

}

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Similar Records

Title: Sodium electrochemical interfaces with NaSICON-type ceramics

Abstract

Citation Formats

Alloy Anodes for Rechargeable Alkali-Metal Batteries: Progress and Challenge journal, June 2019

A high rate and long-cycle-life anode based on micrometer-sized Pb powder for sodium-ion batteries journal, December 2021

Solid‐State Electrolyte Materials for Sodium Batteries: Towards Practical Applications journal, June 2020

Challenges and perspectives on high and intermediate-temperature sodium batteries journal, June 2017

Porous iron oxide coating on β″-alumina ceramics for Na-based batteries journal, September 2014

Investigation of the wetting behavior of Na and Na alloys on uncoated and coated Na-β”-alumina at temperatures below 150 °C journal, March 2017

The Na-Sn (Sodium-Tin) System journal, January 1998

Next generation molten NaI batteries for grid scale energy storage journal, August 2017

High temperature sodium batteries: status, challenges and future trends journal, January 2013

Graphene Regulated Ceramic Electrolyte for Solid-State Sodium Metal Battery with Superior Electrochemical Stability journal, January 2019

A Na+ Superionic Conductor for Room-Temperature Sodium Batteries journal, August 2016

Decorating β′′-alumina solid-state electrolytes with micron Pb spherical particles for improving Na wettability at lower temperatures journal, January 2018

“Ni-Less” Cathodes for High Energy Density, Intermediate Temperature Na-NiCl 2 Batteries journal, March 2018

Salt Splitting Using Ceramic Membranes journal, January 1997

Wetting of sodium on β″-Al2O3/YSZ composites for low temperature planar sodium-metal halide batteries journal, April 2013

Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides patent, January 2012

Composite Alkali Ion Conductive Solid Electrolyte patent-application, July 2013

Sodium zirconium phosphate (NZP) as a host structure for nuclear waste immobilization: A review journal, January 1994

Electrolytic method for the production of sodium and aluminum chloride patent, May 2001

Bulk Bismuth as a High-Capacity and Ultralong Cycle-Life Anode for Sodium-Ion Batteries by Coupling with Glyme-Based Electrolytes journal, July 2017

Bismuth Islands for Low-Temperature Sodium-Beta Alumina Batteries journal, December 2018

Liquid-metal electrode to enable ultra-low temperature sodium–beta alumina batteries for renewable energy storage journal, August 2014

Universal Soldering of Lithium and Sodium Alloys on Various Substrates for Batteries journal, October 2017

Medium-temperature molten sodium batteries with aqueous bromine and iodine cathodes journal, May 2017

Nickel nanowire network coating to alleviate interfacial polarization for Na-beta battery applications journal, October 2013

Low-cost shape-control synthesis of porous carbon film on β″-alumina ceramics for Na-based battery application journal, December 2012

Alkali Metal Super Ionic Conducting Ceramic patent-application, December 2010

Investigation of solid sodium reference electrodes for solid-state electrochemical gas sensors journal, July 1993

Ionic Liquid Redox Catholyte for High Energy Efficiency, Low-Cost Energy Storage journal, April 2015

Alloy Anodes for Rechargeable Alkali-Metal Batteries: Progress and Challenge
journal, June 2019

A high rate and long-cycle-life anode based on micrometer-sized Pb powder for sodium-ion batteries
journal, December 2021

Solid‐State Electrolyte Materials for Sodium Batteries: Towards Practical Applications
journal, June 2020

Challenges and perspectives on high and intermediate-temperature sodium batteries
journal, June 2017

Porous iron oxide coating on β″-alumina ceramics for Na-based batteries
journal, September 2014

Investigation of the wetting behavior of Na and Na alloys on uncoated and coated Na-β”-alumina at temperatures below 150 °C
journal, March 2017

The Na-Sn (Sodium-Tin) System
journal, January 1998

Next generation molten NaI batteries for grid scale energy storage
journal, August 2017

High temperature sodium batteries: status, challenges and future trends
journal, January 2013

Graphene Regulated Ceramic Electrolyte for Solid-State Sodium Metal Battery with Superior Electrochemical Stability
journal, January 2019

A Na+ Superionic Conductor for Room-Temperature Sodium Batteries
journal, August 2016

Decorating β′′-alumina solid-state electrolytes with micron Pb spherical particles for improving Na wettability at lower temperatures
journal, January 2018

“Ni-Less” Cathodes for High Energy Density, Intermediate Temperature Na-NiCl 2 Batteries
journal, March 2018

Salt Splitting Using Ceramic Membranes
journal, January 1997

Wetting of sodium on β″-Al2O3/YSZ composites for low temperature planar sodium-metal halide batteries
journal, April 2013

Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides
patent, January 2012

Composite Alkali Ion Conductive Solid Electrolyte
patent-application, July 2013

Sodium zirconium phosphate (NZP) as a host structure for nuclear waste immobilization: A review
journal, January 1994

Electrolytic method for the production of sodium and aluminum chloride
patent, May 2001

Bulk Bismuth as a High-Capacity and Ultralong Cycle-Life Anode for Sodium-Ion Batteries by Coupling with Glyme-Based Electrolytes
journal, July 2017

Bismuth Islands for Low-Temperature Sodium-Beta Alumina Batteries
journal, December 2018

Liquid-metal electrode to enable ultra-low temperature sodium–beta alumina batteries for renewable energy storage
journal, August 2014

Universal Soldering of Lithium and Sodium Alloys on Various Substrates for Batteries
journal, October 2017

Medium-temperature molten sodium batteries with aqueous bromine and iodine cathodes
journal, May 2017

Nickel nanowire network coating to alleviate interfacial polarization for Na-beta battery applications
journal, October 2013

Low-cost shape-control synthesis of porous carbon film on β″-alumina ceramics for Na-based battery application
journal, December 2012

Alkali Metal Super Ionic Conducting Ceramic
patent-application, December 2010

Investigation of solid sodium reference electrodes for solid-state electrochemical gas sensors
journal, July 1993

Ionic Liquid Redox Catholyte for High Energy Efficiency, Low-Cost Energy Storage
journal, April 2015