Oriented perovskite crystals and methods of making the same
Abstract
An aspect of the present disclosure is a method that includes combining a first organic salt (A1X1), a first metal salt (M1(X2)2), a second organic salt (A2X3), a second metal salt (M2Cl2), and a solvent to form a primary solution, where A1X1 and M1(X2)2 are present in the primary solution at a first ratio between about 0.5 to 1.0 and about 1.5 to 1.0, and A2X3 to M2Cl2 are present in the primary solution at a second ratio between about 2.0 to 1.0 and about 4.0 to 1.0. In some embodiments of the present disclosure, at least one of A1 or A2 may include at least one of an alkyl ammonium, an alkyl diamine, cesium, and/or rubidium.
- Inventors:
- Issue Date:
- Research Org.:
- National Renewable Energy Laboratory (NREL), Golden, CO (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1986959
- Patent Number(s):
- 11535639
- Application Number:
- 16/773,065
- Assignee:
- Alliance for Sustainable Energy, LLC (Golden, CO)
- DOE Contract Number:
- AC36-08GO028308
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 01/27/2020
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Zhu, Kai, Kim, Donghoe, Berry, Joseph Jonathan, and Park, Jaehong. Oriented perovskite crystals and methods of making the same. United States: N. p., 2022.
Web.
Zhu, Kai, Kim, Donghoe, Berry, Joseph Jonathan, & Park, Jaehong. Oriented perovskite crystals and methods of making the same. United States.
Zhu, Kai, Kim, Donghoe, Berry, Joseph Jonathan, and Park, Jaehong. Tue .
"Oriented perovskite crystals and methods of making the same". United States. https://www.osti.gov/servlets/purl/1986959.
@article{osti_1986959,
title = {Oriented perovskite crystals and methods of making the same},
author = {Zhu, Kai and Kim, Donghoe and Berry, Joseph Jonathan and Park, Jaehong},
abstractNote = {An aspect of the present disclosure is a method that includes combining a first organic salt (A1X1), a first metal salt (M1(X2)2), a second organic salt (A2X3), a second metal salt (M2Cl2), and a solvent to form a primary solution, where A1X1 and M1(X2)2 are present in the primary solution at a first ratio between about 0.5 to 1.0 and about 1.5 to 1.0, and A2X3 to M2Cl2 are present in the primary solution at a second ratio between about 2.0 to 1.0 and about 4.0 to 1.0. In some embodiments of the present disclosure, at least one of A1 or A2 may include at least one of an alkyl ammonium, an alkyl diamine, cesium, and/or rubidium.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2022},
month = {12}
}
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
A Solution‐Processed Organometal Halide Perovskite Hole Transport Layer for Highly Efficient Organic Light‐Emitting Diodes
journal, June 2016
- Tian, Yu; Ling, Yichuan; Shu, Yu
- Advanced Electronic Materials, Vol. 2, Issue 7
Liquid-crystalline semiconducting polymers with high charge-carrier mobility
journal, March 2006
- McCulloch, Iain; Heeney, Martin; Bailey, Clare
- Nature Materials, Vol. 5, Issue 4
Role of Chloride in the Morphological Evolution of Organo-Lead Halide Perovskite Thin Films
journal, October 2014
- Williams, Spencer T.; Zuo, Fan; Chueh, Chu-Chen
- ACS Nano, Vol. 8, Issue 10
High-performance photovoltaic perovskite layers fabricated through intramolecular exchange
journal, May 2015
- Yang, W. S.; Noh, J. H.; Jeon, N. J.
- Science, Vol. 348, Issue 6240
Highly oriented crystals at the buried interface in polythiophene thin-film transistors
journal, February 2006
- Joseph Kline, R.; McGehee, Michael D.; Toney, Michael F.
- Nature Materials, Vol. 5, Issue 3
Excitons versus free charges in organo-lead tri-halide perovskites
journal, April 2014
- D’Innocenzo, Valerio; Grancini, Giulia; Alcocer, Marcelo J. P.
- Nature Communications, Vol. 5, Issue 1
High-Performance Planar-Heterojunction Solar Cells Based on Ternary Halide Large-Band-Gap Perovskites
journal, August 2014
- Liang, Po-Wei; Chueh, Chu-Chen; Xin, Xu-Kai
- Advanced Energy Materials, Vol. 5, Issue 1
Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells
journal, July 2014
- Jeon, Nam Joong; Noh, Jun Hong; Kim, Young Chan
- Nature Materials, Vol. 13, Issue 9, p. 897-903
High-efficiency solution-processed perovskite solar cells with millimeter-scale grains
journal, January 2015
- Nie, W.; Tsai, H.; Asadpour, R.
- Science, Vol. 347, Issue 6221, p. 522-525
Solution growth of single-crystal perovskite structures
patent-application, June 2017
- Jin, Song; Fu, Yongping; Meng, Fei
- US Patent Application 14/954442; 20170152608
Nanowire dye-sensitized solar cells
journal, May 2005
- Law, Matt; Greene, Lori E.; Johnson, Justin C.
- Nature Materials, Vol. 4, Issue 6, p. 455-459
Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites
journal, October 2012
- Lee, M. M.; Teuscher, J.; Miyasaka, T.
- Science, Vol. 338, Issue 6107, p. 643-647
Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency
journal, January 2016
- Saliba, Michael; Matsui, Taisuke; Seo, Ji-Youn
- Energy & Environmental Science, Vol. 9, Issue 6
Reproducible One-Step Fabrication of Compact MAPbI 3– x Cl x Thin Films Derived from Mixed-Lead-Halide Precursors
journal, December 2014
- Wang, Dong; Liu, Zhihong; Zhou, Zhongmin
- Chemistry of Materials, Vol. 26, Issue 24
Inorganic-Organic Hybrid Solar Cell Having Durability and High Performance
patent-application, January 2016
- Seok, Sang Il; Im, Sang Hyuk; Noh, Jun Hong
- US Patent Application 14/759748; 20160005547
Efficient inorganic–organic hybrid heterojunction solar cells containing perovskite compound and polymeric hole conductors
journal, May 2013
- Heo, Jin Hyuck; Im, Sang Hyuk; Noh, Jun Hong
- Nature Photonics, Vol. 7, Issue 6, p. 486-491
Optoelectronic Devices With Organometal Perovskites With Mixed Anions
patent-application, May 2015
- Snaith, Henry; Lee, Michael; Murakami, Takuro
- US Patent Application 14/401423; 20150136232
Single Crystal Formamidinium Lead Iodide (FAPbI 3 ): Insight into the Structural, Optical, and Electrical Properties
journal, January 2016
- Han, Qifeng; Bae, Sang-Hoon; Sun, Pengyu
- Advanced Materials, Vol. 28, Issue 11
Synthesis of Perfectly Oriented and Micrometer-Sized MAPbBr 3 Perovskite Crystals for Thin-Film Photovoltaic Applications
journal, May 2016
- Giesbrecht, Nadja; Schlipf, Johannes; Oesinghaus, Lukas
- ACS Energy Letters, Vol. 1, Issue 1
Solar Cell Module
patent-application, September 2012
- Oooka, Haruhi; Saito, Mitsunaga; Hosoya, Masahiro
- US Patent Application 13/422127; 20120234389
Imperfect Oriented Attachment: Dislocation Generation in Defect-Free Nanocrystals
journal, August 1998
- Penn, R. Lee; Banfield, Jillian F.
- Science, Vol. 281, Issue 5379, p. 969-971
FAPbCl 3 Perovskite as Alternative Interfacial Layer for Highly Efficient and Stable Polymer Solar Cells
journal, October 2016
- Wang, Jialin; Peng, Jiajun; Sun, Yong
- Advanced Electronic Materials, Vol. 2, Issue 11